KR940014703A - 기능화 다단 중합체들 - Google Patents

기능화 다단 중합체들 Download PDF

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KR940014703A
KR940014703A KR1019930001091A KR930001091A KR940014703A KR 940014703 A KR940014703 A KR 940014703A KR 1019930001091 A KR1019930001091 A KR 1019930001091A KR 930001091 A KR930001091 A KR 930001091A KR 940014703 A KR940014703 A KR 940014703A
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polymer
stage polymer
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radiation
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하버그 울퍼스버거 마샤
제임즈 쉰들러 프레드릭
윌리엄 노박 로날드
스코트 베클리 로날드
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윌리엄 이. 램버트 3세
롬 앤드 하스 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/02—Alkylation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

본 발명은 수성, 방사선-경화가능한, 기능한 라텍스 중합체 조성물 및 그 제조에 관한 것이다. 본 조성물은 제1단 중합체 및 α, β-불포화 카르보닐 기능기를 가지며 UV방사선에 의한 경화를 가능케하여주는 제2단 중합체로 부터 형성된 다단 라텍스 중합체이다. 최종 경화돈 UV코팅을 우수한 내용매성, 내수성, 스테인내성, 직접 충격 내성 및 고온 프린트 내성을 갖는다. 본 조성물은 도료, 접착제, 잉크 및 피혁코팅에 유용하며, 특히 목재에 대한 코팅으로서 유용하다. 본 발명의 방사선-경화가능한 다단 중합체는 (a)(1)제1단 중합체, 및 (2)산 기능기를 포함하는 최소한 하나의 공단량체를 함유하는 제2단 중합체를 다단 중합체를 형성하고;(b)상기 다단 중합체의 제2단 중합체의 상기 산 기능기를 염기와 함께 부분 중화시키고; (c)부분 중화된 산 기능기를 갖는 상기 다단 중합체를 모노에틸렌계 불포화 에폭시드 화합물과 함께 반응시킴에 의하여 제조된다.

Description

기능화 다단 중합체들
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. (a)제1단 중합체; 및 (a)α,β-불포화 카르보닐 기능기를 갖는 제2단 중합체를 포함하며, 상기 제1단 중합체와 상기 제2단 중합체의 중량비가 20:80 내지 70:30인, 방사선-경화가능한 라텍스 중합체 조성물.
  2. 제1항에 있어서, 상기 제1단 중합체와 상기 제2단 중합체의 중량비가 30:70 내지 50:50인 방사선-경화가능한 라텍스 중합체 조성물.
  3. 제1항에 있어서, 상기 제2단 중합체가 (메트)아크릴레이트 기능기를 포함하는 것인 방사선-경화가능한 라텍스 중합체 조성물.
  4. 제1항에 있어서, 상기 제1단 중합체가 그 제1단 중합체의 10wt%이하의 최소한 하나의 교차결합성 공단량체를 포함하는 것인 방사선-경화가능한 라텍스 중합체 조성물.
  5. 제4항에 있어서, 상기 제1단 중합체가 1-5wt%의 최소한 하나의 교차결합성 공단량체를 포함하는 것인 방사선-경화가능한 라텍스 중합체 조성물.
  6. 제4항에 있어서, 상기 교차결합성 공단량체가 알릴 메타크릴레이트인 것인 방사선-경화가능한 라텍스 중합체 조성물.
  7. (a)제1단 중합체; 및 (2)산 기능기를 포함하는 최소한 하나의 공단량체를 함유하는 제2단 중합체를 갖는 다단 중합체를 형성하고; (b)상기 다단 중합체의 제2단 중합체의 상기 산 기능기를 염기와 함께 부분 중화시키고;(c)부분 중화된 산 기능기를 갖는 상기 다단 중합체를 모노 에틸렌계 불포화 에폭시드 화합물과 함께 반응시키는 것을 특징으로 하는 하는, 방사선-경화가능한 다단 중합체의 제조방법.
  8. 제7항에 있어서, 부분 중화된 산 기능기를 갖는 상기 다단 중합체가 모노에틸렌계 불포화 에폭시드 화합물과 함께 반응되기 전에 4차 암모늄 상전이 촉매(phase transfer catalyst)가 첨가되는 것인 방법.
  9. (a)물; 및 (b)(1)제1단 중합체, 및 (2)α,β-불포화 카르보닐 기능기를 갖는 제2단 중합체를 포함하며, 상기 제1단 중합체와 상기 제2단 중합체의 중량비가 20:80 내지 70:30인, 방사선-경화가능한 라텍스 중합체를 함유하는 도료 조성물.
  10. 제9항에 있어서, 개시제를 함유하는 도료 조성물.
  11. 제9항에 있어서, 상기 제1단 중합체와 상기 제2단 중합체의 중량비가 30:70 내지 50:50인 도료 조성물.
  12. 제9항에 있어서, 상기 제2단 중합체가 (메트)아크릴레이트 기능기를 포함하는 것인 도료 조성물.
  13. 제9항에 있어서, 상기 제1단 중합체가 그 제1단 중합체의 10wt%이하의 최소한 하나의 교차결합성 공단량체를 포함하는 것인 도료 조성물.
  14. 제13항에 있어서, 상기 제1단 중합체가 1-5wt%의 최소한 하나의 교차결합성 공단량체를 포함하는 것인 도료 조성물.
  15. 제13항에 있어서, 상기 교차 결합성 공단량체가 알릴메타크릴레이트인 것인 도료 조성물.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019930001091A 1992-12-18 1993-01-28 기능화 다단 중합체들 KR940014703A (ko)

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US07/993,161 US5306744A (en) 1992-12-18 1992-12-18 Functionalized multistage polymers
US993.161 1992-12-18

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US (2) US5306744A (ko)
EP (1) EP0602763B1 (ko)
JP (1) JPH06211950A (ko)
KR (1) KR940014703A (ko)
CN (3) CN1045615C (ko)
AT (1) ATE159267T1 (ko)
AU (1) AU670561B2 (ko)
BR (1) BR9300471A (ko)
CA (1) CA2087570A1 (ko)
CZ (1) CZ17093A3 (ko)
DE (1) DE69314609T2 (ko)
ES (1) ES2107617T3 (ko)
FI (1) FI930559A (ko)
HK (1) HK1001497A1 (ko)
HU (1) HUT66368A (ko)
IL (1) IL104680A (ko)
MX (1) MX9300459A (ko)
NO (1) NO930420L (ko)
NZ (1) NZ245867A (ko)
PL (1) PL297753A1 (ko)
RU (1) RU2126428C1 (ko)
SI (1) SI9300072A (ko)
SK (1) SK7793A3 (ko)
TW (1) TW216437B (ko)
ZA (1) ZA931024B (ko)

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BR9300471A (pt) 1994-06-28
IL104680A0 (en) 1993-06-10
ATE159267T1 (de) 1997-11-15
US5306744A (en) 1994-04-26
TW216437B (en) 1993-11-21
CN1045615C (zh) 1999-10-13
AU670561B2 (en) 1996-07-25
RU2126428C1 (ru) 1999-02-20
JPH06211950A (ja) 1994-08-02
DE69314609D1 (de) 1997-11-20
NO930420L (no) 1994-06-20
CA2087570A1 (en) 1994-06-19
CN1203248A (zh) 1998-12-30
EP0602763A1 (en) 1994-06-22
HU9300314D0 (en) 1993-05-28
SK7793A3 (en) 1994-07-06
HUT66368A (en) 1994-11-28
ZA931024B (en) 1996-01-25
US5409971A (en) 1995-04-25
AU3293693A (en) 1994-07-07
EP0602763B1 (en) 1997-10-15
CN1226588A (zh) 1999-08-25
FI930559A (fi) 1994-06-19
FI930559A0 (fi) 1993-02-09
ES2107617T3 (es) 1997-12-01
NO930420D0 (no) 1993-02-08
NZ245867A (en) 1996-02-27
HK1001497A1 (en) 1998-06-19
CZ17093A3 (en) 1994-07-13
CN1088230A (zh) 1994-06-22
SI9300072A (en) 1994-06-30
DE69314609T2 (de) 1998-04-09
MX9300459A (es) 1994-06-30
IL104680A (en) 1996-11-14
PL297753A1 (en) 1994-06-27

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