KR950014162A - 방사상 또는 성상 비대칭 블록 공중합체 - Google Patents

방사상 또는 성상 비대칭 블록 공중합체 Download PDF

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KR950014162A
KR950014162A KR1019940029168A KR19940029168A KR950014162A KR 950014162 A KR950014162 A KR 950014162A KR 1019940029168 A KR1019940029168 A KR 1019940029168A KR 19940029168 A KR19940029168 A KR 19940029168A KR 950014162 A KR950014162 A KR 950014162A
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molecular weight
copolymer
block
hydrogenated
conjugated diene
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KR1019940029168A
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KR100348381B1 (ko
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수우현 친 스티븐
로이 힘즈 글렌
제임즈 혹스메이어 로널드
앤 스펜스 브릿지트
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알베르투스 빌 헬무스ㆍ요아네스 쩨스트라텐
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2839—Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2861—Adhesive compositions having readily strippable combined with readily readhearable properties [e.g., stick-ons, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31931—Polyene monomer-containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Sealing Material Composition (AREA)
  • Materials For Medical Uses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

하기 일반식의 방사상 또는 성상 비대칭 볼록 공중합체, 그의 관능화된 유도체, 및 그들을 함유하는 개선된 접착제 및 봉합체 조성물 : (I) (A-HD)x-Y-(UD)z또는 (Ⅱ) (UD-A-HD)x-Y또는 (Ⅲ) ((UD)Y-A-HD)x-Y-(UD)z또는 (Ⅳ)(A-HD1)x-Y- (HD2)2또는 (V)-(HD2-A-HD1x-Y또는 (Vl) (((HD2)2)2Y-A-HD1)x-Y-(HD2)z 여기서, A는 4000-20,000의 분자량을 가지는 비닐 방향족 탄화수소 볼록이고, HD는 10,000-100,000의 분자량을 가지는 수소첨가된 컨쥬게이트 디엔블록이고, Y는 다가 커플링제이고, UD는 1000-80,000의 분자량을 가지는 비수소첨가된 컨쥬게이트 디엔 볼록이 고, x는 2-20의 정수이고, y는 0또는 1이고, z은 1-10의 정수이고, x+z은 3-30의 범위이다.

Description

방사상 또는 성상 비대칭 블록 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 하기 일반식의 방사상 또는 성상 비대칭 블록 공중합체 및 접착성을 증가시키는 극성기로 관능화된 그들의 유도체 : (I) (A-HD)x-Y-(UD)z또는 (Ⅱ) (UD-A-HD)x-Y또는 (Ⅲ) ((UD)Y-A-HD)x-Y-(UD)z또는 (Ⅳ)(A-HD1)x-Y-(HD2)2또는 (V)-(HD2-A-HD1)x-Y또는 (Vl) ((HD2)Y)-A-HD1)x-Y-(HD2)z 여기서, A는 4000-20,000의 분자량을 가지는 비닐 방향족 탄화수소 볼록이고, HD는 10,000-100,000의 분자량을 가지는 수소첨가된 컨쥬게이트 디엔블록이고, Y는 다가 커플링제이고, UD는 1000-80,000의 분자량을 가지는 수소첨가되지 않은 컨쥬게이트 디엔 볼록이고, HD1는 10,000-100,000의 분자량을 가지는 수소첨가된 컨쥬게이트 디엔 블록이고, HD2는 1,000-80,000의 분자량을 가지는 수소첨가된 컨쥬게이트 디엔블록이고 x는 2-20의 정수 이고, y는 0또는 1이고, z는 1-10의 정수이고, x+z은 3-30이다.
  2. 제1항에 있어서, 블록 공중합체는 일반식(Ⅰ)의 방사상 블록 공중합체이고, x는 2-4이고, z는 1-4이며, x+z는 3-6인 공중합체.
  3. 제1및 2항에 있어서, 수소첨가된 디엔은 부타디엔이고, 수소첨가되지 않은 디엔은 이소프렌인 공중합체.
  4. 제1항에 있어서, 폴리 (컨쥬게이트 디엔)블록이 에폭시드화, 카르복실화, 말레이트화, 실란화 또는 아크릴화된 공중합체.
  5. 제4항에 있어서, 수소첨가된 폴리(컨쥬게이트 디엔)블록이 말레이트화 또는 아크릴화 또는 실란화된 공중합체.
  6. 제1-5항의 공중합체 및 접착화 수지로 구성되는 접착체 및 봉합제 조성물.
  7. 제6항에 있어서, 가교된 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940029168A 1993-11-09 1994-11-08 비대칭방사상또는성상블록공중합체 KR100348381B1 (ko)

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Application Number Priority Date Filing Date Title
US08/149,595 US5393841A (en) 1993-11-09 1993-11-09 Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants
US149595 1993-11-09

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KR950014162A true KR950014162A (ko) 1995-06-15
KR100348381B1 KR100348381B1 (ko) 2002-11-30

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US (4) US5393841A (ko)
EP (1) EP0653449B1 (ko)
JP (1) JP3499932B2 (ko)
KR (1) KR100348381B1 (ko)
CN (1) CN1066462C (ko)
AT (1) ATE171196T1 (ko)
AU (1) AU684836B2 (ko)
BR (1) BR9404363A (ko)
CA (1) CA2135266A1 (ko)
DE (1) DE69413350T2 (ko)
DK (1) DK0653449T3 (ko)
ES (1) ES2120565T3 (ko)
NO (1) NO308415B1 (ko)
RU (1) RU2144544C1 (ko)
TW (1) TW275085B (ko)

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US5486574A (en) 1996-01-23
AU7767994A (en) 1995-05-18
ATE171196T1 (de) 1998-10-15
KR100348381B1 (ko) 2002-11-30
US5393841A (en) 1995-02-28
NO308415B1 (no) 2000-09-11
EP0653449B1 (en) 1998-09-16
AU684836B2 (en) 1998-01-08
TW275085B (ko) 1996-05-01
JP3499932B2 (ja) 2004-02-23
BR9404363A (pt) 1995-07-04
NO944243D0 (no) 1994-11-07
US5610238A (en) 1997-03-11
CN1066462C (zh) 2001-05-30
EP0653449A1 (en) 1995-05-17
JPH07188361A (ja) 1995-07-25
US5639831A (en) 1997-06-17
DE69413350D1 (de) 1998-10-22
DE69413350T2 (de) 1999-02-25
CA2135266A1 (en) 1995-05-10
RU94040180A (ru) 1996-10-10
CN1105037A (zh) 1995-07-12
DK0653449T3 (da) 1999-06-23
NO944243L (no) 1995-05-10
RU2144544C1 (ru) 2000-01-20

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