KR880007670A - 자체-접착성 폴리오가노실록산 조성물 - Google Patents
자체-접착성 폴리오가노실록산 조성물 Download PDFInfo
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- KR880007670A KR880007670A KR1019870015205A KR870015205A KR880007670A KR 880007670 A KR880007670 A KR 880007670A KR 1019870015205 A KR1019870015205 A KR 1019870015205A KR 870015205 A KR870015205 A KR 870015205A KR 880007670 A KR880007670 A KR 880007670A
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- organosiloxane
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/44—Block-or graft-polymers containing polysiloxane sequences containing only polysiloxane sequences
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- A. 백금-촉매 하이드로 규소화 반응에 의해 경화될 수 있으며, 1) 분자당 두 개의 비닐 라디칼을 함유하는 액상 폴리디오가노실록산, 2) 조성물에 존재하는 비닐-함유 물질을 경화시키기에 충분한 양의, 분자당 세 개 이상의 규소-결합수소원자를 함유하는 오가노하이드로겐실록산, 및 3) 비닐-함유물질의 경화를 촉진시키기에 충분한 양의 백금-함유 촉매로 이루어진 제1오가노실록산 물질 ; B. 필수적으로 디오가노비닐실록시 단위, 트리오가노실록시 단위 및 SiO4/2단위로 이루어진 벤젠-가용성 공중합체 0 내지 60중량%(제1오가노실록산 조성물의 중량 기준) [여기서, SiO4/2단위에 대한 디오가노비닐실록시 및 트리오가노실록시 단위 혼합물의 몰비는 0.7 : 1 내지 1.2 : 1이고, 디오가노비닐실록시 단위는 공중합체의 2 내지 8중량%를 구성한다] ; 및 C. 제1오가노실록산 물질과 혼화할 수 있으며, (1) 액상 하이드록실-말단 폴리디오가노실록산과, 필수적으로 규소원자가 세 개 이상의 알콕시 그룹에 결합된 실란으로 이루어진 가교결합제의 혼하물 또는 이러한 혼합물의 반응 생성물(여기서는, 폴리디오가노실록산 중의 규소-결합 하이드록실그룹 몰당 0.5몰 이상의 실란이 존재한다), 및 (2) 수분 경화성 오가노실록산 물질의 경화를 촉진시키기에 충분한 양의, 티탄 오르토에스테르 및 킬레이트화된 티탄 화합물로 이루어진 그룹 중에서 선택된 촉매로 이루어진 수분경화성 오가노실록산 물질 0.1 내지 20중량%(제1오가노실록산 물질의 중량 기준)를 균일하게 혼합하여 수득한 생성물로 이루어지며, 이러한 조성물을 경화시켜 수득한 탄성중합체는 쇼어 A경도계 스케일에서 20 이하의 경도를 나타냄을 특징으로 하는, 경화성이 있는 자체-접착성 폴리오가노실록산 조성물.
- 제1항에 있어서, 제1오가노실록산 물질 중의 액상 폴리디오가노실록산은 하기 일반식(a)에 상응하며 ; 경화제의 반복 단위는 Hsio1.5, R5HSiO,및 임의로, 모노오가노실록시, 디오가노실록산, 트리오가노실록시 및 SiO2단위로 이루어진 그룹중의 한 성분 이상으로 이루어진 그룹 중에서 선택되고, 여기서 R5및 R6는 각각 독립적으로 하기의 R1과 동일한 그룹 중에서 선택되며 ; 수지상 오가노실록산 공중합체는 필수적으로 SiO2,및 CH2=CH(R4)2SiO1/2의 반복 단위로 이루어지고, 여기서 R3및 R4는 각각 독립적으로 하기의 R1과 동일한 그룹 중에서 선택되며 ; 하이드록실-말단 폴리디오가노실록산은 하기 일반식(b)의 물질이고 ; 실란은 일반식로 표시되며, 여기서 R9는 하기의 R1과 동일한 그룹 중에서 선택되고 R10은 탄소원자 1 내지 4개를 함유하는 알킬라디칼이며 p는 0 또는 1을 나타내는 조성물.상기 식에서, Vi는 비닐 라디칼을 나타내며, R1및 R2는 각각 독립적으로 에틸렌성 불포화가 없고 탄소 원자 1 내지 20개를 함유하는 1가의 탄화수소 또는 할로겐화 탄화수소 라디칼을 나타내며, n은 25℃에서 0.1 내지 약 100pa,s의 점도에 상당하는 값이고, R7및 R8은 각각 독립적으로 R1과 동일한 그룹 중에서 선택되며, P는 25℃에서 1 내지 약 10pa.s의 점도에 상당하는 값이다.
- 제2항에 있어서, R1,R3,R4,R5및 R7은 메틸을 나타내며, R2및 R8은 각각 독립적으로 메틸, 페닐 및 3,3,3-트리플루오로프로필로 이루어진 그룹 중에서 선택되고, R9및 R10은 각각 독립적으로 메틸 또는 에틸이며, R11은 부틸인 조성물.
- 제3항에 있어서, R2및 R3는 메틸이며, 수지상 오가노실록산 공중합체는 제1오가노실록산 물질의 10 내지 40중량%를 구성하고, 백금-함유 촉매는 제2염화 백금산과 사이클릭 또는 선형 폴리오가노실록산과의 반응 생성물이며, 수분 경화성 오가노실록산 물질의 농도는 제1오가노실록산 물질의 중량을 기준으로 하여 0.1 내지 10중량%인 조성물.
- 제4항에 있어서, 제1오가노실록산 물질이 디메틸비닐실록시-말단 폴리디메틸실록산, 제1오가노실록산 물질의 중량을 기준으로 하여 10 내지 40중량%의 수지상 오가노실록산 공중합체, 반복 단위가 필수적으로 메틸하이드로겐실록산 단위 또는 메틸하이드로겐실록산과 디메틸실록산 단위의 혼합물로 이루어지는 경화제, 및 백금-함유 촉매로 이루어진 조성물.
- 제4항에 있어서, 수분경화성 물질이 하이드록실-말단 폴리디메틸실록산, 경화제인 메틸트리메톡시실란, 경화촉매인 테트라부틸 티타네이트, 및 보강 실리카 충진제로 이루어지는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/947,113 US4754013A (en) | 1986-12-29 | 1986-12-29 | Self-adhering polyorganosiloxane compositions |
US947,113 | 1986-12-29 | ||
US947113 | 1986-12-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880007670A true KR880007670A (ko) | 1988-08-29 |
KR960007223B1 KR960007223B1 (ko) | 1996-05-29 |
Family
ID=25485538
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870015205A KR960007223B1 (ko) | 1986-12-29 | 1987-12-29 | 자체-접착성 폴리오가노실록산 조성물 |
Country Status (10)
Country | Link |
---|---|
US (1) | US4754013A (ko) |
EP (1) | EP0273706B1 (ko) |
JP (1) | JP2533902B2 (ko) |
KR (1) | KR960007223B1 (ko) |
AU (1) | AU594849B2 (ko) |
BR (1) | BR8707083A (ko) |
CA (1) | CA1306559C (ko) |
DE (1) | DE3788343T2 (ko) |
ES (1) | ES2005493A6 (ko) |
MX (1) | MX166150B (ko) |
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CN106589377A (zh) * | 2015-10-15 | 2017-04-26 | 青岛科技大学 | 一种含乙烯基苯基聚硅氧烷及其制备方法 |
GB201703484D0 (en) | 2016-05-06 | 2017-04-19 | Dow Corning | Adhesive compositions and their applications |
GB201613414D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
GB201613412D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
GB201613397D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
GB201613399D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
GB201707437D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination adhesive compositions and their applications |
GB201707439D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination Process |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US3262830A (en) * | 1961-04-19 | 1966-07-26 | Dow Corning | Organosilicon molding compositions containing orthotitanate catalysts |
US3708467A (en) * | 1971-06-16 | 1973-01-02 | Gen Electric | Curable compositions |
US4087585A (en) * | 1977-05-23 | 1978-05-02 | Dow Corning Corporation | Self-adhering silicone compositions and preparations thereof |
JPS5434362A (en) * | 1977-08-24 | 1979-03-13 | Shin Etsu Chem Co Ltd | Curable organopolysiloxane composition |
US4311739A (en) * | 1978-03-07 | 1982-01-19 | General Electric Company | Self-bonding silicone rubber compositions |
JPS57159865A (en) * | 1981-03-27 | 1982-10-02 | Toray Silicone Co Ltd | Primer composition for bonding |
CA1195034A (en) * | 1982-03-18 | 1985-10-08 | Richard P. Eckberg | Vinyl gum cure accelerators for condensation-cure silicone |
JPS59220349A (ja) * | 1983-05-28 | 1984-12-11 | Minolta Camera Co Ltd | 付加型液状シリコ−ンゴム製定着ロ−ル |
US4558109A (en) * | 1984-07-25 | 1985-12-10 | Sws Silicones Corporation | Curable organopolysiloxane compositions |
US4537829A (en) * | 1984-09-20 | 1985-08-27 | Dow Corning Corporation | Curable silicone compositions comprising resins |
FR2577233B1 (fr) * | 1985-02-08 | 1987-02-27 | Rhone Poulenc Spec Chim | Compositions organopolysiloxaniques transformables en mousses ayant une resistance amelioree a la combustion |
US4593049A (en) * | 1985-10-16 | 1986-06-03 | Dow Corning Corporation | Method of producing elastomeric silicone foam |
US4599367A (en) * | 1985-10-16 | 1986-07-08 | Dow Corning Corporation | Water-blown silicone foam |
-
1986
- 1986-12-29 US US06/947,113 patent/US4754013A/en not_active Expired - Lifetime
-
1987
- 1987-11-19 CA CA000552213A patent/CA1306559C/en not_active Expired - Lifetime
- 1987-12-23 DE DE3788343T patent/DE3788343T2/de not_active Expired - Fee Related
- 1987-12-23 MX MX009904A patent/MX166150B/es unknown
- 1987-12-23 ES ES8703717A patent/ES2005493A6/es not_active Expired
- 1987-12-23 EP EP87311360A patent/EP0273706B1/en not_active Expired - Lifetime
- 1987-12-24 AU AU83067/87A patent/AU594849B2/en not_active Ceased
- 1987-12-28 BR BR8707083A patent/BR8707083A/pt unknown
- 1987-12-28 JP JP62330397A patent/JP2533902B2/ja not_active Expired - Fee Related
- 1987-12-29 KR KR1019870015205A patent/KR960007223B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU8306787A (en) | 1988-06-30 |
EP0273706A3 (en) | 1989-04-26 |
DE3788343T2 (de) | 1994-06-09 |
US4754013A (en) | 1988-06-28 |
JP2533902B2 (ja) | 1996-09-11 |
ES2005493A6 (es) | 1989-03-01 |
MX166150B (es) | 1992-12-22 |
JPS63172768A (ja) | 1988-07-16 |
BR8707083A (pt) | 1988-08-02 |
CA1306559C (en) | 1992-08-18 |
AU594849B2 (en) | 1990-03-15 |
EP0273706A2 (en) | 1988-07-06 |
KR960007223B1 (ko) | 1996-05-29 |
EP0273706B1 (en) | 1993-12-01 |
DE3788343D1 (de) | 1994-01-13 |
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