KR960705897A - 접착제용 수소첨가된 다중블록 중합체(multiblock hydrogenated polymers for adhesives) - Google Patents

접착제용 수소첨가된 다중블록 중합체(multiblock hydrogenated polymers for adhesives)

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Publication number
KR960705897A
KR960705897A KR1019960702287A KR19960702287A KR960705897A KR 960705897 A KR960705897 A KR 960705897A KR 1019960702287 A KR1019960702287 A KR 1019960702287A KR 19960702287 A KR19960702287 A KR 19960702287A KR 960705897 A KR960705897 A KR 960705897A
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South Korea
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molecular weight
copolymer
range
polymer block
aromatic hydrocarbon
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KR1019960702287A
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English (en)
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KR100346241B1 (ko
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로이 히메스 글렌
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알베르투스 빌헬무스 요아네스 쩨스트라텐
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Abstract

본 발명은 구조 D-A-(B-A)n-Dx및/또는 (D-A-B)q-Y의 비-테이퍼드 블록 공중합체 및 그들을 함유하는 접착제를 포함하는데, 이때, A는 비닐 방향족 탄화수소 중합체 블록이고, B 및 D는 수소첨가된 컨쥬게이트 디엔 중합체 블록이고, 이때 디엔이 부타디엔이라면, 그것은 적어도 30중량%의 비닐 함량을 가져야 하고, n은 1 내지 5의 정수이고, x는 0 또는 1이고, q는 2 내지 30의 정수이고, Y는 다관능가 커플링제이고, 공중합체는 9 내지 35중량%의 비닐 방향족 탄화수소 함량을 갖는다. B의 분자량에 대한 D의 분자량의 비는 0 초과 내지 180×10-6의 범위일 수 있는 표준화된 분자량 인자에 따른 범위이다.

Description

접착제용 수소첨가된 다중블록 중합체(MULTIBLOCK HYDROGENATED POLYMERS FOR ADHESIVES)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. (a) 하기 식의 다중블록 공증합체 및 (b) 중점 수지로 구성되는 접착제 조성물.
    D-A-(B-A)n-Dx및/또는 (D-A-B)q-Y
    상기 식에서, A는 4000 내지 35,000의 분자량을 갖는 비닐 방향족 탄화수소 중합체 블록이고, B는 20,000 내지 200,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, D는 5000 내지 50,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, B 또는 D중 하나가 수소첨가전에 부타디엔인 경우, 비닐 함량은 30 내지 65중량%이고, B의 분자량에 대한 D의 분자량의 비는 표준화된 분자량 인자가 0 초과 내지 180×10-6의 범위이도록 하는 범위이며, n은 1 내지 5의 정수이며, x는 0 또는 1이며, q는 2 내지 30이며, Y는 다관능가 커플링제이며, 공중합체는 9 내지 35중량%의 비닐 방향족 탄화수소 함량을 갖는다.
  2. 제1항에 있어서, 표준화된 분자량 인자가 0 초과 내지 100×10-6의 범위인 조성물.
  3. 제1항에 있어서, 표준화전 일반식 DA-(B-A)n-Dx의 다중블록 공중합체내 블록 B 및 D의 분자량 비가 0.4 미만인 조성물.
  4. 제1항에 있어서, 표준화전 일반식 (DAB)q-Y의 다중블록 공중합체내 블록 B 및 D의 분자량 비가 0.1 내지 2.2 범위인 조성물.
  5. 제1 내지 4항 중 어느 한 항에 있어서, B 및/또는 D가 수소첨가전에 이소프렌인 조성물.
  6. 제1 내지 5항 중 어느 한 항에 있어서, B 및/또는 D가 수소첨가전에 부타디엔이고, 비닐함량이 30 내지 65%인 조성물.
  7. 하기 일반식의 비-테이퍼드 다중블록 공중합체.
    (D-A-B)q-Y
    상기 식에서, A는 4000 내지 35,000의 분자량을 갖는 비닐 방향족 탄화수소 중합체 블록이고, B는 20,000 내지 200,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, D는 5000 내지 50,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, B 또는 D중 하나가 수소첨가전에 부타디엔인 경우, 비닐 함량은 30 내지 65중량%이고, B의 분자량에 대한 D의 분자량의 비는 표준화된 분자량 인자가 0 초과 내지 180×10-6의 범위이도록 하는 범위이며, q는 2 내지 30이며, Y는 다관능가 커플링제이며, 공중합체는 9 내지 35중량%의 비닐 방향족 탄화수소 함량을 갖는다.
  8. 제7항에 있어서, 표준화된 분자량 인자가 0 초과 내지 100×10-6의 범위인 공중합체.
  9. 제7항에 있어서, 표준화된 분자량 비가 0.1 내지 2.2 범위인 공중합체.
  10. 하기 일반식의 비-테이퍼드 다중블록 공중합체.
    D-A-(B-A)n-D
    상기 식에서, A는 4000 내지 35,000의 분자량을 갖는 비닐 방향족 탄화수소 중합체 블록이고, B는 20,000 내지 200,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, D는 5000 내지 50,000의 분자량을 갖는 수소첨가된 컨쥬게이트 디엔 중합체 블록이며, B 또는 D중 하나가 수소첨가전에 부타디엔인 경우, 비닐 함량은 30 내지 65중량%이고, B의 분자량에 대한 D의 분자량의 비는 표준화된 분자량 인자가 0 초과 내지 180×10-6의 범위이도록 하는 범위이고, n은 1 내지 5의 정수이며, 공중합체는 9 내지 35중량％의 비닐방향족 탄화수소 함량을 갖는다.
  11. 제7항 또는 10항에 있어서, D 및/또는 B가 수소첨가전 이소프레임 다중블록 공중합체.
  12. 제7항 또는 10항에 있어서, D 및/또는 B가 수소첨가전 부타디엔이고, 비닐 함량이 30 내지 65%인 다중블록 공중합체.
  13. 제10항에 있어서, 표준화된 분자량 인자가 0 초과 내지 100×10-6의 범위인 다중블록 공중합체.
  14. 제10항에 있어서, 표준화전 분자량 비가 0.4 미만인 공중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960702287A 1993-11-03 1994-10-31 접착제용수소첨가된다중블록중합체 KR100346241B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US14721893A 1993-11-03 1993-11-03
US08/147,218 1993-11-03
US08/147218 1993-11-03
US08/320,033 1994-10-07
US08/320033 1994-10-07
US08/320,033 US5589542A (en) 1993-11-03 1994-10-07 Multiblock hydrogenated polymers for adhesives

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KR960705897A true KR960705897A (ko) 1996-11-08
KR100346241B1 KR100346241B1 (ko) 2003-10-04

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US (3) US5589542A (ko)
EP (1) EP0726927B1 (ko)
JP (1) JP3556224B2 (ko)
KR (1) KR100346241B1 (ko)
CN (1) CN1066182C (ko)
AT (1) ATE163031T1 (ko)
AU (1) AU687131B2 (ko)
BR (1) BR9407936A (ko)
CA (1) CA2175580A1 (ko)
DE (1) DE69408474T2 (ko)
DK (1) DK0726927T3 (ko)
ES (1) ES2111966T3 (ko)
NO (1) NO308906B1 (ko)
RU (1) RU2160755C2 (ko)
WO (1) WO1995012645A1 (ko)

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WO1995012645A1 (en) 1995-05-11
JP3556224B2 (ja) 2004-08-18
KR100346241B1 (ko) 2003-10-04
RU2160755C2 (ru) 2000-12-20
CN1136821A (zh) 1996-11-27
CN1066182C (zh) 2001-05-23
JPH09504566A (ja) 1997-05-06
US5589542A (en) 1996-12-31
DE69408474T2 (de) 1998-06-04
EP0726927B1 (en) 1998-02-04
BR9407936A (pt) 1996-11-26
NO308906B1 (no) 2000-11-13
CA2175580A1 (en) 1995-05-11
ATE163031T1 (de) 1998-02-15
NO961760L (no) 1996-06-28
AU687131B2 (en) 1998-02-19
US5627235A (en) 1997-05-06
ES2111966T3 (es) 1998-03-16
DK0726927T3 (da) 1998-05-11
AU1107395A (en) 1995-05-23
DE69408474D1 (de) 1998-03-12
EP0726927A1 (en) 1996-08-21
NO961760D0 (no) 1996-04-30
USRE36757E (en) 2000-06-27

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