JPS6456108A - Production of composite semipermeable membrane - Google Patents
Production of composite semipermeable membraneInfo
- Publication number
- JPS6456108A JPS6456108A JP62213708A JP21370887A JPS6456108A JP S6456108 A JPS6456108 A JP S6456108A JP 62213708 A JP62213708 A JP 62213708A JP 21370887 A JP21370887 A JP 21370887A JP S6456108 A JPS6456108 A JP S6456108A
- Authority
- JP
- Japan
- Prior art keywords
- polyfunctional
- soln
- amine
- base film
- acid halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title abstract 2
- 239000012528 membrane Substances 0.000 title abstract 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 150000004820 halides Chemical class 0.000 abstract 3
- 238000012696 Interfacial polycondensation Methods 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 150000004982 aromatic amines Chemical class 0.000 abstract 2
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 abstract 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 abstract 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- RPHKINMPYFJSCF-UHFFFAOYSA-N benzene-1,3,5-triamine Chemical compound NC1=CC(N)=CC(N)=C1 RPHKINMPYFJSCF-UHFFFAOYSA-N 0.000 abstract 1
- UWCPYKQBIPYOLX-UHFFFAOYSA-N benzene-1,3,5-tricarbonyl chloride Chemical compound ClC(=O)C1=CC(C(Cl)=O)=CC(C(Cl)=O)=C1 UWCPYKQBIPYOLX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000011033 desalting Methods 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 229920002492 poly(sulfone) Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Laminated Bodies (AREA)
Abstract
PURPOSE:To produce a composite semipermeable membrane having high desalting capacity and high water permeability by the interfacial polycondensation reaction of a polyfunctional amine with a polyfunctional acid halide wherein 4-chloroformyl phthalic anhydride is contained in the reactants. CONSTITUTION:A fine porous base film such as fiber-reinforced polysulfone base film is dipped in an aq. soln. of polyfunctional aromatic amine having >=2 amino groups in a molecule such as 1,3,5-triaminobenzene, etc. After removing the excess aq. amine soln. by draining the dipped film, a soln. of polyfunctional acid halide such as 1,3,5-benzene tricarboxylic acid chloride and 4-chloroformyl phthalic anhydride and an acylating catalyst such as dimethyl formamide in trichlorotrifluoroethane is applied on the film. Thus, a superthin layer of crosslinked polyamide is formed on the base film by the interfacial polycondensation of a polyfunctional aromatic amine with a polyfunctional acid halide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62213708A JPS6456108A (en) | 1987-08-27 | 1987-08-27 | Production of composite semipermeable membrane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62213708A JPS6456108A (en) | 1987-08-27 | 1987-08-27 | Production of composite semipermeable membrane |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6456108A true JPS6456108A (en) | 1989-03-03 |
Family
ID=16643670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62213708A Pending JPS6456108A (en) | 1987-08-27 | 1987-08-27 | Production of composite semipermeable membrane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6456108A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014499A1 (en) * | 1990-03-27 | 1991-10-03 | Toray Industries, Inc. | Composite membrane |
CN106621829A (en) * | 2015-10-28 | 2017-05-10 | 中国石油化工股份有限公司 | Composite reverse osmosis membrane preparation method and composite reverse osmosis membrane |
CN113117530A (en) * | 2020-01-15 | 2021-07-16 | 中国科学院大连化学物理研究所 | Composite membrane for improving permselectivity of polyamide nanofiltration composite membrane and preparation method thereof |
-
1987
- 1987-08-27 JP JP62213708A patent/JPS6456108A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014499A1 (en) * | 1990-03-27 | 1991-10-03 | Toray Industries, Inc. | Composite membrane |
CN106621829A (en) * | 2015-10-28 | 2017-05-10 | 中国石油化工股份有限公司 | Composite reverse osmosis membrane preparation method and composite reverse osmosis membrane |
CN113117530A (en) * | 2020-01-15 | 2021-07-16 | 中国科学院大连化学物理研究所 | Composite membrane for improving permselectivity of polyamide nanofiltration composite membrane and preparation method thereof |
CN113117530B (en) * | 2020-01-15 | 2022-05-31 | 中国科学院大连化学物理研究所 | Composite membrane for improving permselectivity of polyamide nanofiltration composite membrane and preparation method thereof |
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