KR910009630A - 불포화 카르복시산 에스테르의 제조방법 - Google Patents
불포화 카르복시산 에스테르의 제조방법 Download PDFInfo
- Publication number
- KR910009630A KR910009630A KR1019900019297A KR900019297A KR910009630A KR 910009630 A KR910009630 A KR 910009630A KR 1019900019297 A KR1019900019297 A KR 1019900019297A KR 900019297 A KR900019297 A KR 900019297A KR 910009630 A KR910009630 A KR 910009630A
- Authority
- KR
- South Korea
- Prior art keywords
- carboxylic acid
- acid ester
- unsaturated carboxylic
- producing
- methyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- α-히드록시 카르복시산 에스테르, α-알콕시 카르복시산 에스테르 및 β-알콕시 카르복시산 에스테르의 1종 또는 2종 이상을 원료로 하여 기체상 접촉 반응으로 αㆍβ-불포화카르복시산 에스테르를 제조하는데 있어서, 결정성 알루미노규산염을 알칼리금속과 백금족원소로 변성한 촉매를 사용하는 것을 특징으로 하는 α, β-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, 결정성 알루미노규산염이 X형 제올라이트인 αㆍβ-불포화카르복시산 에스테르의 방법.
- 제1항에 있어서, 결정성 알루미노규산염이 Y형 제올라이트인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제2항에 있어서, X형 제올라이트가 몰레클라 시이브 13X인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, 알칼리금속이 Li, Na, K, Cs, Rb인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, 백금족원소가 Pt, Pd, Rh, Ru, Ir, Os인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, α-히드록시 카르복시산 에스테르가 α-히드록시이소부티르산 메틸, 락트산 메틸인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, α-알콕시 카르복시산 에스테르가 α-메톡시이소부티르산 메틸 또는 α-메톡시프로피온산 메틸인 αㆍβ-불포화카르복시산 에스테르의 제조방법.
- 제1항에 있어서, β-알콕시 카르복시산 에스테르가 β-메톡시이소부티르산 메틸 또는 β-메톡시프로피온판메틸인 αㆍβ-불포화카르복시산 에스테르의 방법.
- 제1항에 있어서, 희석제로서 그 에스테르의 알콕시 부분에 상응하는 알코올을 사용하는 αㆍβ-불포화카르복시산 에스테르의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1-306647 | 1989-11-28 | ||
JP306647/1989 | 1989-11-28 | ||
JP1306647A JP2884639B2 (ja) | 1989-11-28 | 1989-11-28 | 不飽和カルボン酸エステルの製造法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR910009630A true KR910009630A (ko) | 1991-06-28 |
KR960000041B1 KR960000041B1 (ko) | 1996-01-03 |
Family
ID=17959625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900019297A KR960000041B1 (ko) | 1989-11-28 | 1990-11-28 | 불포화 카르복시산 에스테르의 제조방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5068399A (ko) |
EP (1) | EP0429800B2 (ko) |
JP (1) | JP2884639B2 (ko) |
KR (1) | KR960000041B1 (ko) |
DE (1) | DE69015591T3 (ko) |
ES (1) | ES2070233T5 (ko) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5268506A (en) * | 1992-03-27 | 1993-12-07 | Mitsui Toatsu Chemicals, Incorporated | Process for producing α, β-unsaturated carboxylic acid |
JP3189858B2 (ja) * | 1992-11-16 | 2001-07-16 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造法 |
US5612303B1 (en) * | 1993-06-15 | 2000-07-18 | Nitto Chemical Industry Co Ltd | Solvent composition |
US5393918A (en) * | 1993-12-02 | 1995-02-28 | Rohm And Haas Company | High yield process for the production of methacrylic acid esters |
KR100367534B1 (ko) * | 1994-09-14 | 2003-06-02 | 미쯔비시 레이온 가부시끼가이샤 | 안정성이개선된옥시이소부티르산에스테르를함유하는용제조성물 |
JP3520878B2 (ja) * | 1995-01-10 | 2004-04-19 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造方法 |
GB9807498D0 (en) * | 1998-04-08 | 1998-06-10 | Ici Plc | Production of unsaturated acids therfore and catalysts therfor |
EP1186592A1 (en) * | 2000-09-11 | 2002-03-13 | Mitsubishi Gas Chemical Company, Ltd. | Production of methacrylates |
US6545175B1 (en) | 2000-10-19 | 2003-04-08 | Battelle Memorial Institute | Ester compounds and their use in forming acrylates |
US6992209B2 (en) * | 2002-12-09 | 2006-01-31 | Battelle Memorial Institute | Methods of forming alpha, beta-unsaturated acids and esters |
US6816104B1 (en) * | 2003-07-14 | 2004-11-09 | Benq Corporation | Analog-to-digital converter utilizing a timer for increased resolution |
DE102005023975A1 (de) * | 2005-05-20 | 2006-11-23 | Röhm Gmbh | Verfahren zur Herstellung von Alkyl(meth)acrylaten |
JP5432852B2 (ja) * | 2009-09-30 | 2014-03-05 | ローム アンド ハース カンパニー | メタクリル酸メチルの精製によって生じる流れから価値のある化合物を回収する方法 |
CN101703944B (zh) * | 2009-11-13 | 2013-05-22 | 江苏工业学院 | 分子筛改性催化剂、制备方法及其在制备丙烯酸酯的应用 |
US9012686B2 (en) | 2010-09-23 | 2015-04-21 | Olan S. Fruchey | Acrylic acid from lactide and process |
CN103221380B (zh) * | 2010-10-07 | 2015-04-29 | 罗门哈斯公司 | 生产甲基丙烯酸酯的方法 |
WO2012091114A1 (ja) | 2010-12-28 | 2012-07-05 | 株式会社日本触媒 | アクリル酸および/またはそのエステルおよびその重合体の製法 |
WO2013184345A1 (en) * | 2012-06-04 | 2013-12-12 | Rohm And Haas Company | Process for production of methacrylic acid esters |
US20160102043A1 (en) * | 2013-06-26 | 2016-04-14 | Rohm And Haas Company | Process for production of methacrylic acid esters |
RU2665466C2 (ru) | 2013-12-24 | 2018-08-30 | Мицубиси Газ Кемикал Компани, Инк. | Катализатор для применения для получения метилметакрилата и способ получения метилметакрилата |
RU2671574C2 (ru) | 2014-04-10 | 2018-11-02 | Мицубиси Газ Кемикал Компани, Инк. | Формованный катализатор для применения в производстве метилметакрилата и способ производства метилметакрилата с применением указанного катализатора |
JP6694641B2 (ja) * | 2015-06-30 | 2020-05-20 | 国立研究開発法人産業技術総合研究所 | アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法 |
EP3710421B1 (en) * | 2017-11-17 | 2023-06-07 | PURAC Biochem BV | Process for the production of methyl acrylate from methyl lactate |
WO2023169810A1 (de) | 2022-03-11 | 2023-09-14 | Röhm Gmbh | Verfahren zur herstellung von alpha-hydroxyisobuttersäuremethylester und dessen anwendung in der elektronik-industrie |
KR20240037607A (ko) | 2022-09-15 | 2024-03-22 | 재원산업 주식회사 | Euv 반도체 공정용 고순도 메틸 2-히드록시이소부틸레이트의 제조 및 정제방법 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH430691A (de) * | 1963-09-17 | 1967-02-28 | Lonza Ag | Verfahren zur Herstellung von Methacrylverbindungen |
JPS6317844A (ja) * | 1986-07-09 | 1988-01-25 | Nippon Shokubai Kagaku Kogyo Co Ltd | 不飽和カルボン酸エステルの製造方法 |
US4812593A (en) * | 1986-08-27 | 1989-03-14 | Basf Aktiengesellschaft | Preparation of bifunctional compounds |
DE3638011A1 (de) * | 1986-11-07 | 1988-05-11 | Basf Ag | Verfahren zur herstellung von 4-pentensaeureestern |
JP2727618B2 (ja) * | 1989-01-26 | 1998-03-11 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造方法 |
-
1989
- 1989-11-28 JP JP1306647A patent/JP2884639B2/ja not_active Expired - Lifetime
-
1990
- 1990-09-17 US US07/583,802 patent/US5068399A/en not_active Expired - Lifetime
- 1990-10-04 EP EP90118954A patent/EP0429800B2/en not_active Expired - Lifetime
- 1990-10-04 ES ES90118954T patent/ES2070233T5/es not_active Expired - Lifetime
- 1990-10-04 DE DE69015591T patent/DE69015591T3/de not_active Expired - Lifetime
- 1990-11-28 KR KR1019900019297A patent/KR960000041B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR960000041B1 (ko) | 1996-01-03 |
JPH03167157A (ja) | 1991-07-19 |
EP0429800B1 (en) | 1994-12-28 |
DE69015591T2 (de) | 1995-05-11 |
EP0429800A2 (en) | 1991-06-05 |
US5068399A (en) | 1991-11-26 |
JP2884639B2 (ja) | 1999-04-19 |
DE69015591D1 (de) | 1995-02-09 |
ES2070233T3 (es) | 1995-06-01 |
EP0429800A3 (en) | 1992-02-19 |
ES2070233T5 (es) | 1998-01-16 |
DE69015591T3 (de) | 1998-09-10 |
EP0429800B2 (en) | 1997-10-08 |
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