KR880004026A - 그래프트된 블록 공중합체, 내충격성 중합체 조성물 및 그들의 제조방법 - Google Patents

그래프트된 블록 공중합체, 내충격성 중합체 조성물 및 그들의 제조방법 Download PDF

Info

Publication number
KR880004026A
KR880004026A KR870010547A KR870010547A KR880004026A KR 880004026 A KR880004026 A KR 880004026A KR 870010547 A KR870010547 A KR 870010547A KR 870010547 A KR870010547 A KR 870010547A KR 880004026 A KR880004026 A KR 880004026A
Authority
KR
South Korea
Prior art keywords
component
weight
block
composition
copolymer
Prior art date
Application number
KR870010547A
Other languages
English (en)
Other versions
KR960013123B1 (ko
Inventor
젤리스 리차드
가아디너 루츠 로버어트
피이터 저어젠 윌리엄
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/911,555 external-priority patent/US4795782A/en
Application filed by 오노 알버어스, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR880004026A publication Critical patent/KR880004026A/ko
Priority to KR1019960027445A priority Critical patent/KR960013075B1/ko
Application granted granted Critical
Publication of KR960013123B1 publication Critical patent/KR960013123B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

그래프트된 블록 공중합체, 내충격성 중합체 조성물 및 그들의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. 성분(b) 및/또는 성분(c)가 산화합물이나 산화합물의 유도체로 그래프트되며, 성분(a),(b) 및 (c)의 백분율의 합이 100인 하기 (a)-(c)의 성분으로 이루어지는 것을 특징으로 하는 내충격성 중합체 조성물; 성분(a) 5,000이상의 수평균 분자량을 갖는 폴리아미드 1-95중량%; 성분(b)폴리올레핀 1-95중량%; 및 성분(c)탄성 중합체 1-50중량%.
  2. 제1항에 있어서, 성분(c)가 (i)산 화합물이나 산 화합물의 유도체 및 (ⅱ)폴리올레핀으로 그래프트되며, 성분(b)는 산 화합물이나 산 화합물의 유도체로 그래프트되지 않으며, 조성물이 성분(b)의 폴리올레핀을 1-50중량% 함유하는 조성물.
  3. 제1항 또는 제2항에 있어서, 성분(c)의 탄성종합체가 올레핀 공중합체인 조성물.
  4. 제3항에 있어서, 올레핀 공중합체가 에틸렌, 프로필렌 및 하나 이상의 비공역 디엔의 공중합체인 조성물.
  5. 제1항 또는 제2항에 있어서, 성분(c)의 탄성중합체가 아크릴산 함유 중합체인 조성물.
  6. 제1항 또는 제2항에 있어서, 성분(c)의 탄성종합체는 하기 일반식 Ⅰ의 선택적으로 수소화된 블록 공중합체로서, 블록A는 공중합체의 5-95중량%를 이루며 블록 B의 불포화는 원래 불포화의 20%이하이고 블록 A의 불포화는 원래 불포화의 50%이상인 조성물;
    Bn(AB)OAP
    여기에서 각각의 A는 지배적으로 2,000∼115,000의 평균 분자량을 갖는 중합된 모노알케닐 방향족 탄화수소블록이고, 수소화 전의 각각의 B는 지배적으로 20,000-450,000의 평균 분자량을 갖는 중합된 공역 디엔 탄화수소 블록이고, n은 0 또는 1이고, o는 1-100이며, p는 0이나 1이다.
  7. 제6항에 있어서, 일반식 Ⅰ의 블록 공중합체가 선택적으로 수소화된 스틴렌-부타디엔-스티렌-블록 공중합체인 조성물.
  8. 제6항 또는 제7항에 있어서, 블록 B는 원래 값의 5% 이하의 불포화를 가지며, 블록 A에서 10%이하의 모노알케닐 방향족 탄화수소의 평균이 각각 4,000-60,000과 35,000-150,000의 평균 분자량을 갖는 수소화된 블록 A와 B이며, 축합된 부타디엔 단위의 35-50%는 1,2-배열을 갖는 조성물.
  9. 제1항 내지 제8항중 어느 하나에 있어서, 폴리올레핀 및/또는 탄성종합체에 그래프된 산 화합물이 카르복실산인 조성물.
  10. 제9항에 있어서, 카르복실산이 말레산인 조성물.
  11. 제1항 내지 제10항중 어느 하나에 있어서, 성분(b)의 폴리올레핀이 폴리프로필렌, 폴리부틸렌, 고밀도 폴리에틸렌, 저밀도 폴리에틸렌이나 에틸렌비닐 아세테이트 공중합체인 조성물.
  12. 제1항 내지 제11항중 어느 하나에 있어서, 성분(a)의 폴리아미드가 폴리헥사메틸렌 아디프아미드인 조성물.
  13. 제1항 내지 제11항중 어느 하나에 있어서, 폴리아미드가 폴리헥사메틸렌 세바스아미드, 폴리카프로락탐, 폴리헥사메틸렌 이소프탈아미드, 폴리헥사메틸렌 테레-코-이소프탈아미드 혹은 그 혼합물이나 공중합체인 조성물.
  14. 제1항 내지 제13항중 어느 하나에 있어서, 성분(c)가 성분(c)를 기준으로 계산했을때 0.02∼20중량%의 그래프트된 산 화합물이나 그 유도체부분을 갖는 조성물.
  15. 제1항 내지 제14항중 어느 하나에 있어서, 성분(b)가 폴리올레핀을 기준으로 계산했을 때 1-10중량%의 산 화합물이나 그 유도체로 그래프트 된 조성물.
  16. 제1항 및 제3항 내지 제15항중 어느 하나에 있어서, 성분(a) 10-70중량%, 성분(b)10-70중량%와 성분(c)1-50중량%(세가지성분(a),(b) 및 (c)의 백분률의 합은 100이다)로 이루어진 조성물.
  17. 제2항내지 제15항중 어느 하나에 있어서, 성분(a) 40∼90중량%, 성분(b)5∼30중량%, 성분(c)5∼30중량%와 블록 공중합체가 산화합물이나 산화합물의 유도체로 그래프트된 일반식(Ⅰ)의 관능화 선택적으로 수소화된 블록 공중합체인 성분(d) 0∼30중량% (네가지 성분(a),(b),(c) 및 (d)의 백분율의 합은 100이다)로 이루어진 조성물.
  18. 제17항에 있어서, 성분(d)가 5∼30중량%로 존재하는 조성물.
  19. 블록 A는 공중합체의 5∼95중량%를 이루며, 블록 B의 불포화는 원래 불포화의 20%이하이며, 블록 A의 불포화는 원래 불포화의 50%이상인 하기 일반식을 갖는 선택적으로 수소화된 블록 공중합체로 이루어진 (a)산 부분이나 그 유도체 및 (b) 폴리올레핀으로 그래프트된 블록 공중합체.
    Bn(AB)OAP
    여기에서 각각의 A는 지배적으로 2,000∼115,000의 평균 분자량을 갖는 중합화된 모노알케닐 방향족 탄화수소 블록이고, 수소화전의 각각의 B는 지배적으로 20,000∼450,000의 평균 분자량을 갖는 중합화된 공역 디엔 탄화수소 블록이며, n은 0 또는 1이고, o는 1∼100이며, p는 0 또는 1이다.
  20. (a)제6항의 일반식(Ⅰ)을 갖는 선택적으로 수소화된 블록 공중합체, (b)산 화합물이나 산화합물의 유도체 및 (c)폴리올레핀을 용융 혼합하고, 유리 라디칼 개시제를 첨가하고, 유리 라디칼 상태하에서 그래프트 반응시키고, 그래프트 블록 공중합체 생성물을 회수하는 것으로 구성되는 제19항의 그래프트된 블록 공중합체의 제조 방법.
  21. 성분(b)와 (c)중 적어도 하나가 산화합물이나 산화합물의 유도체로 그래프트되며, 성분(a),(b) 및 (c)의 백분율의 합이 100인 하기 (a)∼(c)의 성분들을 용융 혼합하는 것으로 구성되는 내충격성 중합체 조성물의 제조방법: 성분(a) 5,000이상의 수 평균 분자량을 갖는 폴리아미드 1∼95 중량%, 성분(b) 폴리올레핀 1∼95중량% 및 성분(c)탄성중합체 1∼50중량%.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870010547A 1986-09-25 1987-09-23 내충격성 중합체 조성물 및 그 제조 방법 KR960013123B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960027445A KR960013075B1 (ko) 1986-09-25 1996-07-08 그래프트된 블록 공중합체 및 그 제조 방법

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US91155686A 1986-09-25 1986-09-25
US91155986A 1986-09-25 1986-09-25
US91155786A 1986-09-25 1986-09-25
US91155886A 1986-09-25 1986-09-25
US911,557 1986-09-25
US911,555 1986-09-25
US911,556 1986-09-25
US06/911,555 US4795782A (en) 1986-09-25 1986-09-25 Impact resistant blends of thermoplastic polyamides, functionalized polyolefins and functionalized elastomers
US911,558 1986-09-25
US911,559 1986-09-25

Publications (2)

Publication Number Publication Date
KR880004026A true KR880004026A (ko) 1988-06-01
KR960013123B1 KR960013123B1 (ko) 1996-09-30

Family

ID=27542294

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870010547A KR960013123B1 (ko) 1986-09-25 1987-09-23 내충격성 중합체 조성물 및 그 제조 방법

Country Status (8)

Country Link
EP (1) EP0261748B1 (ko)
JP (2) JP2602664B2 (ko)
KR (1) KR960013123B1 (ko)
AU (1) AU602725B2 (ko)
DE (1) DE3781353T2 (ko)
DK (1) DK171897B1 (ko)
ES (1) ES2033809T3 (ko)
NO (1) NO173283C (ko)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE67770T1 (de) * 1985-08-16 1991-10-15 Shell Int Research Modifizierte blockcopolymere, diese copolymere enthaltende zusammensetzungen und verfahren zur herstellung dieser copolymere.
CN1030459C (zh) * 1986-10-30 1995-12-06 三井石油化学工业株式会社 热塑性树脂组合物
US4772649A (en) * 1986-12-18 1988-09-20 The Dow Chemical Company Polyesteramide and sufficient carbodiimide to impart improved compression set
WO1988006174A1 (en) * 1987-02-13 1988-08-25 Dexter Corporation Blends of polyamides with graft compounds
EP0294062B1 (en) * 1987-06-03 1993-09-01 Ube Industries, Ltd. Resin compositions and molded products thereof
WO1989004348A1 (en) * 1987-11-05 1989-05-18 Allied-Signal Inc. Polyamide composition resistant to fluorocarbon and hydrocarbon permeation
JPH01311148A (ja) * 1988-06-09 1989-12-15 Tonen Sekiyukagaku Kk ポリエチレン組成物
JPH01311146A (ja) * 1988-06-09 1989-12-15 Tonen Sekiyukagaku Kk 熱可塑性樹脂組成物
US4937290A (en) * 1988-09-26 1990-06-26 The Goodyear Tire & Rubber Company Nylon modified rubber composition wherein either nylon or rubber or both are reacted with a thio acid
US5070143A (en) * 1989-03-09 1991-12-03 Morton International, Inc. Adhesive blend of polyolefins and grafted block copolymer of polystyrene
DE3911695A1 (de) * 1989-04-10 1990-10-11 Inventa Ag Verbundwerkstoffe und ihre verwendung
EP0494145B1 (en) * 1989-09-25 1994-09-21 AlliedSignal Inc. Impact resistant polyamide composition
IT1237127B (it) * 1989-11-09 1993-05-18 Montedipe Srl Composizioni termoplastiche a base di un copolimero vinil aromatico e di una resina poliammidica.
DE4029226A1 (de) * 1990-09-14 1992-03-19 Du Pont Polyamid/polypropylen-blends
US5292805A (en) * 1992-05-29 1994-03-08 Amoco Corporation Filled polyphthalamide blends having improved processability and composite and filled articles therefrom
AT399158B (de) * 1991-09-13 1995-03-27 Danubia Petrochem Polymere Verwendung von aus polyolefinen, polyamiden und haftvermittlern bestehenden formteilen zur hochfrequenzschweissung, sowie folien aus polyolefinen, polyamiden und haftvermittlern
DE4142271A1 (de) * 1991-12-20 1993-06-24 Danubia Petrochem Deutschland Verfahren zum schweissen von aus polyolefinen, polyamiden und haftvermittlern bestehenden formteilen durch hochfrequenzschweissung, sowie folien aus polyolefinen, polyamiden und haftvermittlern
KR930021723A (ko) * 1992-04-03 1993-11-22 미리암 디. 메코너헤이 저온 강화 폴리아미드
DE4407712A1 (de) * 1993-03-24 1994-09-29 Inventa Ag Ternäre Polymermischung und ihre Verwendung
KR950003089A (ko) * 1993-07-26 1995-02-16 만프레트 래츠슈, 일 요르간 개질된 탄성중합체성 폴리프로필렌
AT403583B (de) * 1993-07-26 1998-03-25 Danubia Petrochem Polymere Modifizierte elastomere polypropylene
GB9519381D0 (en) * 1995-09-22 1995-11-22 Exxon Chemical Patents Inc Rubber toughened blends
GB9617507D0 (en) 1996-08-21 1996-10-02 Exxon Chemical Patents Inc Chemically modified elastomeres and blends thereof
DE19715120A1 (de) * 1997-04-11 1998-10-15 Basf Ag Thermoplastische Formkörper mit Segmenten unterschiedlicher Steifigkeit
EP1670857B1 (en) * 2003-10-10 2015-03-18 ExxonMobil Chemical Patents Inc. Compostions of polypropylene and polyamide
JP4946387B2 (ja) * 2006-11-27 2012-06-06 住友電気工業株式会社 ポリマーの無水マレイン酸含有量の定量方法
DE102007030801B4 (de) 2007-06-29 2010-11-04 Kometra Kunststoff-Modifikatoren Und -Additiv Gmbh Thermoplastisch verarbeitbare carboxylierte Styrol-Olefin-Blockcopolymer/Polyolefin-Kompositionen und ihre Verwendung
DE102007038578A1 (de) 2007-08-16 2009-02-19 Evonik Degussa Gmbh Verfahren zur Dekorierung von Oberflächen
FR2933978B1 (fr) * 2008-07-18 2012-12-21 Arkema France Fabrication d'anhydride maleique a partir de matieres renouvelables, anhydride maleique obtenu et utilisations
JP5836923B2 (ja) * 2011-12-22 2015-12-24 トヨタ紡織株式会社 植物由来ポリアミド樹脂を用いた熱可塑性樹脂組成物及び成形体
CN103998512B (zh) * 2011-12-22 2017-04-26 丰田纺织株式会社 热塑性树脂组合物及其制造方法以及成型体
US9353251B2 (en) 2011-12-22 2016-05-31 Toyota Boshoku Kabushiki Kaisha Thermoplastic resin composition and method for producing same
JP5879253B2 (ja) * 2011-12-22 2016-03-08 トヨタ紡織株式会社 熱可塑性樹脂組成物及びその製造方法
US10078261B2 (en) * 2013-09-06 2018-09-18 Rohm And Haas Electronic Materials Llc Self-assembled structures, method of manufacture thereof and articles comprising the same
RU2725668C2 (ru) 2015-12-01 2020-07-03 Тойота Босоку Кабусики Кайся Модификатор, его применение, способ производства модификатора и носитель для вспомогательного материала
WO2017094737A1 (ja) 2015-12-01 2017-06-08 トヨタ紡織株式会社 成形体及びその製造方法
SG11201806672XA (en) 2016-03-11 2018-09-27 Toyota Boshoku Kk Foamed resin molded article and method for manufacturing same
JP6288142B2 (ja) 2016-03-31 2018-03-07 トヨタ紡織株式会社 分散径の調整方法及び熱可塑性樹脂組成物
JP6916459B2 (ja) * 2016-06-22 2021-08-11 株式会社豊田中央研究所 樹脂組成物

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4174358A (en) * 1975-05-23 1979-11-13 E. I. Du Pont De Nemours And Company Tough thermoplastic nylon compositions
DE2612011A1 (de) * 1976-03-20 1977-09-22 Bayer Ag Verfahren zur herstellung von schlagzaehen thermoplastischen formmassen
US4085163A (en) * 1976-06-07 1978-04-18 Shell Oil Company Multicomponent polyamide-block copolymer-polymer blends
CA1110374A (en) * 1977-04-22 1981-10-06 William P. Gergen Compositions containing hydrogenated block copolymers and engineering thermoplastic resins
JPS55165952A (en) * 1979-06-14 1980-12-24 Unitika Ltd Polyamide composition
DE3151441A1 (de) * 1981-12-24 1983-07-14 Bayer Ag, 5090 Leverkusen Schlagzaehe polyamid-formmassen
JPS59131642A (ja) * 1983-01-19 1984-07-28 Mitsui Petrochem Ind Ltd ポリアミド組成物
JPS59149940A (ja) * 1983-02-16 1984-08-28 Mitsui Petrochem Ind Ltd プロピレン重合体組成物
JPS6176518A (ja) * 1984-08-31 1986-04-19 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 変性されたブロツクコポリマーおよびその製造方法
EP0173380A1 (en) * 1984-08-31 1986-03-05 Shell Internationale Researchmaatschappij B.V. Modified block copolymers and processes for the preparation therefore.
JPS61141743A (ja) * 1984-12-13 1986-06-28 Mitsubishi Petrochem Co Ltd 熱可塑性樹脂組成物
CA1289686C (en) * 1985-07-31 1991-09-24 Richard Gelles Impact resistant polymeric compositions

Also Published As

Publication number Publication date
DE3781353T2 (de) 1992-12-10
EP0261748A3 (en) 1989-02-22
ES2033809T3 (es) 1993-04-01
NO173283C (no) 1993-11-24
AU602725B2 (en) 1990-10-25
JP2712016B2 (ja) 1998-02-10
AU7890487A (en) 1988-03-31
JPH08208771A (ja) 1996-08-13
JP2602664B2 (ja) 1997-04-23
EP0261748B1 (en) 1992-08-26
DK500187A (da) 1988-03-26
NO173283B (no) 1993-08-16
EP0261748A2 (en) 1988-03-30
JPS6389550A (ja) 1988-04-20
DK171897B1 (da) 1997-08-04
KR960013123B1 (ko) 1996-09-30
NO873977L (no) 1988-03-28
DE3781353D1 (de) 1992-10-01
NO873977D0 (no) 1987-09-23
DK500187D0 (da) 1987-09-23

Similar Documents

Publication Publication Date Title
KR880004026A (ko) 그래프트된 블록 공중합체, 내충격성 중합체 조성물 및 그들의 제조방법
KR940005747A (ko) 분자량 분포가 넓은 폴리프로필렌을 함유하는 충격 개질된 그래프트 공중합체 조성물
US3830767A (en) Block copolymer compositions
US3562356A (en) Block copolymer blends with certain ethylene-unsaturated ester copolymers
KR100350087B1 (ko) 개선된표면특성을갖는열가소성탄성중합체
EP0773255B1 (en) Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber
KR910016839A (ko) 내열성 프로필렌 중합체 조성물
CS9100816A2 (en) Mixture containing styrene-grafted propylene's polymer
KR960041273A (ko) 폴리올레핀 그래프트 공중합체 및 폴리카보네이트의 혼합물
KR970705611A (ko) 폴리카보네이트와 에틸렌 중합체의 블렌드(blends of polycarbonate and ethylene polymers)
EP0396780A4 (en) Hydrogenated block copolymer and composition thereof
KR940005748A (ko) 유리 섬유 강화 중합체 조성물
KR910006397A (ko) 폴리올레핀과 스티렌 수지의 성형가능한 폴리블렌드
KR930021709A (ko) 모노비닐 방향족-공역디엔 블럭 공중합체 브렌드 조성물 및 그로 구성되는 물품
US4690976A (en) Blends of olefinic and monovinylidene aromatic polymers
KR950014162A (ko) 방사상 또는 성상 비대칭 블록 공중합체
KR960703140A (ko) 고체상 탄성 블록 공중합체(solid elastomeric block copolymers)
KR930701542A (ko) 개선된 내용제성 및 내충격성을 갖는 열가소성 성형조성물 및 그의 용도
US5420198A (en) Process for the preparation of polymide blends having improved low temperature properties
US3538193A (en) Recovery of polymeric materials from organic reaction mixtures
KR930019759A (ko) 충격 개질제로서 폴리아크릴레이트의 그래프트 공중합체를 함유하는 열가소성 블렌드
KR900000424A (ko) 폴리 아미드 조성물
KR960004431A (ko) 헤테로상 올레핀 중합체 물질로 내충격성 개질된 프로필렌 중합체 물질의 그래프트 공중 합체
EP0346837B1 (en) Vulcanized, ethylene/alpha-olefin copolymer rubber composition
KR890701693A (ko) 가요성이고, 클로로플루오로 탄화수소 침투저항성이 있는 폴리아미드 조성물

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20030826

Year of fee payment: 8

LAPS Lapse due to unpaid annual fee