KR930002404A - 폴리우레탄 분산액 - Google Patents
폴리우레탄 분산액 Download PDFInfo
- Publication number
- KR930002404A KR930002404A KR1019920011819A KR920011819A KR930002404A KR 930002404 A KR930002404 A KR 930002404A KR 1019920011819 A KR1019920011819 A KR 1019920011819A KR 920011819 A KR920011819 A KR 920011819A KR 930002404 A KR930002404 A KR 930002404A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- polyhydroxy
- polyurethane
- groups
- polymerization
- Prior art date
Links
- 229920003009 polyurethane dispersion Polymers 0.000 title claims 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 11
- 239000000178 monomer Substances 0.000 claims 10
- 239000002253 acid Substances 0.000 claims 9
- 229920002635 polyurethane Polymers 0.000 claims 8
- 239000004814 polyurethane Substances 0.000 claims 8
- 238000006116 polymerization reaction Methods 0.000 claims 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims 5
- 229920000515 polycarbonate Polymers 0.000 claims 5
- 239000004417 polycarbonate Substances 0.000 claims 5
- 229920000728 polyester Polymers 0.000 claims 5
- 229920000570 polyether Polymers 0.000 claims 5
- 125000000542 sulfonic acid group Chemical group 0.000 claims 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
- 229920001228 polyisocyanate Polymers 0.000 claims 4
- 239000005056 polyisocyanate Substances 0.000 claims 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical group CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 3
- 150000003254 radicals Chemical class 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000003973 paint Substances 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 239000000976 ink Substances 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 238000010526 radical polymerization reaction Methods 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/04—Polymeric products of isocyanates or isothiocyanates with vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/6705—Unsaturated polymers not provided for in the groups C08G18/671, C08G18/6795, C08G18/68 or C08G18/69
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 카복실산, 포스폰산 또는 설폰산 그룹 및 측면 비닐 그룹 및 임의로는 말단 비닐, 하이드록실, 우레탄, 티오 우레탄 및/또는 우레아 그룹을 함유하는 폴리우레탄 마크로모노머(macromonomer)의 유리 라디칼에 의해 개시되는 중합에 의해 제조된 폴리우레탄 분산액.
- 제1항에 있어서, 폴리하이드록시-폴리에테르, 폴리하이드록시-폴리에스테르 또는 폴리하이드록시-폴리카보네이트 및 폴리하이드록시카복실산, 폴리하이드록시포스폰산 또는 폴리하이드록시설폰산과 폴리이소시아네이트 및 2개 이상의 하이드록실 그룹 및 1개 이상의 비닐 그룹을 함유하는 단량체와의 증부가에 의해 수죽한 카복실산, 포스폰산 또는 설론산 그룹 및 말단 하이드록실 그룹 및 측면 비닐 그룹을 함유하는 폴리우레탄 마크로모노머의 중합에 의해 제조된 폴리우레탄 분산액.
- 제1항에 있어서, 폴리하이드록시-폴리에테르, 폴리하이드록시-폴리에스테르 및 폴리하이드록시-폴리카보네이트 및 폴리하이드록시카복실산, 폴리하이드록시포스폰산 또는 폴리하이드록시설폰산과 폴리하이드록시 폴리이소시아네이트 및 2개 이상의 하이드록실 그룹 및 1개 이상의 비닐 그룹을 함유하는 단량체를 증부가시켜 이소시아네이트 및카복실산, 포스폰산 또는 설폰산 그룹 및 측면 비닐 그룸을 함유하는 마크로모노머를 형성시키고 이렇게 하여 수득한 마크로모노머를 아민, 알콜 또는 티오알콜과 반응시켜 수득한 폴리우레탄 마크로모노머의 중합에 의해 제조된 폴리우레탄 분삭액.
- 제1항에 있어서, 폴리하이드록시-폴리에테르, 폴리하이드록시-폴리에스테르 또는 폴리하이드록시-폴리카보네이트 및 폴리하이드록시카복실산, 폴리하이드록시포스폰산 또는 폴리하이드록시설폰산과 폴리이소시아네이트 및 2개 이상의 하이드록실 그룹 및 1개 이상의 비닐 그룹을 함유하는 단량체를 증부가시키고 후속적으로 1개 이상의 비닐 그룹 외에 이소시아네이트 그룹과 반응하는 그룹을 함유하는 단량체를, 임의로는 1급 또는 2급 아민, 알콜 또는 티오알콜과 함께 반응시켜 수득한, 카복실산, 포스폰산 또는 설폰산 그룹 및 말단 및 측면 비닐 그룹 및 임의로는 우레탄, 티오우레탄 또는 우레아 그룹을 함유하는 폴리우레탄 마크로모노머의 중합에 의해 제조된 폴리우레탄 분산액.
- 제1항에 있어서, 폴리하이드록시-폴리에테르, 폴리하이드록시-폴리에스테르 또는 폴리하이드록시-폴리카보네이트 및 폴리이소시아네이트 및 2개 이상의 하이드록실 그룹 및 1개 이상의 비닐 그룹을 함유하는 단량체를 증부가시켜 이소시아네이트 그룹및 측면 비닐 그룹을 함유하는 마크로모노머를 형성시키고 이렇게 하여 수득한 마크로모노모럴 아미노카복실산, 아미노설폰산, 하이드록시카복실산 또는 하이드록시설폰산과 반응시켜 수득한 폴리우레탄 마크로모노머의 중합에 의해 제조된 폴리우레탄 분산액.
- 제1항에 있어서, 폴리하이드록시-폴리에테르, 폴리하이드록시-폴리에스테르 또는 폴리하이드록시-폴리카보네이트가 카복실산, 포스폰산 또는 설폰산 그룹을 함유하는 폴리우레탄 분산액.
- 제1항에 있어서, 용매로서 작용하며 폴리우레탄 마크로 모노머와 공중합할 수 있는 불포화 단량체중에서, 경우에 따라 추가의 공중합할 수 있는 불포화 단량체의 존재하에, 유리 라디칼에 의해 개시되는 중합에 의해 제조된 폴리우레탄 분산액.
- 제1항에 있어서, 물과 이소시아네이트 그룹에 대해 불활성인 유기 용매와의 혼합물중에서, 경우에 따라 폴리우레탄 마크로모노머와 공중합할 수 있는 불포화 단량체의 존재하에, 경우에 따라 유리 라디칼 중합 전 또는 후에 증류에 의해 유기 용매를 제거하여, 유리 라디칼에 의해 개시되는 중합에 의해 제조된 폴리우레탄 분산액.
- 기재상 피복물의 제조를 위한 또는 접착제로서의 또는 인쇄 잉크에 있어서의 결합제로서의 제1항에 따른 폴리우레탄 분산액의 용도.
- 페인트의 다중-피복 부착층에 있어서 금속 및 고체 염기 페인트를 제조하기 위한 제1항에 따른 폴리우레탄 분산액의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4122265A DE4122265A1 (de) | 1991-07-05 | 1991-07-05 | Polyurethan-dispersionen |
DEP4122265.2 | 1991-07-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930002404A true KR930002404A (ko) | 1993-02-23 |
KR100248684B1 KR100248684B1 (ko) | 2000-04-01 |
Family
ID=6435494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920011819A KR100248684B1 (ko) | 1991-07-05 | 1992-07-03 | 폴리우레탄 분산액 |
Country Status (14)
Country | Link |
---|---|
US (1) | US5691425A (ko) |
EP (1) | EP0522419B1 (ko) |
JP (1) | JP3334908B2 (ko) |
KR (1) | KR100248684B1 (ko) |
AT (1) | ATE138403T1 (ko) |
AU (1) | AU656981B2 (ko) |
BR (1) | BR9202601A (ko) |
CA (1) | CA2073081C (ko) |
CZ (1) | CZ287575B6 (ko) |
DE (2) | DE4122265A1 (ko) |
DK (1) | DK0522419T3 (ko) |
ES (1) | ES2089299T3 (ko) |
MX (1) | MX9203953A (ko) |
NO (1) | NO301645B1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR980002330A (ko) * | 1996-06-29 | 1998-03-30 | 이중열 | 샷틀레스직기의 위사 연속공급장치 |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4336206A1 (de) * | 1993-10-23 | 1995-04-27 | Hoechst Ag | Wäßrige selbstvernetzende Polyurethan-Vinyl-Hybrid-Dispersionen |
DE4339085C1 (de) † | 1993-11-16 | 1995-05-24 | Herberts Gmbh | Physikalisch trocknende Überzugsmittel auf wäßriger Basis und deren Verwendung |
DE4344063C1 (de) * | 1993-12-23 | 1995-06-08 | Herberts Gmbh | Wäßrige Bindemitteldispersion für physikalisch trocknende Überzugsmittel und deren Verwendung |
US5824733A (en) * | 1994-04-30 | 1998-10-20 | Wacker-Chemie Gmbh | Aqueous coating product and a process for producing multiple layer paint coatings whose perceived color varies with the angle from which they are viewed |
DE4435950A1 (de) | 1994-10-07 | 1996-04-11 | Hoechst Ag | Copolymerisate mit cyclischen oder polycyclischen Monomeren mit einer speziellen Isomerenverteilung und deren Einsatz in Beschichtungsmitteln |
JPH09157342A (ja) * | 1995-12-07 | 1997-06-17 | Nof Corp | ポリウレタン樹脂の水系分散物、ポリウレタン樹脂グラフト重合体の水系分散物および水系塗料組成物 |
JPH09165425A (ja) * | 1995-12-18 | 1997-06-24 | Toyo Ink Mfg Co Ltd | 水性ウレタン化合物の製造方法 |
DE19602040A1 (de) * | 1996-01-20 | 1997-07-24 | Herberts Gmbh | Wäßrige Polymer/Polyurethan-Harz-Bindemitteldispersion, deren Herstellung, Überzugsmittel und Verwendung |
DE19613685C1 (de) * | 1996-04-05 | 1997-09-11 | Herberts Gmbh | Säurefreie Katalysatorpaste, deren Herstellung und Verwendung bei der kathodischen Elektrotauchlackierung |
JP3790908B2 (ja) * | 1996-09-03 | 2006-06-28 | 大日本インキ化学工業株式会社 | 湿気硬化型ウレタンプライマー組成物及びその被覆方法 |
DE19643802A1 (de) * | 1996-10-30 | 1998-05-07 | Herberts Gmbh | Wäßrige Bindemitteldispersion für physikalisch trocknende Überzugsmittel und deren Verwendung |
US6069217A (en) * | 1997-03-07 | 2000-05-30 | Rheox, Inc. | Urethane-acrylic copolymer thickening compositions for aqueous systems |
DE19722862C1 (de) * | 1997-05-31 | 1999-01-14 | Basf Coatings Ag | Wäßriger Lack und dessen Verwendung zur Herstellung einer zweischichtigen Lackierung |
DE19728411C2 (de) | 1997-07-03 | 2001-09-27 | Basf Coatings Ag | Polyurethanharz, Verfahren zu seiner Herstellung und seine Verwendung in wäßrigen Zweikomponenten-Klarlacken |
DE19750451A1 (de) * | 1997-11-14 | 1999-05-27 | Herberts & Co Gmbh | Verfahren zur Herstellung von Mehrschichtlackierungen |
DE19753222A1 (de) * | 1997-12-01 | 1999-06-02 | Bayer Ag | Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen |
US6136890A (en) * | 1998-02-17 | 2000-10-24 | 3M Innovative Properties Company | Ink jet ink containing polyurethane dispersant |
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-
1991
- 1991-07-05 DE DE4122265A patent/DE4122265A1/de not_active Withdrawn
-
1992
- 1992-06-30 AT AT92111066T patent/ATE138403T1/de not_active IP Right Cessation
- 1992-06-30 DK DK92111066.4T patent/DK0522419T3/da active
- 1992-06-30 EP EP92111066A patent/EP0522419B1/de not_active Expired - Lifetime
- 1992-06-30 ES ES92111066T patent/ES2089299T3/es not_active Expired - Lifetime
- 1992-06-30 DE DE59206340T patent/DE59206340D1/de not_active Expired - Lifetime
- 1992-07-02 US US07/908,318 patent/US5691425A/en not_active Expired - Lifetime
- 1992-07-03 KR KR1019920011819A patent/KR100248684B1/ko not_active IP Right Cessation
- 1992-07-03 BR BR929202601A patent/BR9202601A/pt not_active IP Right Cessation
- 1992-07-03 CZ CS19922094A patent/CZ287575B6/cs not_active IP Right Cessation
- 1992-07-03 MX MX9203953A patent/MX9203953A/es not_active IP Right Cessation
- 1992-07-03 JP JP17723192A patent/JP3334908B2/ja not_active Ceased
- 1992-07-03 AU AU19391/92A patent/AU656981B2/en not_active Ceased
- 1992-07-03 CA CA002073081A patent/CA2073081C/en not_active Expired - Fee Related
- 1992-07-03 NO NO922643A patent/NO301645B1/no not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR980002330A (ko) * | 1996-06-29 | 1998-03-30 | 이중열 | 샷틀레스직기의 위사 연속공급장치 |
Also Published As
Publication number | Publication date |
---|---|
BR9202601A (pt) | 1993-03-16 |
EP0522419A1 (de) | 1993-01-13 |
KR100248684B1 (ko) | 2000-04-01 |
US5691425A (en) | 1997-11-25 |
ES2089299T3 (es) | 1996-10-01 |
CZ287575B6 (cs) | 2000-12-13 |
JP3334908B2 (ja) | 2002-10-15 |
NO922643L (no) | 1993-01-06 |
DE4122265A1 (de) | 1993-01-07 |
DE59206340D1 (de) | 1996-06-27 |
NO301645B1 (no) | 1997-11-24 |
NO922643D0 (no) | 1992-07-03 |
JPH05194687A (ja) | 1993-08-03 |
AU656981B2 (en) | 1995-02-23 |
CZ209492A3 (en) | 1993-01-13 |
AU1939192A (en) | 1993-01-07 |
DK0522419T3 (da) | 1996-06-17 |
EP0522419B1 (de) | 1996-05-22 |
CA2073081C (en) | 2003-05-13 |
MX9203953A (es) | 1993-01-01 |
CA2073081A1 (en) | 1993-01-06 |
ATE138403T1 (de) | 1996-06-15 |
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