KR880007234A - 접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법 및 신규의 복합필름 - Google Patents

접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법 및 신규의 복합필름 Download PDF

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KR880007234A
KR880007234A KR870014818A KR870014818A KR880007234A KR 880007234 A KR880007234 A KR 880007234A KR 870014818 A KR870014818 A KR 870014818A KR 870014818 A KR870014818 A KR 870014818A KR 880007234 A KR880007234 A KR 880007234A
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film
composite
polyester film
sulfonated
sulfonated copolyester
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KR870014818A
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그로스쟝 삐에르
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로제 리우프 레이
롱쁠랑 필름
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Publication of KR880007234A publication Critical patent/KR880007234A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886—Dicarboxylic acids and dihydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/795—Photosensitive materials characterised by the base or auxiliary layers the base being of macromolecular substances
    • G03C1/7954—Polyesters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
    • G03C1/93—Macromolecular substances therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

내용 없음.

Description

접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법 및 신규의 복합필름
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 결정화 가능한 폴리에스테르 및 옥시술포닐기함유 코폴리에스테르의 동시 압출, 이렇게 얻은 복합체의 냉각, 적어도 1방향의 연신 및 열경화에 의하여, 그 표면들 중 적어도 1면에 술폰화 코폴리에스테르-기본 접착 프라이머 피막의 접촉층(B)을 갖는 두께 40㎛ 이상인 결정성 또는 반결정성 폴리에스테르 지지필름(A)으로 구성된, 각종 최종 도막에 대한 접착성이 개량된 복합 폴리에스테르 필름을 제조함에 있어서, 술폰화 코폴리에스테르는 비-술폰화된 2산으로 부터 유도되는 반복단위의 총량에 대하여 테레프탈레이트 반복단위를 80몰% 이상, 그리고 동일한 성질의 반복단위의 총량에 대하여 옥시술포닐기함유 반복단위를 3 내지 10몰% 함유함을 특징으로 하는 접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법.
  2. 제1항에 있어서 층(A)의 제조에 사용되는 결정화 가능한 폴리에스테르는 테레프탈레이트 단위를 80몰% 이상 함유하는 테레프탈산의 호모폴리에스테르 또는 코폴리에스테르임을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필림의 제조방법.
  3. 제2항에 있어서, 층(A)의 제조에 사용되는 결정화 가능한 폴리에스테르는 에틸렌글리콜 폴리테레프탈레이트임을 특징으로 하는 접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법.
  4. 제1항 내지 3항 중 어느 하나에 있어서, 층(B)의 구성성분으로 사용되는 술폰화 코폴리에스테르는 하기 식으로 표시되는 복수의 옥시술포닐기를 가짐을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법:
    (-SO3)nM (⅓)
    상기식에서, n은 1 또는 2이고, M은 수소원자, 알칼리금속, 알칼리토금속, 암모늄양이온 또는 4차 암모늄 양이온임.
  5. 제1항 내지 4항중 어느 하나에 있어서, 술폰화 코폴리에스테르는 하기식의 방향족 2산 또는 이들의 유도체로부터 유도되는 복수의 단위를 가짐을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법:
    상기식에서 n은 1 또는 2이고, M은 수소원자, 알칼리금속, 알칼리토금속, 앙모늄 양이온 또는 4차 암모늄 양이온이고, Z는 다가 방향족 라디칼이고, X 및 Y는 히드록시카르보닐라디칼 또는 유도체: 저급 지방족 알코올라디칼 또는 산할라이드(염화물 또는 브롬화물)이고, p는 1 또는 2의 정수임.
  6. 제1항 내지 5항에 있어서, 술폰화 코폴리에스테르는 히드록시술포닐이소프탈산으로부터 유도되는 복수의 단위를 가짐을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법.
  7. 제6항에 있어서, 술폰화 코폴리에스테르는 이소프탈산으로부터 유도되는 복수의 단위를 가짐을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법.
  8. 제7항에 있어서, 술폰화 코폴리에스테르내에서 이소프탈산으로부터 유도되는 단위의 수는 테레프탈레이트/이소프탈레이트 단위들의 총수의 20% 이하임을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법.
  9. 제1항 내지 8항중 어느 하나에 있어서, 술폰화 코폴리에스테르는 에틸렌글리콜 및/또는 그의 분자량 600이하인 올리고머로부터 유도되는 복수의 단위를 가짐을 특징으로 하는 접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법.
  10. 제9항에 있어서, 술폰화 코폴리에스테르내에서 에틸렌글리콜 올리고머로부터 유도되는 단위의 중량 함량은 2 내지 30% 임을 특징으로 하는 접착성이 개량된 두꺼운 복합폴리에스테르 필름의 제조방법.
  11. 그 표면들중 적어도 1면에 슬폰화 코폴리에스테르-기본 접착 프라이머 피막의 접촉층(B)을 갖는 두께 40㎛ 이상인 결정성 또는 반결정성 지지필름(A)으로 구성된, 각종 최종도막에 대한 접착성이 개량된 배향된 복합 폴리에스테르 필름으로서, 층(B)를 형성하는 술폰화 코폴리에스테르는 비-술폰화된 2산으로부터 유도되는 반복단위의 총수에 대하여 테레프탈레이트 반복단위를 80몰% 이상, 그리고 동일한 성질의 반복단위의 총수에 대하여 옥시술포닐기 함유 반복단위를 3 내지 10몰% 함유함을 특징으로 하는 최종도막에 대한 접착성이 개량된 배향된 복합폴리에스테르 필름.
  12. 제11항에 있어서, 층(들)(B)의 두께가 0.3내지 1026Ⅶ의 범위이내임을 특징으로 하는 최종도막에 대한 접착성이 개량된 배향된 복합폴리에스테르 필름.
  13. 그 표면들 중 적어도 1면에 술폰화 코폴리에스테르-기본 접착 프라이머 피막의 층(B)위에 부착시킨 도막을 갖는 두께 40㎛ 이상인 결정성 또는 반결정성 배향된 폴리에스테르 지지필름(A)으로 구성되며, 상기 층(B)는 제1항 내지 제10항 증 어느 하나에 따른 술폰화 코폴리에스테르로 구성됨을 특징으로 하는 복잡한 복합필름.
  14. 제13항에 있어서, 그 표면들 중 적어도 1면에 최종도막을 갖는 두께 40㎛ 이상인 결정성 또는 반결정성 배향된 폴리에스테르 지지필름(A)로 구성되며 최종 도막은 매트 피막(mat coating)임을 특징으로 하는 복잡한 복합필름.
  15. 제13항에 있어서, 그 표면들 중 적어도 1면에 최종도막을 갖는 두께 40㎛ 이상인 결정성 또는 반결정성 배양된 폴리에스테르 지지필름(A)로 구성되며 최종 도막은 디아조 피막임을 특징으로 하는 복잡한 복합필름.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870014818A 1986-12-23 1987-12-23 접착성이 개량된 두꺼운 복합 폴리에스테르 필름의 제조방법 및 신규의 복합필름 KR880007234A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8618230A FR2608506B1 (fr) 1986-12-23 1986-12-23 Procede d'obtention de films polyester composites epais a adherence amelioree et nouveaux films composites
FR86/18230 1986-12-23

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KR880007234A true KR880007234A (ko) 1988-08-26

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US (1) US4883706A (ko)
EP (1) EP0275801B1 (ko)
JP (1) JPS63168349A (ko)
KR (1) KR880007234A (ko)
BR (1) BR8707196A (ko)
DE (1) DE3770938D1 (ko)
FR (1) FR2608506B1 (ko)

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DE3770938D1 (de) 1991-07-25
JPS63168349A (ja) 1988-07-12
FR2608506A1 (fr) 1988-06-24
FR2608506B1 (fr) 1989-03-31
BR8707196A (pt) 1988-08-16
US4883706A (en) 1989-11-28
EP0275801B1 (fr) 1991-06-19
EP0275801A1 (fr) 1988-07-27

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