KR940019629A - 피복장치, 유리의 피복방법, 유리 피복용 화합물 및 조성물, 및 피복된 유리기재 - Google Patents

피복장치, 유리의 피복방법, 유리 피복용 화합물 및 조성물, 및 피복된 유리기재 Download PDF

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KR940019629A
KR940019629A KR1019940002624A KR19940002624A KR940019629A KR 940019629 A KR940019629 A KR 940019629A KR 1019940002624 A KR1019940002624 A KR 1019940002624A KR 19940002624 A KR19940002624 A KR 19940002624A KR 940019629 A KR940019629 A KR 940019629A
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substituted
vapor
coating composition
coating
substrate
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KR970001212B1 (ko
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루자코우스키 아데이 페트리시아
사무엘 도슨 더글라스
에밀 레콕크 데이비드
앤드류 뉴만 죠지
프랭크 솝코 죤
린 스테와트-데이비스 로얀
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조 안 벤틀레이 액스톤
피피지 인더스트리즈, 인코포레이티드
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Abstract

본 발명은 상기한 거리로 피복 소단위장치의 각 측면위에 배기수단을 갖는 유리 리본 피복용 장치에 관한 것이다. 이러한 배열에 있어서, 피복 소단위 장치중의 리본 상부 및 하부는 상이한 시간동안 피복 소단위 장치로부터 피복 증기에 노출되어 있다. 피복 혼합물은 주석-함유 전구물질과 규소-함유 전구물질을 포함한다. 규소-함유 전구물질은 하기 일반식을 갖는다 :
상기식에서, R1은 과산화 결합을 형성하는데 사용할 수 있는 산소를 갖지 않는 그룹이고, R2는 산화규소 피복재로 쉽게 전환되는 능력을 규소-함유 전구물질을 제공하는 작용기이고, R3는다수의 규소 원자를 갖는 분자를 생성하는 가교 그룹이고, R4는 결합 구조를 완결한다.
촉진제, 예를들어 인-함유 전구물질은 피복재의 증착 속도를 증가시키기 위해 금속-함유 전구물질과 함께 사용할 수도 있다. 유리상에 증착된 피복재는 유리-피복재 계면으로부터의 거리가 증가함에 따라 산화 규소 및 산화주석의 중량%가 계속 변하는 영역을 가지며, 유리-피복재 계면으로부터 가장 먼 피복재의 표면은 주로 산화주석이가. 피복재내의 영역들은 바깥쪽 피복 표면에서 산화주석의 두께가 증가함에 따라 무지개 빛깔을 제거하고 피복유리 제품에 중간 색상을 제공하기 위해 상이한 굴절률을 피복재에 제공한다. 촉진제로서 인을 사용하는 경우, 결정도(%)가 감소하여 0에 근접하고, 따라서 피복재의 흐림현상이 감소하거나 제거된다.

Description

피복장치, 유리의 피보방법, 유리 피복용 화합물 및 조성물, 및 피복된 유리기재
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 특징이 혼입되고 본 발명의 장치, 방법 및 피복재를 사용하여 수득한 피복 기재를 도시한 것이다.
제3도는 본 발명의 특징이 혼입된 하나의 피복 영역을 갖는 피복 장치의 제2도의 입면도와 유사한 입면도이다.
제4도는 본 발명의 교시에 따라 증착된 구배(gradient) 피복재 및 확장되고 개선된 구배 피복재를 도시한 그래프이다.

Claims (38)

  1. 증기상 피복 조성물을 기재 표면상의 제1예정된 위치로 배향시키는 단계 : 증기의 제1부분을 제1방향으로 기재 표면의 제1영역을 따라, 및 증기의 제2부분을 제1방향과 반대되는 제2방향으로 기재 표면의 제2영역을 따라 이동시키는 단계 : 기재를 피복하기 위해, 증기의 제2부분이 기재표면의 제2영역상에 유지되어 있는 시간보다 더 긴 시간동안 피복 조성물의 제1부분을 기재 표면의 제1영역상에 유지시키는 단계를 포함하는, 기재-피복재 계면으로 부터의 거리가 증가함에 따라 화학 조성이 연속적으로 변하는 피복재를 제공하기 위한 이동 기재의 피복방법.
  2. 제1항에 있어서, 상기 증기상 피복 조성물이 2개이상의 금속-함유 전구물질을 갖는방법.
  3. 제2항에 있어서, 상기 기재가 유리 기재인 방법.
  4. 제3항에 있어서, 상기 금속-함유 전구물질중의 하나가 주석, 티탄, 텅스텐 및 안티몬으로 이루어진 그룹중에서 선택되는 방법.
  5. 제2항에 있어서, 상기 제1예정된 위치의 한 측면에서 위로 이격되어 있는 제2예정된 위치, 및 제2예정된 위치가 제1예정된 위치와 제3예정된 위치사이에 있게 되도록 제1 및 제2예정된 위치에서 위로 이격되어 있는 제3예정된 위치에서 상기 배향 단계를 수행함을 또한 포함하는 방법.
  6. 제5항에 있어서, 상기 기재를 비-산화 대기를 갖는 챔버내에서 피복시키고, 비-산화 대기가 예정된 위치로 이동하지 모사도록 불활성가스의 커텐(curtain)(여기에서, 불활성 가스의 커텐과 상기 예정된 위치는 피복위치를 한정한다)을 제공함을 또한 포함하는 방법.
  7. 제6항에 있어서, 상기 챔버가 산화가능한 용융 금속의 욕을 함유하고, 상기 기재가 용융 금속위에 지지되고 챔버를 거쳐 피복위치를 통해 진행되는 유리 리본인 방법.
  8. 제2항에 있어서, 상기 유지 단계를, 하나의 배기 수단이 제1예정된 위치로부터 “x”거리로 이격되어 있으며 다른 배기수단이 상기 제1예정된 위치로부터 “y”거리로 이격되어 있고 추가로 x/y의 비가 1이상인 배기 수단들을 상기 제1예정된 위치의 각 측면상에 제공함으로써 수행하는 방법.
  9. 제3항에 있어서, 상기 금속-함유 전구물질중의 하나가 하나이사의 규소-산소 결합을 함유하는 규소-함유 전구물질인 방법.
  10. 제9항에 있어서, 상기 배향단계가 유리 기재상에서의 산화규소의 피복 증착 속도를 증가시키기 위한 촉진제와 규소-함유 전구물질을 혼합함을 포함하는 방법.
  11. 제2항에 있어서, 하나이상의 금속-함유 전구물질이 규소-함유 전구물질인 방법.
  12. 증기를 유리 표면으로 배향시키는 수단 : 상기 증기 배향 수단으로부터 이격되어 그의 한 측면상에 있는 제1배기수단 : 상기 증기 배향 수단으로부터 이격되어 그의 다른 측면사에 있으며 상기 증기 배향 수단 및 상기 제1배기수단과 일렬로 배열딘 제2배기수단 : 및 상기 제1배기수단과 상기 증기 배향 수단사이의 거리가 “x”로 한정되고 상기 제2배기수단과 상기 증기 배향 수단사이의 거리가 “y”로 한정(여기에서, “x”와 “y”의 값은 다르다) 되도록 상기 제1배기수단, 제2배기수단 및 상기 배향수단을 서로 관련하여 위치시키는 수단을 포함하는 피복장치.
  13. 제12항에 있어서, x/y의 비가 약 1.2 내지 약 50의 범위인 피복장치.
  14. 증기를 기재로 배향시키기 위한 노즐(이 노즐은 개구부를 갖고 있다)을 포함하는 수단 : 상기 증기 배향 수단으로부터 이격되어 그의 한 측면위에 있는, 개구부를 갖는 제1배기수단 : 상기 증기 배향 수단으로부터 이격되어 그의 다른 측면위에 있으며 상기 증기 배향 수단과 일렬로 배열된, 개구부를 갖는 제2배기수단 : 및 상기 증기 배향수단의 상기 개구부와 상기 제1배기수단의 상기 개구부의 표면이 상기 제2배기수단의 개구부와 기재사이의 이격 거리와 다른 이격거리로 있게 되도록 상기 제1배기수단, 제2배기수단 및 상기 증기 배향 수단을 기재표면과 관련하여 위치시키는 수단을 포함하는 피복장치.
  15. 증기를 기재로 배향시키기 위한 수단 : 상기 증기 배향 수단으로부터 이격되어 그의 하 측면위에 있는 제1배기수단 : 상기 증기 배향 수단으로부터 이격되어 그의 다른 측면위에 있으며 상기 증기 배향 수단 및 상기 제1배기수다과 일렬로 배열된 제2배기수단 : 및 상기 증기 배향 수단의 수용 유량이 상기 배기 수단중 적어도 하나의 수용 유량과 다르게 하도록 사익 증기 배향 수단과 제1 및 제2배기 수단의 수용 유량을 조절하는 수단을 포함하는 피복장치.
  16. 하나이상의 혼합된 산화 금속(이 혼합된 산화금속 자체는 인, 알루미늄 및 붕소를 포함하지 않는다)으로 이루어진 피복재를 위에 가지며, 인, 알루미늄 및 붕소로 이루어진 그룹중에서 선택된 원소가 완전히 분산되어 있는 기재.
  17. 산화 금속의 고정비를 갖는 층이 거의 없으므로 연속적으로 변하는 산화 금속비의 영역을 피복재중에 갖는 혼합된 산화금속들로 이루어진 피복재를 위에 가지며, 인, 알루미늄 및 붕소로 이루어진 그룹중에서 선택된 원소가 완전히 분산되어 있는 기재.
  18. 제17항에 있어서, 상기 기재가 유리하고, 혼합된 산화금속이 산화 규소 및 산화주석이고, 이때 유리-피복재 계면에서 70 내지 100중량%가 산화 규소이고 대향되는 피복표면에서 70 내지 100중량%가 산화주석이고, 분산되어 있는 원소가 있는기재.
  19. 하기 일반식으로 정의되는 금속-함유 전구물질을 갖는 피복조성물 :
    상기식에서, R1은 과산화 결합을 형성하는데 사용할 수 있는 산소를 갖지 않는 그룹이고, R2는 산화규소 피복재로 쉽게 전환되는 능력을 규소-함유 전구물질에 제공하는 작용기이고, R3는 다수의 규소 원자를 갖는 분자를 생성하는 가교 그룹이고, R4는 결합 구조를 완결한다.
  20. 제19항에 있어서, R1이 C1내지 1010의 알킬 또는 치환된 알킬 라디칼 : C2내지 1010의 알케닐 또는 치환된 알케닐 라디칼 : C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼 : 및 C6내지 C11의 아릴, 아르알킬, 치환된 아릴 또는 치환된 아르알킬 라디칼로 이루어진 그룹중에서 선택된 피복 조성물.
  21. 제19항에 있어서, R2가 수소 : 할로겐 : C2내지 C10의 알케닐 또는 치환된 알케닐 라디칼 : C1내지 C10의 α-할로겐화 알킬 또는 과할로겐화 알킬 라디칼 및 치환된 유도체 : 및 C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼로 이루어진 그룹중에서 선택된 피복 조성물.
  22. 제21항에 있어서, R2와 규소 원자사이의 결합이 열에 의해 쉽게 파괴되는 피복 조성물.
  23. 제19항에 있어서, R3가(여기에서, R5는 C1내지 C10의 알킬 또는 치환된 알킬 라디칼이다) :(여기에서, R5는 상기 정의된 바와같다) :(여기에서, n은 1 내지 10이다)로 이루어진 그룹중에서 선택된 피복 조성물.
  24. 제19항에 있어서, R4가 C1내지 C10의 알킬 또는 치환된 알킬 라디칼 : C2내지 1010의 알케닐 또는 치환된 알케닐 라디칼 : C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼 : 및 C6내지 C11의 아릴, 아르알킬, 치환된 아릴 또는 치환된 아르알킬 라디칼로 이루어진 그룹중에서 선택된 피복 조성물.
  25. 제19항에 있어서, R4가 수소 : 할로겐 : C2내지 C19의 알케닐 또는 치환된 알케닐 라디칼 : C1내지 C10의 α-할로겐화 알킬 또는 과할로겐화 알킬 라디칼 및 치환된 유도체 : 및 C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼로 이루어진 그룹중에서 선택된 피복 조성물.
  26. 제19항에 있어서, R4가 C1내지 C10의 알콕사이드 또는 치환된 알콕사이드 라이칼 : C1내지 C10의 알킬 또는 치환된 알킬 라디칼 : -CN : -OCN : 및 포스핀, 알킬포스핀 및 디알킬포스핀(여기에서, 알킬 라디칼은 1 내지 10개의 탄소원자를 갖는다)을 이루어진 그룹중에서 선택된 피복 조성물.
  27. 제19항에 있어서, 상기 화합물이 테트라메틸사이클로테트라실록산, 테트라메틸디실릭산 및 트리에톡시실란으로 이루어진 그룹중에서 선택된 피복 조성물.
  28. 제19항에 있어서, 산화규소의 증착 속도를 증가시키기 위한 촉진제를 또한 포함하는 피복 조성물.
  29. 제28항에 있어서, 상기 촉진제가 루이스 산인 피복 조성물.
  30. 제28항에 있어서, 상기 촉진제가 루이스 염기인 피복 조성물.
  31. 제28항에 있어서, 상기 촉진제가 트리에틸포스파이트인 피복 조성물.
  32. 제19항에 있어서, 제2금속-함유 전구물질을 또한 포함하는 피복 조성물.
  33. 약 750℉ 내지 약 1500℉(400℃ 내지 815℃)의 온도에서 상응하는 산화규소로 전환될 수 있는 구조식의 규소-함유 전구물질, 상응하는 산화금속으로 전화될 수 있는 금속-함유 전구물질, 및 촉진제를 포함하는 증기상 피복 조성물.
  34. 제33항에 있어서,결합이, R1이 Cx내지 C10의 알킬 또는 치환된 알킬 라디칼 : C1내지 C10, 바람직하게는 C1내지 C4의 할로겐화 알킬 라디칼, 예를 들어 -CCl3, -CH2CHClCH3및 -CH2CCl2CCl3: C2내지 C10의 알케닐 또는 치환된 알케닐 라디칼 : C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼 : 및 C6내지 C11의 아릴, 아르알킬, 치환된 아릴 또는 치환된 아르알킬 라디칼로 이루어진 그룹중에서 선택된R1인 피복 조성물.
  35. 제34항에 있어서,R1결합이 R2가 수소 : 할로겐 : C2내지 C10의 알케닐 또는 치환된 알케닐 라디칼 : C1내지 C10의 α-할로겐화 알킬, 과할로겐화 알킬 라디칼 및 치환된 유도체 : 및 C2내지 C10의 알키닐 또는 치환된 알키닐 라디칼로 이루어진 그룹중에서 선택된인 피복 조성물.
  36. 제35항에 있어서,결합이 R3가 -S- :(여기에서, R5는 C1내지 C10의 알킬 또는 치환된 알킬 라디칼이다)(여기에서, n은 1 내지 10이다)로 이루어진 그룹중에서 선택된인 피복 조성물.
  37. 제36항에 있어서,결합이 R4가 C1내지 C10의 알콕사이드 또는 치환된 알콕사이드 라디칼 : C1내지 C10의 알킬 또는 치환된 알킬 라디칼 : -CN : -OCN : 및 포스핀, 알킬포스핀 및 디알킬포스핀(여기에서 알킬 라디칼은 1 내지 10개의 탄소원자를 갖는다)으로 이루어진인 피복 조성물.
  38. 제33항에 있어서,상기 촉진제가 트리에틸포스파이트, 트리메틸포스파이트, 트리메틸보레이트, PF5, PCl3, PBr3, PCl5, BCl3, BF3, (CH3)2BBr, SF4및 HO3SF로 이루어진 그룹중에서 선택된 피복 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940002624A 1993-02-16 1994-02-15 피복장치, 유리의 피복방법, 유리 피복용 화합물 및 조성물 및 피복된 유리 기재 KR970001212B1 (ko)

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FI940451A (fi) 1994-08-17
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CN1196655C (zh) 2005-04-13
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TW325457B (en) 1998-01-21
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