KR890012988A - 3,3-디아릴아크릴 산 아미드의 제법 - Google Patents

3,3-디아릴아크릴 산 아미드의 제법 Download PDF

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KR890012988A
KR890012988A KR1019890001790A KR890001790A KR890012988A KR 890012988 A KR890012988 A KR 890012988A KR 1019890001790 A KR1019890001790 A KR 1019890001790A KR 890001790 A KR890001790 A KR 890001790A KR 890012988 A KR890012988 A KR 890012988A
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alkyl
group
alkoxy
hydrogen
halogen
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KR1019890001790A
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KR970011285B1 (ko
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쿠르체 위르겐
쉬뢰더 루트비히
하워드 브리너 폴
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오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
    • C07D265/30—1,4-Oxazines; Hydrogenated 1,4-oxazines not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

내용 없음.

Description

3,3-디아릴아크릴 산 아미드의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 사용되는 염기가 3차 알콜 나트륨인 것을 특징으로 하는 염기의 존재하에서, 하기 일반식(Ⅱ)의 벤조페는 과하기 일반식(Ⅲ)의 아세트아미드를 반응시켜 하기 일반식(Ⅰ)의 3,3-디아릴 아크릴 산 아미드를 제조하는 방법:
    상기식에서,
    여기서, R1는 C1-4-알킬, C1-4-알콕시, NH2, NHC1-4-알킬, N(C1-4-알킬)2, C3-4-알케닐, C3-4-알키닐, C3-4-알케닐록시, C3-4알키닐록시, 또는 C3-6-시클로알킬이고;
    R2는 C1-4-알킬, C1-4-알콕시 또는 할로겐이며; R3는 수소 또는 할로겐이고; R4는 수소, 할로겐, C1-4-알킬 또는 C1-4-알콕시이며; R5는 C5-8-시클로알케닐 또는 나프틸기 또는 페닐기에 의해 각각 임의로 치환딘 C2-6-알키닐 또는 C2-6-알케닐기, 페녹시페닐기 또는 페닐페닐기, C3-7-시클로알킬기, 한개 이상의 할로겐 원자에 의해 임의로 치환된 C1-12알킬기, 할로겐 부분, C1-4-알콕시 및 C1-4-알킬로 부터 선택된 한개 이상의 치환체에 의해 임의로 치환된 페닐기 및 수소이며;
    X는 단일결합, -O-,-S(O)p-,-N=N-,-CHR9O-,-OCHR9-,-CHR9S(O)p-,-S(O)pCHR9-,-(CH2)n-,-HC=CH-, 또는 -C=C-이며;
    R6는 C1-4-알킬, C3-7-시클로알킬, 벤질, C3-4-알케닐 또는 C3-4-알키닐이며; R7은 C1-4알킬이고; R8은 수소, C1-4-알킬 또는 C1-4-알콕시이고; R9는 수소 또는 C1-4-알킬이고;p는 0,1 또는 2이며;n은 1-10 까지의 정수이다.
  2. 제1항에 있어서, 3차 알콜 나트륨은 각각의 R이 독립적으로 C1-4알킬기인 하기 일반식(Ⅳ)의 알콜로부터 유도되는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 3차 알콜 나트륨이 아민 알콜 또는 부틸 알콜로부터 유도되는 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 과량의 나트륨 알콜 화합물이 존재하는 것을 특징으로 하는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 제1항의 일반식(Ⅲ)의 아세트아미드가 과량으로 존재하는 것을 특징으로 하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 불활성 용매가 사용되는 것을 특징으로 하는 방법.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 반응 온도가 10℃-150℃인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890001790A 1988-02-19 1989-02-16 3,3-디아릴아크릴 산 아미드의 제법 KR970011285B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP3805235.0 1988-02-19
DE3805235A DE3805235A1 (de) 1988-02-19 1988-02-19 Verfahren zur herstellung von 3,3-diarylacrylsaeureamiden
NLP3805235.0 1988-02-19

Publications (2)

Publication Number Publication Date
KR890012988A true KR890012988A (ko) 1989-09-20
KR970011285B1 KR970011285B1 (ko) 1997-07-09

Family

ID=6347757

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Application Number Title Priority Date Filing Date
KR1019890001790A KR970011285B1 (ko) 1988-02-19 1989-02-16 3,3-디아릴아크릴 산 아미드의 제법

Country Status (11)

Country Link
US (1) US4920222A (ko)
EP (1) EP0329256B1 (ko)
JP (1) JP2573872B2 (ko)
KR (1) KR970011285B1 (ko)
CN (1) CN1019971C (ko)
AT (1) ATE105286T1 (ko)
BR (1) BR8900689A (ko)
DE (2) DE3805235A1 (ko)
ES (1) ES2056188T3 (ko)
HK (1) HK1000116A1 (ko)
IL (1) IL89331A (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5421067A (en) * 1977-07-15 1979-02-16 Keigo Kishimoto Ash receiving chute with damper for refuse incinerator
DE3817711A1 (de) * 1988-05-25 1989-11-30 Shell Int Research Verfahren zur herstellung von 3,3-diphenylacrylsaeureamiden
US5071166A (en) * 1990-01-12 1991-12-10 Thomas Marino Environmentally designed transportable holding tank
AU660205B2 (en) 1991-12-23 1995-06-15 Virbac, Inc Systemic control of parasites
IL106122A (en) * 1992-07-10 1997-04-15 Shell Int Research Preparation of 3, 3-diaryl acrylic acid amides
CN101637176B (zh) * 2009-08-27 2013-09-18 深圳诺普信农化股份有限公司 农药悬浮剂

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3128574C2 (de) * 1981-07-20 1984-03-29 Deutsche Texaco Ag, 2000 Hamburg Verfahren zur Herstellung von N-substituierten Acryl- und Methacrylamiden
CS244440B2 (en) * 1983-02-28 1986-07-17 Celamerck Gmbh & Co Kg Method of acrylic acids' new amides production
DE3689506D1 (de) * 1985-10-09 1994-02-17 Shell Int Research Neue Acrylsäureamide.
DE3536029A1 (de) * 1985-10-09 1987-04-09 Celamerck Gmbh & Co Kg Neue acrylsaeureamide
DE3719488A1 (de) * 1987-06-11 1988-12-29 Shell Agrar Gmbh & Co Kg Verfahren zur herstellung von 3,3-diarylacrylsaeureamiden
DE3817711A1 (de) * 1988-05-25 1989-11-30 Shell Int Research Verfahren zur herstellung von 3,3-diphenylacrylsaeureamiden

Also Published As

Publication number Publication date
BR8900689A (pt) 1989-10-10
JP2573872B2 (ja) 1997-01-22
EP0329256A1 (en) 1989-08-23
IL89331A (en) 1993-06-10
US4920222A (en) 1990-04-24
CN1035659A (zh) 1989-09-20
JPH023639A (ja) 1990-01-09
KR970011285B1 (ko) 1997-07-09
HK1000116A1 (en) 1997-12-05
DE68915025D1 (de) 1994-06-09
CN1019971C (zh) 1993-03-03
DE3805235A1 (de) 1989-08-31
ES2056188T3 (es) 1994-10-01
ATE105286T1 (de) 1994-05-15
IL89331A0 (en) 1989-09-10
EP0329256B1 (en) 1994-05-04
DE68915025T2 (de) 1994-08-25

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