KR920702824A - 내염소성 반투막 및 그 제조방법 - Google Patents

내염소성 반투막 및 그 제조방법

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Publication number
KR920702824A
KR920702824A KR1019910701096A KR910701096A KR920702824A KR 920702824 A KR920702824 A KR 920702824A KR 1019910701096 A KR1019910701096 A KR 1019910701096A KR 910701096 A KR910701096 A KR 910701096A KR 920702824 A KR920702824 A KR 920702824A
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Prior art keywords
semipermeable membrane
chlorine resistant
resistant semipermeable
membrane according
chlorine
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KR1019910701096A
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English (en)
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KR970006838B1 (ko
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엔. 트랜 친
시. 츄 홍
지. 라이트 윌리엄
Original Assignee
제라드 피. 루우니
알라이드-시그날 인코포레이티드
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Publication of KR920702824A publication Critical patent/KR920702824A/ko
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1213Laminated layers
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B5/00Anti-hunting arrangements
    • G05B5/01Anti-hunting arrangements electric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0006Organic membrane manufacture by chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0023Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/003Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0088Physical treatment with compounds, e.g. swelling, coating or impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/107Organic support material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/125In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/1251In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/58Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/60Polyamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/08Specific temperatures applied
    • B01D2323/081Heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/219Specific solvent system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/48Influencing the pH
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/30Chemical resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31536Including interfacial reaction product of adjacent layers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Automation & Control Theory (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

내용 없음

Description

내염소성 반투막 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 폴리히드릭 화합물을 함유하는 방향족 폴리아민의 수용액을 다공성 지지보강물질상에 도포 적용하고; 과량의 용액을 제거하고; 도포된 다공성 지지보강 물질을 방향족 폴리카르복시산 할라이드의 유기용매용액과 접촉시켜 상기 다공성 지지물질의 표면상에 계면축합반응산물을 형성시키고; 결과의 합성물을 내염소성 반투막을 형성하는 경화조건하에서 경화시킴에 의하여 제조되는, 내염소성 반투막.
  2. 제1항에 있어서, 상기 경화조건이 20-150℃의 온도에서 10분-2시간 동안 처리하는 것임을 특징으로 하는, 내염소성 반투막.
  3. 제1항에 있어서, 상기 방향족 폴리아민이 m-페닐렌디아민, 4-클로로페닐렌디아민, 5-클로로페닐렌디아민, 및 그 혼합물로 구성된 군으로부터 선택된 것임을 특징으로 하는, 내염소성 반투막.
  4. 제1항에 있어서, 상기 방향족 폴리카르복시산할라이드가 이소프탈로일 클로라이드, 트리메조일 클로라이드 및 테레프탈로일 클로라이드로 구성된 군으로부터 선택된 것임을 특징으로 하는, 내염소성 반투막.
  5. 제1항에 있어서, 상기 폴리히드릭 화합물이 에틸렌글리콜, 글리세린, 프로필렌글리콜 및 폴리에틸렌 글리콜로 구성된 군으로부터 선택된 것임을 특징으로 하는, 내염소성 반투막.
  6. 제1항에 있어서, 상기 수용액이 산수용체를 함유하는 것임을 특징으로 하는, 내염소성 반투막.
  7. 제1항에 있어서, 상기 수용액의 pH가 9-11인 것을 특징으로 하는, 내염소성 반투막.
  8. 제1항에 있어서, 상기 경화막이 알칼리 화합물을 세척처리 되어진 것임을 특징으로 하는, 내염소성 반투막.
  9. 제8항에 있어서, 경화막이 20-100℃ 범위의 온도에서 세척되어진 것임을 특징으로 하는, 내염소성 반투막.
  10. 제1항에 있어서, 반투막이 알칼리 화합물과의 세척처리후 침출처리 되어진 것임을 특징으로 하는, 내염소성 반투막.
  11. 제10항에 있어서, 침출처리가 20-100℃의 온도에서 아황산수소나트륨의 존재하에 수행되는 것을 특징으로 하는, 내염소성 반투막.
  12. 제1항에 있어서, 상기 반투막이 침출처리후 막상에 코딩을 형성하도록 폴리히드릭 화합물과 함께 처리된 것을 특징으로 하는, 내염소성 반투막.
  13. 폴리히드릭 화합물 및 산수용체를 함유하는 방향족 폴리아민의 수용액을 다공성 지지보강물질상에 도포적용하고; 과량의 용액을 제거하고; 상기 다공성 지지물질의 표면상에 계면축합 반응산물이 형성되도록, 상기 도포된 다공성 지지물질을 방향족 폴리카르복시산 할라이드의 유기용매 용액과 접촉시키고; 결과의 합성물을 경화조건에서 경화시키고; 경화된 막을 높은 온도 및 pH에서 알칼리 화합물로 세척하고; 세척된 합성물을 고온에서 아황산수소나트륨과 함께 침출시키고; 침출처리된 합성물을 폴리히드릭 화합물과 함께 처리하고; 결과의 내염소성 반투막을 회수하는 것으로 구성된, 내염소성 반투막의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910701096A 1987-06-08 1989-03-16 내염소성 반투막 및 그 제조방법 KR970006838B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/059,295 US4830885A (en) 1987-06-08 1987-06-08 Chlorine-resistant semipermeable membranes
PCT/US1989/001087 WO1990010494A1 (en) 1987-06-08 1989-03-16 Chlorine-resistant semipermeable membranes
ZA892353A ZA892353B (en) 1987-06-08 1989-03-30 Chlorine-resistant semipermeable membranes
CN89102360A CN1029824C (zh) 1987-06-08 1989-04-17 耐氯半透膜

Publications (2)

Publication Number Publication Date
KR920702824A true KR920702824A (ko) 1992-10-28
KR970006838B1 KR970006838B1 (ko) 1997-04-30

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KR1019910701096A KR970006838B1 (ko) 1987-06-08 1989-03-16 내염소성 반투막 및 그 제조방법

Country Status (8)

Country Link
US (1) US4830885A (ko)
EP (1) EP0462967B1 (ko)
KR (1) KR970006838B1 (ko)
CN (1) CN1029824C (ko)
AT (1) ATE82703T1 (ko)
AU (1) AU634717B2 (ko)
WO (1) WO1990010494A1 (ko)
ZA (1) ZA892353B (ko)

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CN1029824C (zh) 1995-09-27
ATE82703T1 (de) 1992-12-15
AU634717B2 (en) 1993-03-04
US4830885A (en) 1989-05-16
EP0462967A1 (en) 1992-01-02
WO1990010494A1 (en) 1990-09-20
EP0462967B1 (en) 1992-11-25
KR970006838B1 (ko) 1997-04-30
AU3966189A (en) 1990-10-09
ZA892353B (en) 1989-12-27

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