KR890700547A - 소량의 산화칼슘을 함유한 강화된 코오디어라이트 - Google Patents

소량의 산화칼슘을 함유한 강화된 코오디어라이트

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Publication number
KR890700547A
KR890700547A KR1019880701764A KR880701764A KR890700547A KR 890700547 A KR890700547 A KR 890700547A KR 1019880701764 A KR1019880701764 A KR 1019880701764A KR 880701764 A KR880701764 A KR 880701764A KR 890700547 A KR890700547 A KR 890700547A
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weight
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ppm
sintered refractory
mgo
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KR1019880701764A
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KR910001949B1 (ko
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알.프루니어 쥬니어 아더
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리차드 지.워터만
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
    • C04B35/04—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

내용 없음.

Description

소량의 산화칼슘을 함유한 강화된 코오디어라이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 CaO의 중량% 함수로서 본 발명의 소결된 코오디어라이트체의 요곡강도를 나타낸 도면이다.

Claims (21)

  1. SiO247.5 내지 56중량%, Al2O331 내지 40중량%, MgO 12 내지 19중량%, 및 CaO 0.15 내지 1중량%를 함유한 코오디어라이트로 필수적으로 이루어지며 적어도 138MPa (20,000 Psi)의 금속요곡 강도를 갖는 소결된 내화체.
  2. 제1항에 있어서, 코오디어라이트체가 불순물로서, 산화물을 기준으로 하여, MgO 및 CaO외에 0.3중량% 미만의 전체 알카리성 토금속 산화물, 250ppm 미만의 Na2O, 150ppm 미만의 K2O 및 500ppm 미만의 전이금속을 갖는 소결된 내화체.
  3. 제1항에 있어서, 코오디어라이트가 합성물질을 사용하여 제조된 소결된 내화체.
  4. 제2항에 있어서, 산화물을 기준으로하여 MgO 및 CaO를 제외한 알카리성 토금속 함량이 약 1,000ppm 미만인 소결된 내화체.
  5. 제4항에 있어서, 알칼리성 토금속 함량이 약 500ppm 미만인 소결된 내화체.
  6. 제2항에 있어서, 산화물을 기준으로 하여 전이금속의 함량이 200ppm 미만인 소결된 내화체.
  7. 제6항에 있어서, 산화물을 기준으로 하여 전이금속의 함량이 100ppm 미만인 소결된 내화체.
  8. 제1항에 있어서, 평균 요곡강도가 적어도 155MPa (22, 500psi)인 소결된 내화체.
  9. 제1항에 있어서, 유전상수가 1MHZ 및 25℃에서 측정시 약 5.2 미만이고, 밀도가 이론상 밀도의 적어도 96%인 소결된 내화체.
  10. 제2항에 있어서, 산화물을 기준으로 하여 알카리 금속 함량이 전체 조성물의 750ppm 미만인 소결된 내화체.
  11. 제10항에 있어서, 산화물을 기준으로 하여 알카리 금속함량이 전체 조성물의 500ppm 미만인 소결된 내화체.
  12. 제1항에 있어서, 48.7 내지 54.1중량%의 SiO2, 32.6 내지 37.7중량%의 Al2O3, 및 12.8 내지 16.6중량%의 MgO를 함유하는 소결된 내화체.
  13. 제12항에 있어서, 50.3 내지 52.2중량%의 SiO2, 34.3 내지 35.7중량%의 Al2O3및 13.3 내지 14.6중량%의 MgO를 함유하는 소결된 내화체.
  14. 제1항에 있어서, Si, Al, Mg 및 Ca의 산화물의 전체 중량을 기준으로 하여 산화칼슘의 양이 0.25 내지 0.75중량%인 소결된 내화체.
  15. 제14항에 있어서, 산화칼슘의 양이 0.4 내지 0.6중량%인 소결된 내화체.
  16. 내화체의 전체중량을 기준으로 하여, SiO250.3 내지 52.2중량%, Al2O334.3 내지 35.7중량%, MgO 13.3 내지 14.6중량% 및 CaO 0.4 내지 0.6중량%를 함유하고 합성원료를 사용하여 제조한 코오디어라이트로 필수적으로 이루어지며 CaO 및 MgO 이외에 불순물로서 500ppm 미만의 전체 알카리 금속산화물, 100ppm 미만의 전체 전이금속 산화물, 및 500ppm 미만의 전체 알카리 토금속 산화물을 함유하고, 평균 요곡강도가 적어도 138MPa (20,000psi)인 소결된 등방성 내화체.
  17. (a) 합성 원료로부터 합성 코오티어라이트 전구체 분말을 제조하고, (b) 산화칼슘과 단계 (a) 분말의 수성 슬러지를 제조하며, (c) 슬러리를 처리하여 건조된 산화칼슘-함유 분말을 수득하고, (d) 단계 (c)의 분말로부터 녹색체를 제조하며, (e) 녹색체를 발화시켜 SiO247.5 내지 56중량%, Al2O3내지 40중량%, MgO 12 내지 19중량, 및 CaO 0.15 내지 1중량%를 함유하며 적어도 138MPa의 평균 요곡 강도를 갖는 내화 코오디어라이트체를 형성함을 특징으로 하여, 내화체를 제조하는 방법.
  18. 제17항에 있어서, 산화칼슘 공급원이 질산칼슘인 방법.
  19. 제18항에 있어서, 평균 요곡 강도가 적어도 155Mpa (22,500psi)인 방법.
  20. 제17항에 있어서, 합성 코오디어라이트 전구 분말의 제조 단계가 500℃ 내지 1150℃의 온도에서 하소하는 과정을 포함하는 방법.
  21. 제20항에 있어서, 내화체가 250ppm 미만인 Na2O 및 150ppm의 K2O를 함유하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880701764A 1987-04-27 1988-04-21 소량의 산화칼슘을 함유한 강화된 코오디어라이트 KR910001949B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/042996 1987-04-27
US07/042,996 US4745092A (en) 1987-04-27 1987-04-27 Strengthened cordierite having minor amounts of calcia
US042996 1987-04-27
PCT/US1988/001346 WO1988008413A1 (en) 1987-04-27 1988-04-21 Strengthened cordierite having minor amounts of calcia

Publications (2)

Publication Number Publication Date
KR890700547A true KR890700547A (ko) 1989-04-25
KR910001949B1 KR910001949B1 (ko) 1991-03-30

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Country Status (7)

Country Link
US (1) US4745092A (ko)
EP (1) EP0370020A4 (ko)
JP (1) JPH02503190A (ko)
KR (1) KR910001949B1 (ko)
BR (1) BR8807481A (ko)
CA (1) CA1294292C (ko)
WO (1) WO1988008413A1 (ko)

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WO1988008413A1 (en) 1988-11-03
CA1294292C (en) 1992-01-14
US4745092A (en) 1988-05-17
EP0370020A4 (en) 1991-01-16
JPH02503190A (ja) 1990-10-04
EP0370020A1 (en) 1990-05-30
KR910001949B1 (ko) 1991-03-30
BR8807481A (pt) 1990-04-10

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