KR950000841A - 정제된 고온 가스 제조를 위한 부분 산화방법 - Google Patents
정제된 고온 가스 제조를 위한 부분 산화방법 Download PDFInfo
- Publication number
- KR950000841A KR950000841A KR1019940013701A KR19940013701A KR950000841A KR 950000841 A KR950000841 A KR 950000841A KR 1019940013701 A KR1019940013701 A KR 1019940013701A KR 19940013701 A KR19940013701 A KR 19940013701A KR 950000841 A KR950000841 A KR 950000841A
- Authority
- KR
- South Korea
- Prior art keywords
- gas
- gas stream
- alkali metal
- sulfur
- fuel
- Prior art date
Links
- 230000003647 oxidation Effects 0.000 title claims abstract 4
- 238000007254 oxidation reaction Methods 0.000 title claims abstract 4
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 title claims description 14
- 239000007789 gas Substances 0.000 claims abstract 57
- 239000000446 fuel Substances 0.000 claims abstract 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 11
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 11
- 239000011593 sulfur Substances 0.000 claims abstract 11
- 150000001339 alkali metal compounds Chemical class 0.000 claims abstract 10
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims abstract 10
- 239000013618 particulate matter Substances 0.000 claims abstract 7
- 239000007788 liquid Substances 0.000 claims abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- -1 hydrogen halides Chemical class 0.000 claims abstract 4
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims abstract 4
- 230000003197 catalytic effect Effects 0.000 claims abstract 3
- 238000007323 disproportionation reaction Methods 0.000 claims abstract 3
- 150000004820 halides Chemical class 0.000 claims abstract 3
- 229910001508 alkali metal halide Inorganic materials 0.000 claims abstract 2
- 150000008045 alkali metal halides Chemical class 0.000 claims abstract 2
- 229910021529 ammonia Inorganic materials 0.000 claims abstract 2
- 230000015572 biosynthetic process Effects 0.000 claims abstract 2
- 239000000839 emulsion Substances 0.000 claims abstract 2
- 238000001914 filtration Methods 0.000 claims abstract 2
- 239000002737 fuel gas Substances 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 2
- 239000002006 petroleum coke Substances 0.000 claims abstract 2
- 239000002002 slurry Substances 0.000 claims abstract 2
- 230000000153 supplemental effect Effects 0.000 claims abstract 2
- 238000003786 synthesis reaction Methods 0.000 claims abstract 2
- 239000003921 oil Substances 0.000 claims 7
- 239000003463 adsorbent Substances 0.000 claims 4
- 238000001816 cooling Methods 0.000 claims 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 239000003209 petroleum derivative Substances 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 239000011280 coal tar Substances 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims 1
- 230000009970 fire resistant effect Effects 0.000 claims 1
- 238000004231 fluid catalytic cracking Methods 0.000 claims 1
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims 1
- 239000003502 gasoline Substances 0.000 claims 1
- 239000012433 hydrogen halide Substances 0.000 claims 1
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 1
- 239000003350 kerosene Substances 0.000 claims 1
- 239000003915 liquefied petroleum gas Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- 239000003345 natural gas Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 239000011275 tar sand Substances 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 abstract 2
- 239000002250 absorbent Substances 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 239000002893 slag Substances 0.000 abstract 1
- 239000011882 ultra-fine particle Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/466—Entrained flow processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/024—Dust removal by filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1606—Combustion processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1662—Conversion of synthesis gas to chemicals to methane
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Treating Waste Gases (AREA)
Abstract
본 발명은 NH3를 포함하거나 포함하지 않고, 미립자 물질, 알칼리금속 화합물, 할로겐화수소, 시안화수소, 황을 함유하는 가스가 실질적으로 없는, 합성 가스, 환원 가스 또는 연료 가스용의 정제된 고온 가스기류를 제조하기 위한 부분 산화방법에 관한 것이다. 액체 탄화수소질 연료 또는 이들의 액체 에멀젼, 석유 코크스의 수성 슬러리, 및 이들의 혼합물로부터 선택된, 할로겐화물, 알칼리금속 화합물, 황, 질소 및 무기회분을 함유하는 펌프할수 있는 연료는 부분 산화에 의하여, H2, CO, CO2, H2O, CH4, NH3, HCN, HCl, HF, H2S, COS, N2, Ar, 미립자 물질, 증기상 알칼리금속 화합물, 용융 슬래그를 함유하는 고온의 원료 가스기류를 제조한다. 상기한 고온의 원료 가스기류는 냉각되고 세척된다. 임의로, 암모니아는 촉매적으로 N2와 H2로 불균등화되어 제거된다. 가공중의 가스기류는 냉각되어 가스기류중의 할로겐화물과 HCN은 HCl, HF, HCN을 제거하기 위한 보충 알칼리금속 화합물과 반응한다. 할로겐화 알칼리금속과 시안화 알칼리금속, 증기화된 알칼리금속 화합물과 잔류 초미립자 물질은 재냉각 및 여과에 의해 제거된다. 가공중의 가스기류내의 황을 함유하는 기체는 고온에서 혼합 금속 산화물 황 흡수제와 반응하여 적어도 540℃의 정제된 고온의 청정 가스기류에서 분리된 황화된 흡수제를 생성한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 방법의 한 구현예를 도시화한 것이다.
Claims (12)
- (1) 펌프할수 있는 탄화수소질 연료 원료공급원을 유리 산소를 함유하는 기체로 부분 산화반응시키되, 산화 탄화수소질 연료 원료공급원은 액체 탄화수소질 연료 또는 이들의 액체 에멀젼, 석유 코크스의 수성 슬러리, 또는 이들의 혼합물이고, 상기 연료는 할로겐화물, 알칼리금속 화합물, 황, 질소 및 무기 회분을 함유하는 성분을 포함하고 내화성 피복된 수직의 부분 산화 가스 발생기에서 유리 산소를 함유하는 기체와 반응하여 980 내지 1650℃의 온도를 가지는 H2, CO, CO2, H2O, CH4, NH3, HCN, HCl, HF, H2S, COS, N2, Ar을 함유하고 미립자 물질과 증기상 알칼리금속 화합물을 포함하는 고온의 원료 가스기류를 제조하고; (2) 가스 냉각영역에서 상기 단계(1)의 고온 원료 가스기류를 540 내지 700℃로 부분적으로 냉각하고; (3) 상기 단계(2)의 원료 가스기류로부터 미립자 물질을 분리하고; (4) 보충 알칼리금속 화합물을 단계(3)의 가공중의 가스기류에 주입하여 가공중의 가스기류 내에 존재하는 시안화수소 및 기체 상태의 할로겐화수소와 반응시키고; 이 가스기류를 약 430 내지 540℃로 냉각하고 얻어진 가스기류를 여과하여 할로겐화 알칼리금속과 시안화물, 잔여 알칼리금속 화합물, 및 잔여미립자 물질을 분리하고; (5) 냉각 및 여과된 상기 단계(4)의 가스기류를 황-제거 영역에서 황 반응성 산화물을 함유하는 혼합 금속 산화물 흡착제와 접촉시키는데, 상기에서 단계(4)의 냉각 및 여과된 가스기류중의 황을 함유하는 기체는 황 반응성 산화물을 함유하는 혼합 금속 산화물 흡착제와 반응하여 황화된 흡착제를 생성하고; 냉각 및 여과된 가스기류로부터 상기 황화된 흡착제 물질을 분리하여 미립자 물질, 알칼리금속 화합물, 할로겐화수소, 시안화수소, H2S, COS가 실질적으로 없는 적어도 540℃의 온도를 가지는 정제된 가스기류를 제조하는 것으로 이루어진 합성 가스, 환원 가스 또는 연료 가스를 제조하기 위한 부분 산화방법.
- 제1항에 있어서, 상기 액체 탄화수소질 연료는 액화 석유 가스, 석유 증류액 및 잔류물, 가솔린, 나프타, 케로신, 정제되지 않은 석유, 아스팔트, 가스 오일, 잔류 오일, 타르 모래 및 세일유, 코올 오일, 벤젠, 톨루엔 및 크실렌 분획물 등의 방향족 탄화수소, 코올 타르, 유동 촉매 크래킹 처리로부터의 순환 가스 오일, 코커 가스 오일의 퓨어퓨랄 추출물, 타이어 오일 또는 이들의 혼합물인 것임을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 상기 기체 탄화수소 연료는 메탄, 에탄, 프로판, 부탄, 펜탄, 천연 가스, 수성 가스, 코크스-오븐 가스, 정유 가스, 아세틸렌정제 가스, 에틸렌 오프-가스, 합성 가스, 또는 이들의 혼합물인 것임을 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 하나의 항에 있어서, 단계(4)로부터 방출되는 가공중의 가스기류를 촉매 수성 가스 이동 반응영역을 통과시켜 이 가공중의 가스기류를 단계(5) 이전에 540 내지 680℃의 온도를 가열하여 단계를 특징으로 하는 방법.
- 제4항에 있어서, 보충수를 상기 수성 가스 이동 반응영역 이전에 가공중의 가스기류에 주입하는 단계를 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 하나의 항에 있어서, 단계(4)로부터 방출되는 가공중의 가스기류를 촉매메탄화 반응영역을 통과시켜 이 가공중의 가스기류를 단계(5)이전에 540 내지 680℃의 온도로 가열하는 단계를 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 하나의 항에 있어서, 단계(4)로부터 방출되는 가스 기류를 단계(5)이전에 간접 열교환방법에 의해 540 내지 680℃의 온도로 가열하는 단계를 특징으로 하는 방법.
- 제1항 내지 제7항중 어느 하나의 항에 있어서, 단계(5)에서 540 내지 680℃의 온도 및 단계(1)의 가스발생기에서 라인내의 통상의 압력강하가 더적은 압력하에서 단계(4)의 가스기류 중의 H2S 및 COS가 상기 황 반응성 혼합금속 산화물의 황 반응성 부분과 반응하는 것임을 특징으로 하는 방법.
- 제1항 내지 제8항중 어느 하나의 항에 있어서, 단계(2)와 (3)이 단계(1)의 고온의 원료 가스기류를 가스 냉각영역에서 800 내지 980℃로 부분적으로 냉각하고; 상기 부분적으로 냉각된 원료 가스기류로부터 포집된 미립자 물질을 분리하고; 가공중의 가스기류 내의 암모니아를 촉매적으로 불균등화하여 단계(4)로 이송하기 위한 실질적으로 NH3가 없는 가공중의 가스기류를 제조하는 것으로 이루어진 것임을 특징으로 하는 방법.
- 제9항에 있어서, 단계(5)에서의 황 반응성 산화물과의 접촉은 540 내지 680℃의 온도에서 실시되는 것임을 특징으로 하는 방법.
- 제9항 또는 제10항에 있어서, 상기 가스기류가 800 내지 980℃에서 니켈 불균등화 촉매와 접촉하는 동안 상기 NH3가 N2및 H2로 불균등화되는 것임을 특징으로 하는 방법.
- 제1항 내지 제11항중 어느 하나의 항에 있어서, 상기 탄화수소질 연료 연료공급원은 980 내지 1650℃의 온도 및 2 내지 300atm의 압력하에서 탄화수소질 연료에 대한 물의 중량비가 0.1 내지 5.0이고 0/C의 원자비가 0.7 내지 1.5로 상기 유리 산소를 함유하는 기체와 반응하는 것임을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/077,269 US5403366A (en) | 1993-06-17 | 1993-06-17 | Partial oxidation process for producing a stream of hot purified gas |
| US077,269 | 1993-06-17 | ||
| US077.269 | 1993-06-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR950000841A true KR950000841A (ko) | 1995-01-03 |
| KR100317107B1 KR100317107B1 (ko) | 2002-06-20 |
Family
ID=22137093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940013701A KR100317107B1 (ko) | 1993-06-17 | 1994-06-17 | 정제된고온가스제조를위한부분산화방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5403366A (ko) |
| EP (1) | EP0629684B1 (ko) |
| JP (1) | JPH0710502A (ko) |
| KR (1) | KR100317107B1 (ko) |
| CN (1) | CN1037956C (ko) |
| CA (1) | CA2124147C (ko) |
| DE (1) | DE69415728T2 (ko) |
| ES (1) | ES2125409T3 (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100398421B1 (ko) * | 1999-12-23 | 2003-09-19 | 주식회사 포스코 | 냉각법을 이용한 코크스 가스 정제방법 |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5720785A (en) * | 1993-04-30 | 1998-02-24 | Shell Oil Company | Method of reducing hydrogen cyanide and ammonia in synthesis gas |
| US6432368B1 (en) * | 1994-06-30 | 2002-08-13 | General Electric Company | Staged catalytic ammonia decomposition in integrated gasification combined cycle systems |
| US5801115A (en) * | 1995-09-05 | 1998-09-01 | Kataleuna Gmbh | Catalyst composition and methods for using and preparing same |
| US5753198A (en) * | 1996-12-30 | 1998-05-19 | General Electric Company | Hot coal gas desulfurization |
| US6641625B1 (en) * | 1999-05-03 | 2003-11-04 | Nuvera Fuel Cells, Inc. | Integrated hydrocarbon reforming system and controls |
| TW565470B (en) * | 1999-12-28 | 2003-12-11 | Nippon Catalytic Chem Ind | Process for disposing of exhaust gases |
| US6196000B1 (en) * | 2000-01-14 | 2001-03-06 | Thermo Energy Power Systems, Llc | Power system with enhanced thermodynamic efficiency and pollution control |
| JP3072293U (ja) | 2000-04-05 | 2000-10-06 | 船井電機株式会社 | 光センサホルダ |
| US20040122267A1 (en) * | 2002-12-23 | 2004-06-24 | Jaimes Sher | Integrated gas to olefins process with recovery and conversion of by-products |
| CN1314579C (zh) * | 2003-03-14 | 2007-05-09 | 华东理工大学 | 气态烃为原料非催化部分氧化法生产合成气的装置与方法 |
| US7056487B2 (en) * | 2003-06-06 | 2006-06-06 | Siemens Power Generation, Inc. | Gas cleaning system and method |
| US20050154069A1 (en) * | 2004-01-13 | 2005-07-14 | Syntroleum Corporation | Fischer-Tropsch process in the presence of nitrogen contaminants |
| US7022742B2 (en) * | 2004-04-08 | 2006-04-04 | Syntroleum Corporation | Process to control nitrogen-containing compounds in synthesis gas |
| US7694523B2 (en) * | 2004-07-19 | 2010-04-13 | Earthrenew, Inc. | Control system for gas turbine in material treatment unit |
| US7024796B2 (en) * | 2004-07-19 | 2006-04-11 | Earthrenew, Inc. | Process and apparatus for manufacture of fertilizer products from manure and sewage |
| US7685737B2 (en) | 2004-07-19 | 2010-03-30 | Earthrenew, Inc. | Process and system for drying and heat treating materials |
| US7024800B2 (en) * | 2004-07-19 | 2006-04-11 | Earthrenew, Inc. | Process and system for drying and heat treating materials |
| US7610692B2 (en) * | 2006-01-18 | 2009-11-03 | Earthrenew, Inc. | Systems for prevention of HAP emissions and for efficient drying/dehydration processes |
| US20080190026A1 (en) * | 2006-12-01 | 2008-08-14 | De Jong Johannes Cornelis | Process to prepare a mixture of hydrogen and carbon monoxide from a liquid hydrocarbon feedstock containing a certain amount of ash |
| DE102007059542A1 (de) * | 2007-12-11 | 2009-06-25 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Entsorgung von Abgasen |
| US20100018216A1 (en) * | 2008-03-17 | 2010-01-28 | Fassbender Alexander G | Carbon capture compliant polygeneration |
| FR2929955B1 (fr) * | 2008-04-09 | 2012-02-10 | Saint Gobain | Gazeification de materiaux organiques combustibles |
| US7955403B2 (en) * | 2008-07-16 | 2011-06-07 | Kellogg Brown & Root Llc | Systems and methods for producing substitute natural gas |
| DE102008049579A1 (de) * | 2008-09-30 | 2010-04-01 | Uhde Gmbh | Heißgasreinigung |
| KR101482160B1 (ko) | 2008-10-02 | 2015-01-14 | 재단법인 포항산업과학연구원 | 산업 폐열을 이용한 이산화탄소의 화학적 처리방법 및 그처리장치 |
| US8007688B2 (en) * | 2008-10-22 | 2011-08-30 | Southern Research Institute | Process for decontaminating syngas |
| CN101508915B (zh) * | 2009-03-17 | 2012-09-05 | 惠生工程（中国）有限公司 | 一种液体燃料或固体燃料水淤浆的气化装置 |
| CA2756306A1 (en) * | 2009-03-30 | 2010-10-07 | Shell Internationale Research Maatschappij B.V. | Process for producing a purified synthesis gas stream |
| KR101178526B1 (ko) | 2010-10-05 | 2012-08-30 | 주식회사 포스코 | 코크스로 가스 또는 석탄가스화로 가스의 이용방법 |
| US8992640B2 (en) * | 2011-02-07 | 2015-03-31 | General Electric Company | Energy recovery in syngas applications |
| JP2013170091A (ja) | 2012-02-20 | 2013-09-02 | Toyo Eng Corp | 合成ガスの製造方法 |
| JP2014015499A (ja) * | 2012-07-06 | 2014-01-30 | Hitachi Ltd | ガス化方法とそのシステム、石炭ガス化複合発電方法とそのシステム。 |
| CN103146432B (zh) * | 2013-03-18 | 2014-05-07 | 华北电力大学 | 一种生物质热解气化与焦油催化裂解的装置与方法 |
| CN105885944A (zh) * | 2014-11-03 | 2016-08-24 | 胥利先 | 生物质在线催化气化方法及系统 |
| CN110312779B (zh) * | 2017-02-20 | 2021-08-31 | 沙特阿拉伯石油公司 | 使用焦化器脱硫和除砜 |
| CN108543386A (zh) * | 2018-06-26 | 2018-09-18 | 贵阳铝镁设计研究院有限公司 | 一种用于净化炭素制品焙烧烟气的方法 |
| CN108607361B (zh) * | 2018-07-05 | 2023-09-19 | 苏州西热节能环保技术有限公司 | 一种一体化喷射系统 |
| CN108607362B (zh) * | 2018-07-05 | 2023-09-19 | 苏州西热节能环保技术有限公司 | 一种具有一体化喷射系统的脱除烟气中三氧化硫与NOx的装置 |
| CN110470789B (zh) * | 2019-08-26 | 2022-07-05 | 四川达兴能源股份有限公司 | 一种焦炉煤气中氰化氢的测定方法 |
| CN114410349A (zh) * | 2021-12-29 | 2022-04-29 | 中石化宁波工程有限公司 | 配套水煤浆气化的废物预处理工艺 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US436531A (en) * | 1890-09-16 | Machine for forming type-bars | ||
| SE7503313L (sv) * | 1975-03-21 | 1976-09-22 | Stora Kopparbergs Bergslags Ab | Sett for omvandling av kolhaltiga material innehallande svavel till i huvudsak svavelfri brennbar gas samt anordning for genomforande av settet |
| KR790001806B1 (ko) * | 1975-11-27 | 1979-12-20 | 에프 에이취 토우스리 쥬니어 | 합성가스로부터 미립자상 탄소를 회수하는 방법 |
| US4032618A (en) * | 1976-05-11 | 1977-06-28 | The United States Energy Research And Development Administration | Conversion of ammonia into hydrogen and nitrogen by reaction with a sulfided catalyst |
| US4132065A (en) * | 1977-03-28 | 1979-01-02 | Texaco Inc. | Production of H2 and co-containing gas stream and power |
| US4189307A (en) * | 1978-06-26 | 1980-02-19 | Texaco Development Corporation | Production of clean HCN-free synthesis gas |
| US4202167A (en) * | 1979-03-08 | 1980-05-13 | Texaco Inc. | Process for producing power |
| US4374105A (en) * | 1979-12-11 | 1983-02-15 | Institute Of Gas Technology | Purification of fuel gases |
| DE3113993A1 (de) * | 1981-04-07 | 1982-11-11 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur gleichzeitigen erzeugung von brenngas und prozesswaerme aus kohlenstoffhaltigen materialien |
| DE3137812A1 (de) * | 1981-09-23 | 1983-03-31 | Vereinigte Elektrizitätswerke Westfalen AG, 4600 Dortmund | "verfahren zum abscheiden von chlor, fluor und schwefel aus brenn- und rauchgasen" |
| US4436531A (en) * | 1982-08-27 | 1984-03-13 | Texaco Development Corporation | Synthesis gas from slurries of solid carbonaceous fuels |
| DE3611429A1 (de) * | 1985-02-15 | 1986-11-06 | SKF Steel Engineering AB, Hofors | Verfahren zur abfallzersetzung |
| DE3629817A1 (de) * | 1986-09-02 | 1988-03-03 | Bergwerksverband Gmbh | Verfahren zur verringerung der schadstoffemisionen von kraftwerken mit kombinierten gas-/dampfturbinenprozessen mit vorgeschalteter kohlevergasung |
| US4704137A (en) * | 1987-02-09 | 1987-11-03 | Texaco Inc. | Process for upgrading water used in cooling and cleaning of raw synthesis gas |
| GB2202546B (en) * | 1987-02-16 | 1991-07-31 | Hitachi Ltd | Desulfurizing agent, process for treating hydrogen sulfide-containing gas, coal gasification system and power generation system |
| US4857285A (en) * | 1987-06-04 | 1989-08-15 | General Electric Environmental Services, Inc. | Method and system for removal of sulfur compounds from gases and for regenerating spent sorbents |
| US5213587A (en) * | 1987-10-02 | 1993-05-25 | Studsvik Ab | Refining of raw gas |
| SE459584B (sv) * | 1987-10-02 | 1989-07-17 | Studsvik Ab | Foerfarande foer foeraedling av raagas framstaelld ur ett kolhaltigt material |
| US4880439A (en) * | 1988-05-05 | 1989-11-14 | Texaco Inc. | High temperature desulfurization of synthesis gas |
| DE3929926A1 (de) * | 1989-09-08 | 1991-03-21 | Metallgesellschaft Ag | Verfahren zum behandeln der gase aus der vergasung fester, feinkoerniger brennstoffe |
| US5045522A (en) * | 1990-03-27 | 1991-09-03 | Phillips Petroleum Company | Absorption composition comprising zinc titanate for removal of hydrogen sulfide from fluid streams |
| US5118480A (en) * | 1990-06-25 | 1992-06-02 | General Electric Environmental Services, Incorporated | Method for removing hcl and hf from coal derived fuel gas |
| US5227351A (en) * | 1991-03-13 | 1993-07-13 | The United States Of America As Represented By The United States Department Of Energy | Sorbent for use in hot gas desulfurization |
| US5220782A (en) * | 1991-10-23 | 1993-06-22 | Bechtel Group, Inc. | Efficient low temperature solvent removal of acid gases |
| NL9101793A (nl) * | 1991-10-24 | 1993-05-17 | Hoogovens Groep Bv | Werkwijze en inrichting voor de droge verwijdering van halogeenhoudende componenten uit een gas. |
| US5243922A (en) * | 1992-07-31 | 1993-09-14 | Institute Of Gas Technology | Advanced staged combustion system for power generation from coal |
-
1993
- 1993-06-17 US US08/077,269 patent/US5403366A/en not_active Expired - Lifetime
-
1994
- 1994-05-24 CA CA002124147A patent/CA2124147C/en not_active Expired - Fee Related
- 1994-06-02 EP EP94303954A patent/EP0629684B1/en not_active Expired - Lifetime
- 1994-06-02 ES ES94303954T patent/ES2125409T3/es not_active Expired - Lifetime
- 1994-06-02 DE DE69415728T patent/DE69415728T2/de not_active Expired - Lifetime
- 1994-06-16 CN CN94106474A patent/CN1037956C/zh not_active Expired - Fee Related
- 1994-06-17 JP JP6158185A patent/JPH0710502A/ja active Pending
- 1994-06-17 KR KR1019940013701A patent/KR100317107B1/ko not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100398421B1 (ko) * | 1999-12-23 | 2003-09-19 | 주식회사 포스코 | 냉각법을 이용한 코크스 가스 정제방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1101890A (zh) | 1995-04-26 |
| JPH0710502A (ja) | 1995-01-13 |
| ES2125409T3 (es) | 1999-03-01 |
| EP0629684B1 (en) | 1999-01-07 |
| US5403366A (en) | 1995-04-04 |
| CA2124147A1 (en) | 1994-12-18 |
| KR100317107B1 (ko) | 2002-06-20 |
| CN1037956C (zh) | 1998-04-08 |
| DE69415728T2 (de) | 1999-06-10 |
| EP0629684A1 (en) | 1994-12-21 |
| DE69415728D1 (de) | 1999-02-18 |
| CA2124147C (en) | 2005-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR950000841A (ko) | 정제된 고온 가스 제조를 위한 부분 산화방법 | |
| KR950000842A (ko) | 정제된 고온 가스 제조를 위한 부분 산화방법 | |
| US4057510A (en) | Production of nitrogen rich gas mixtures | |
| US5958365A (en) | Method of producing hydrogen from heavy crude oil using solvent deasphalting and partial oxidation methods | |
| US7004985B2 (en) | Recycle of hydrogen from hydroprocessing purge gas | |
| US6448441B1 (en) | Gasification process for ammonia/urea production | |
| US3928000A (en) | Production of a clean methane-rich fuel gas from high-sulfur containing hydrocarbonaceous materials | |
| KR100209982B1 (ko) | 고순도 수소의 제조 방법 | |
| EP2737031B1 (en) | Process for the gasification of heavy residual oil with particulate coke from a delayed coking unit | |
| US3252774A (en) | Production of hydrogen-containing gases | |
| EP0290689A1 (en) | Partial oxidation process | |
| US6613125B1 (en) | Utilization of membranes and expander/compressors in gasification | |
| KR950000839A (ko) | 숯 제조장치 | |
| KR20080047604A (ko) | 열 크래킹법 | |
| US3927998A (en) | Production of methane-rich gas stream | |
| US3927999A (en) | Methane-rich gas process | |
| US3928001A (en) | Production of methane | |
| GB1572071A (en) | Production of purified synthesis gas and carbon monoxide | |
| US4218326A (en) | Production of nitrogen-rich gas mixtures | |
| CA2791874A1 (en) | Systems and methods that integrate a sulphur cycle into a hydrocarbon refinement process to exploit petroleum coke, and related systems and methods of transporting and storing sulphur and carbon dioxide by-products | |
| CA1049049A (en) | Process for the preparation of hydrocarbons | |
| CA1041765A (en) | Reducing gas generation | |
| CA1044894A (en) | Substitute fuel gas generation | |
| US3236763A (en) | Cracking of hydrocarbons | |
| CA1204285A (en) | Production of synthesis gas from heavy hydrocarbon fuels containing high metal concentrations |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20061120 Year of fee payment: 6 |
|
| LAPS | Lapse due to unpaid annual fee |