KR890015984A - 사이클로헥사놀 및/또는 사이클로헥사논의 제조방법 - Google Patents

사이클로헥사놀 및/또는 사이클로헥사논의 제조방법 Download PDF

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KR890015984A
KR890015984A KR1019890005239A KR890005239A KR890015984A KR 890015984 A KR890015984 A KR 890015984A KR 1019890005239 A KR1019890005239 A KR 1019890005239A KR 890005239 A KR890005239 A KR 890005239A KR 890015984 A KR890015984 A KR 890015984A
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South Korea
Prior art keywords
cyclohexene
cyclohexane
stream
cyclohexanone
benzene
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KR1019890005239A
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KR920000443B1 (ko
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크리스티안 반김 풀
토비아스 베르나르더스 죠세프반 덴브린크 프란시스커스
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제이.지.엠.뉴캠프
스태미카본 베.뷔.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/29—Saturated compounds containing keto groups bound to rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Seasonings (AREA)

Abstract

내용 없음

Description

사이클로헥사놀 및/또는 사이클로헥사논의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 본 발명에 따른 사이클로헥사놀 및/또는 사이클로헥사논의 제조 방법의 간략화된 블록 다이어그램이다.

Claims (5)

  1. 사이클로헥센, 사이클로헥산 및 벤젠을 함유한 피드스트림내의 사이클로헥센이 사이클로헥사놀로 수화 및/또는 사이클로헥사논의 산화되고, 생성된 사이클로헥사놀 및/또는 사이클로헥사논이 반응 혼합물로부터 분리되어지고, 잔류하는 사이클로헥산과 미리 연결괸 사이클로 헥센제조 구역으로 재순환되는 과정으로 구성되고, 사이클로헥산과 벤젠이 미리 연결된 사이클로헥센제조 구역으로 재순환되는 과정으로 구성되고, 사이클로헥센제조 구역으로 재순환된 스트림의 일부가 탈수소화 반응을 거치고 잔류부분은 수소화 반응을 거치며 그렇게 생성된 반응 스트림 결합되어서 수화 및/또는 산화 단계의 피드 스트림을 형성하는 것을 특징으로 하는 사이클로 헥사놀 및/또는 사이클로헥사논의 제조방법.
  2. 제 1 항에 있어서, 탈수소화 단계에서 생성된 수소의 전부 또는 일부가 수소화 단계에 사용되는 것을 특징으로 하는 방법.
  3. 제 1 항 또는 제 2 항에 있어서, 회수 스트림의 벤젠과 사이클로헥산의 몰비가 5 : 1-1 : 5인것을 특징으로 하는 방법.
  4. 제 1 항 내지 제 3 항중 어느 한항에 있어서, 재순환된 스트림이 수소화 구역과 탈수소화 구역으로 나뉘는 비율이 피드 스트림의 벤젠/사이클로헥산의 비율에 의하는 것을 특징으로 하는 방법.
  5. 제 1 항 내지 제 4 항중 어느 한 항에 있어서, 사이클로헥센의 농도를 증가시키기 위하여 피드 스트림이 전처리되고, 그 처리된 스트림이 수화 및/또는 산화단계에 공급되는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890005239A 1988-04-21 1989-04-19 사이클로헥사놀 및/또는 사이클로헥사논의 제조방법 KR920000443B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8801036A NL8801036A (nl) 1988-04-21 1988-04-21 Werkwijze voor de bereiding van cyclohexanol en/of cyclohexanon.
NL8801036 1988-04-21

Publications (2)

Publication Number Publication Date
KR890015984A true KR890015984A (ko) 1989-11-27
KR920000443B1 KR920000443B1 (ko) 1992-01-14

Family

ID=19852177

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890005239A KR920000443B1 (ko) 1988-04-21 1989-04-19 사이클로헥사놀 및/또는 사이클로헥사논의 제조방법

Country Status (16)

Country Link
US (1) US4927974A (ko)
EP (1) EP0340827B1 (ko)
JP (1) JP2688246B2 (ko)
KR (1) KR920000443B1 (ko)
CN (1) CN1023216C (ko)
AT (1) ATE84776T1 (ko)
BR (1) BR8901880A (ko)
CA (1) CA1327212C (ko)
CS (1) CS277195B6 (ko)
DE (1) DE68904466T2 (ko)
ES (1) ES2038819T3 (ko)
GE (1) GEP19960308B (ko)
MX (1) MX169563B (ko)
NL (1) NL8801036A (ko)
RU (1) RU1833359C (ko)
SG (1) SG25293G (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5218704A (en) * 1989-10-30 1993-06-08 Texas Instruments Real-time power conservation for portable computers
DE4029485A1 (de) * 1990-09-18 1992-03-19 Basf Ag Verfahren zur abtrennung von cyclohexen aus gemischen mit benzol und cyclohexan
CN1073077C (zh) * 1997-07-31 2001-10-17 巴陵石油化工公司鹰山石油化工厂 环己醇脱氢方法的改进
EP1028109A1 (en) * 1999-02-12 2000-08-16 Dsm N.V. Process for the preparation of epsilon-caprolactam
JP4601805B2 (ja) * 2000-11-24 2010-12-22 ダイセル化学工業株式会社 シクロヘキサンの酸化方法
DE10209701A1 (de) * 2002-03-06 2003-09-18 Basf Ag Verfahren zur Herstellung von Cyclohexanol aus Benzol
RU2205819C1 (ru) * 2002-03-20 2003-06-10 Институт катализа им. Г.К.Борескова СО РАН Способ получения циклогексанона из бензола
RU2205175C1 (ru) * 2002-03-20 2003-05-27 Институт катализа им. Г.К. Борескова СО РАН Способ получения циклогексанона
WO2006046852A1 (en) * 2004-10-27 2006-05-04 Dsm Ip Assets B.V. Process for the preparation of cyclohexanol and cyclohexanone
TWI612031B (zh) 2012-09-18 2018-01-21 China Petrochemical Technology Co Ltd 一種聯產環己醇和鏈烷醇的方法和裝置
CN103265418A (zh) * 2013-06-08 2013-08-28 南京德力菲技术咨询有限公司 一种水合环己烯法环己醇制己内酰胺原料环己酮的方法
CN110872208B (zh) * 2019-02-18 2023-10-27 南京匹亚化工有限公司 一种耦合环己烷混合物脱氢技术的环己醇制备方法
CN111217684A (zh) * 2019-10-29 2020-06-02 山西潞宝兴海新材料有限公司 一种提高环己酮收率的生产方法
CN115838325A (zh) * 2021-09-18 2023-03-24 中国石油化工股份有限公司 一种环己烯与环己烷耦合制环己酮的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7905781A (nl) * 1979-07-26 1981-01-28 Stamicarbon Werkwijze voor het bereiden van cyclohexanol.
NL8006602A (nl) * 1980-12-04 1982-07-01 Stamicarbon Werkwijze voor het bereiden van cyclohexanol en/of cyclohexanon.
DE3203286A1 (de) * 1981-03-20 1982-12-09 The Agency of Industrial Science and Technology, Tokyo Verfahren zur herstellung von zyklohexanon
JPS59193836A (ja) * 1983-04-15 1984-11-02 Asahi Chem Ind Co Ltd アルコ−ル類の製造法
US4507512A (en) * 1983-05-31 1985-03-26 Toa Nenryo Kogyo Kabushiki Kaisha Process for hydration of olefins
JPS60104028A (ja) * 1983-11-09 1985-06-08 Asahi Chem Ind Co Ltd 環状アルコ−ルの製造法

Also Published As

Publication number Publication date
CN1023216C (zh) 1993-12-22
NL8801036A (nl) 1989-11-16
CS277195B6 (en) 1992-12-16
EP0340827A1 (en) 1989-11-08
DE68904466T2 (de) 1993-08-19
BR8901880A (pt) 1989-11-28
SG25293G (en) 1993-05-21
CS8902478A2 (en) 1991-07-16
EP0340827B1 (en) 1993-01-20
MX169563B (es) 1993-07-12
JPH01316330A (ja) 1989-12-21
CN1038273A (zh) 1989-12-27
GEP19960308B (en) 1996-02-20
ES2038819T3 (es) 1993-08-01
JP2688246B2 (ja) 1997-12-08
US4927974A (en) 1990-05-22
ATE84776T1 (de) 1993-02-15
DE68904466D1 (de) 1993-03-04
CA1327212C (en) 1994-02-22
KR920000443B1 (ko) 1992-01-14
RU1833359C (en) 1993-08-07

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