KR920008109A - 산소-민감성 물질에 대한 장벽 패키징으로서의 하이드록실 관능화 폴리에테르아민 - Google Patents

산소-민감성 물질에 대한 장벽 패키징으로서의 하이드록실 관능화 폴리에테르아민 Download PDF

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KR920008109A
KR920008109A KR1019910017242A KR910017242A KR920008109A KR 920008109 A KR920008109 A KR 920008109A KR 1019910017242 A KR1019910017242 A KR 1019910017242A KR 910017242 A KR910017242 A KR 910017242A KR 920008109 A KR920008109 A KR 920008109A
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amine
oxygen
independently
polyetheramine
substituted
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KR1019910017242A
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KR100235359B1 (ko
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크레이그 실비스 에이치.
이. 화이트 제리
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리챠드 지. 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/64—Amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/024—Polyamines containing oxygen in the form of ether bonds in the main chain
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
    • Y10T428/1341—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y10T428/1383—Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Abstract

내용 없음

Description

제목 산소-민감성 물질에 대한 장벽 패키징으로서의 하이드록실 관능화 포리에테르아민
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 다음 일반식(I)의 반복단위를 갖고, 통상적으로 고체이며 성형가능한 열가소성 폴리에테르아민.
    A는 각각 독립적으로 다음 일반식
    [여기에서, R2는 C2-C10하이드로카빌렌 또는 치환된 하이드로카빌렌이고, R3는 C1-C10하이드로카빌 또는 치환된 하이드로카빌이며, R4는 C2-C10알킬렌 또는 치환된 C2-C10알킬렌이고, R5는 각각 독립적으로 C1-C10하이드로카빌 또는 치환된 C1-C10하이드로카빌인데, 단 적어도 하나의 R5는 아미도 잔기를 함유하며, R6은 C2-C103가 지방족 탄화수소(예:3가 알칸)이고 Z는 C1-C10하이드로카빌아미도이다]으로 나타낸 아미도아민 잔기이고, B는 각각 독립적으로 2가 방향족 잔기이며, Y는 각각 독립적으로 2가 산소 또는 황이고, R1는 수소, 1가 탄화수소 또는 치환된 1가 탄화수소이며, X는 폴리에테르의 산소 투과성을 일반식(여기서, Ar은 비스페놀-A로부터 2개의 하이드록실 잔기를 제거함으로서 생성된 2가 라디칼이다)의 반복 단위로 이루어진 폴리에테르의 측정치보다 낮은 값으로 저하시키기에 충분한 수이다.
  2. 제1항에 있어서, R1는 수소 또는 메틸이고, R2가 알킬렌이며, R4가 에틸렌이고, R5가 알킬 또는 치환된 알킬이며, R6이 에탄트리일이고, Z가 알킬아미드이며, B가 아릴렌 또는 아릴렌알킬리덴아릴렌이고, Y가 2가 산소이며 X가 0.2내지 1인 폴리에테르아민.
  3. 제2항에 있어서, 다음 일반식의 폴리에테르아민.
    상기식에서, V 및 V′는 독립적으로 하이드록시알킬아미노 또는 비스(하이드록시알킬)아미노이고, x는 0.5내지 1이며, w는 10내지 400의 수이다.
  4. 제1항에 있어서, 2가 페놀의 디글리시딜 에테르와 분자당 단지 2개의 아민 수소를 함유하는 아민과의 반응생성물인 폴리에테르아민.
  5. 제4항에 있어서, 2가 페놀이 비스페놀-A, 하이드로퀴논 또는 레조르시놀이고익 아민이 피페라진, 2,5-디메틸-피페라진, 4-(메틸아미도)아닐린, 4-메톡시아닐린, 2-아미노에탄올, 1,2-비스(2-에탄올아미노)에탄 및 1,4-비스(2-에탄올아미노)벤젠인 폴리에테르아민.
  6. 제4항에 있어서, 2가 페놀이 비스페놀-A이 아민이 2-아미노에탄올인 폴리에테르아민.
  7. 제1항에 있어서, 2가 페놀이 디글리시딜 에테르, 분자당 단지 2개의 아민 수소를 함유하는 아민 및 2가 페놀의 공중합체성 반응 생성물인 폴리에테르아민.
  8. 제7항에 있어서, 비스페놀-A 또는 레조르시놀의 디글리시딜 에테르, 2-에탄올아민 또는 피페라진, 및 레조르시놀 또는 비스페놀-A의 반응 생성물인 폴리에테르아민.
  9. 제1항에 있어서, 장벽 용기, 장벽 필름 또는 장벽 피복물의 형태인 폴리에테르아민.
  10. 다음 일반식의 반복단위를 갖고, 통상적으로 고체이며, 열가소성인 하이드록시-관능성 폴리에테르아민중에 산소-민감성 물질을 봉입시킴으로써 상기 물질을 환경상 산소로부터 보호하기 위한 산소 장벽을 제공하는 단계를 포함하는 패키징법.
    상기식에서, A는 각각 독립적으로 2가 아민 잔기이고, B는 각각 독립적으로 2가 방향족 잔기이며, Y는 각각 2가 산소 또는 황이고, R1은 수소, 1가 탄화수소 또는 치환된 1가 탄화수소이며, V 및 V′는 각각 독립적으로 2급아민 3급 아민이고, w는 10내지 400의 수이며, x는 폴리에테르의 산소 투과성을 일반식의 반복단위로 이루어진 폴리에테르의 측정치보다 낮은 값으로 저하시키기에 충분한 수이다.
  11. 2가 페놀의 디글리시딜 에테르를 아민의 아민 잔기가 디글리시딜 에테르의 에폭시 잔기와 반응하여 폴리에테르아민을 형성하기에 충분한 조건하에 압출기 속에서 단지 2개의 아민수소를 함유하는 아민과 접촉시킴을 포함하는 제1항의 폴리에테르아민의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910017242A 1990-10-03 1991-10-02 산소 민감성 물질에 대한 차단 패키징으로서의 하이드록실 관능화 폴리에테르아민, 이의 제조방법 및 패키징 방법 KR100235359B1 (ko)

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US59209790A 1990-10-03 1990-10-03
US7/592,097 1990-10-03
US07/592,097 1990-10-03

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KR920008109A true KR920008109A (ko) 1992-05-27
KR100235359B1 KR100235359B1 (ko) 1999-12-15

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AT (1) ATE163949T1 (ko)
AU (1) AU642303B2 (ko)
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HK1005486A1 (en) 1999-01-08
FI914619A (fi) 1992-04-04
CA2052653A1 (en) 1992-04-04
ES2113366T3 (es) 1998-05-01
FI107338B (fi) 2001-07-13
BR9104272A (pt) 1992-06-02
AU8553691A (en) 1992-04-09
EP0479445B1 (en) 1998-03-11
US5275853A (en) 1994-01-04
EP0479445A3 (en) 1992-08-26
NZ240001A (en) 1993-12-23
KR100235359B1 (ko) 1999-12-15
EP0479445A2 (en) 1992-04-08
DE69129055T2 (de) 1998-08-06
TW276259B (ko) 1996-05-21
ATE163949T1 (de) 1998-03-15
FI914619A0 (fi) 1991-10-02
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DE69129055D1 (de) 1998-04-16

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