KR880003925A - 벤즈옥사진, 그의 제조방법 및 용도 - Google Patents

벤즈옥사진, 그의 제조방법 및 용도 Download PDF

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Publication number
KR880003925A
KR880003925A KR870009907A KR870009907A KR880003925A KR 880003925 A KR880003925 A KR 880003925A KR 870009907 A KR870009907 A KR 870009907A KR 870009907 A KR870009907 A KR 870009907A KR 880003925 A KR880003925 A KR 880003925A
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hydrogen
formula
compound
group
general formula
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KR870009907A
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English (en)
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구메도요히꼬
도시오 고또
아쭈미 가모찌
나오꼬 야마구찌
아끼히꼬 야나기
히데노리 하야까와
시게끼 야기
히로시 미야우찌
Original Assignee
다데노 고자부로
니혼 도꾸슈 노야꾸 세이죠 가부시끼 가이샤
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Priority claimed from JP21072586A external-priority patent/JPS6368587A/ja
Priority claimed from JP62027194A external-priority patent/JPS63196582A/ja
Application filed by 다데노 고자부로, 니혼 도꾸슈 노야꾸 세이죠 가부시끼 가이샤 filed Critical 다데노 고자부로
Publication of KR880003925A publication Critical patent/KR880003925A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
    • C07D265/34—1,4-Oxazines; Hydrogenated 1,4-oxazines condensed with carbocyclic rings
    • C07D265/36—1,4-Oxazines; Hydrogenated 1,4-oxazines condensed with carbocyclic rings condensed with one six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

내용 없음

Description

벤즈옥사진, 그의 제조방법 및 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 일반식(Ⅰ)의 벤즈옥사진.
    상기식에서, X는 수소 또는 할로겐이고, R1은 수소 또는 C1-C2알킬이고, R2는 시아노, 트리메틸실릴, 트리메틸실릴메톡시카보닐, C1-C4알킬티오 또는 사이클로프로필이고, Q는 그룹
  2. 제1항에 있어서, X는 수소, 불소 또는 염소이고, R1은 수소 또는 메틸이고, R2는 시아노, 트리메틸실릴, 트리메틸실릴메톡시카보닐, 메틸티오 또는 사이클로프로필이고, Q는 그룹
    일반식(Ⅰ)의 화합물.
  3. 제1항에 있어서, X는 수소 또는 불소이고, R1은 수소 또는 메틸이고, R2는 시아노이고, Q는 그룹
    일반식(Ⅰ)의 화합물.
  4. 제1항에 있어서, 하기 구조식(1)의 2-[시아노메틸-7-플루오로-2H-1,4-벤즈옥사진-3(4H)-온-6-일]-4,5,6,7-테트라하이드로-2H-이소인돌-1,3-디온; 하기구조식(2)의 2-[4-(1-시아노에틸)-플루오로-2H-1,4-벤즈옥사진-3(4H)-온-6-일]-4,5,6,7-테트라하이드로-2H-이소인돌-1,3-디온; 하기 구조식(3)의 3-[4-시아노메틸-7-플루오로-2H-1,4-벤즈옥사진-3(4H)-온-6-일]-1,5-테트라메틸렌-1,3-디아졸리딘-2,4-디온: 또는 하기 구조식(4)의 2-[4-시아노메틸-7-플루오로-2H-1,4-벤즈옥사진-3(4H)-온-6-일]-헥사하이드로-1H-(1,2,4)트리아졸로 (1,2-a)피리다진-1,3-디온인 화합물.
  5. a)일반식(Ⅱ)의 화합물을 불활성 용매의 존재하에, 경우에 따라서는 염기의 존재하에 일반식(Ⅲ)의 화합물과 반응시키거나;
    b)Q가 그룹인 경우, 일반식(Ⅳ)의 화합물을 아세트산의 존재하에 구조식의 테트라하이드로프탈산 무수물과 반응시키거나; c)Q가 그룹 또는인 경우, 일반식(Ⅴ)의 화합물을 불활성 용매의 존재하에 일반식(Ⅵ)의 화합물과 반응시킨 다음, 생성물을 산 또는 염기의 존재하에 폐환시킴을 특징으로 하여, 일반식(Ⅰ)의 벤즈옥사진을 제조하는 방법.
    상기식에서, X는 수소 또는 할로겐이고, R1은 수소 또는 C1-C2알킬이고, R2는 시아노, 트리메틸실릴, 트리메틸실리메톡시카보닐, C1-C4알킬티오 또는 사이클로프로필이고, Q는 그룹
    이고, M1은 할로겐이고, W는 그룹
    T는 수소 또는 알킬이다.
  6. 제1항 및 제5항에 따른 일반식(Ⅰ)의 벤즈옥사진을 하나 이상 함유함을 특징으로 하는 제초제 조성물.
  7. 제1항 및 제5항에 따른 일반식(Ⅰ)의 벤즈옥사진을 잡초 및/또는 그들의 서식지에 작용시킴을 특징으로 하여 잡초를 제거하는 방법.
  8. 제1항 및 제5항에 따른 일반식(Ⅰ)의 벤즈옥사진의 잡초를 제거하기 위한 것으로서의 용도.
  9. 제1항 및 제5항에 따른 일반식(Ⅰ)의 벤즈옥사진을 증량제 및/또는 계면활성제와 혼합함을 특징으로 하여 제초제 조성물을 제조하는 방법.
  10. 일반식(ⅩIⅩ)의 화합물.
    상기식에서, R1-1은 수소, 메틸 또는 에틸이고, R2-1은 시아노, 히드록시, 염소, 트리메틸실릴, 트리메틸실릴 메톡시카보닐, C1-C4-알킬티오 또는 사이클로프로필이고, A는 수소, 아미노 또는 니트로이며, X1은 수소 또는 할로겐이고, 단, R2-1이 염소 또는 히드록시일 경우, A는 니트로이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870009907A 1986-09-09 1987-09-08 벤즈옥사진, 그의 제조방법 및 용도 KR880003925A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP210725 1986-09-09
JP21072586A JPS6368587A (ja) 1986-09-09 1986-09-09 テトラヒドロフタルイミド類及び除草剤
JP62027194A JPS63196582A (ja) 1987-02-10 1987-02-10 ベンゾオキサジン類及び除草剤
JP27194 1987-02-10

Publications (1)

Publication Number Publication Date
KR880003925A true KR880003925A (ko) 1988-05-31

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Country Link
US (1) US4804394A (ko)
EP (1) EP0263299B1 (ko)
KR (1) KR880003925A (ko)
BR (1) BR8704655A (ko)
DE (1) DE3766066D1 (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3807295A1 (de) * 1988-03-05 1989-09-14 Basf Ag Neue n-heteroaryl-tetrahydrophthalimidverbindungen
DE3832348A1 (de) * 1988-03-10 1989-09-28 Bayer Ag Substituierte benzoxazinone, mehrere verfahren sowie neue zwischenprodukte zu ihrer herstellung sowie ihre herbizide verwendung
JPH0215082A (ja) * 1988-07-04 1990-01-18 Nippon Tokushu Noyaku Seizo Kk 新規ヘテロ環式化合物及び除草剤
JPH0283383A (ja) * 1988-09-20 1990-03-23 Nippon Tokushu Noyaku Seizo Kk 新規ジメチルマレインイミド類及びその除草剤としての利用
JPH02138183A (ja) * 1988-11-17 1990-05-28 Nippon Tokushu Noyaku Seizo Kk 除草性ピロール類
JPH02160781A (ja) * 1988-12-14 1990-06-20 Nippon Tokushu Noyaku Seizo Kk ベンゾアゾール類及び除草剤としての利用
USRE37664E1 (en) * 1989-02-25 2002-04-16 Basf Aktiengessellschaft Use of derivatives of N-phenl-3,4,5,6-tetrahydrophthalimide for the desiccation and abscission of plant organs
DE3905916A1 (de) * 1989-02-25 1990-08-30 Basf Ag Verwendung von derivaten des n-phenyl-3,4,5,6-tetrahydrophthalimids zur desikkation und abszission von pflanzenorganen
DE3922847A1 (de) * 1989-07-07 1991-01-17 Schering Ag Substituierte benzoxazolinon- und benzoxazinon-derivate, verfahren zu ihrer herstellung und ihre verwendung als mittel mit herbizider wirkung
DE3936826A1 (de) * 1989-11-04 1991-05-08 Bayer Ag N-aryl-stickstoffheterocyclen
DE4008691A1 (de) * 1990-03-15 1991-09-19 Schering Ag Verfahren und zwischenprodukte zur herstellung von substituierten 6-(3,5,6,7-tetrahydropyrrolo(2,1-c)(1,2,4)-thiadiazol-3-ylidenimino)-7-fluor-2h-1,4-benzoxazin-3(4h)-onen
EP0448188A3 (en) * 1990-03-15 1992-02-26 Schering Aktiengesellschaft Process and intermediates for the preparation of substituted 6-(3,5,6,7-tetrahydropyrrolo-(2,1-c)(1,2,4)-thiadiazol-3-ylidenimino)-7-fluoro-2h-1,4-benzoxazin-3(4h)-ones
JP2677115B2 (ja) * 1991-09-30 1997-11-17 住友化学工業株式会社 イミン化合物およびその製造方法
US5410050A (en) * 1991-09-30 1995-04-25 Sumitomo Chemical Company, Limited Imine compounds and their production
BR9510107A (pt) * 1994-12-27 1997-11-25 Sagami Chem Res Derivados de hidantoina processos para preparação dos mesmos e herbicidas contendo os referidos derivados como ingrediente ativo
DE10034800A1 (de) * 2000-07-18 2002-01-31 Bayer Ag Substituierte Benzostickstoffheterocyclen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4640707A (en) * 1984-07-23 1987-02-03 Sumitomo Chemical Company, Ltd. Tetrahydrophthalimides and their herbicidal use
US4619687A (en) * 1984-09-27 1986-10-28 Sumitomo Chemical Company, Limited Triazolopyridazines and their use as herbicides
JPS6314782A (ja) * 1986-07-07 1988-01-21 Nippon Tokushu Noyaku Seizo Kk 新規ジアルキルマレインイミド類及び除草剤
US4734124A (en) * 1987-01-15 1988-03-29 Fmc Corporation Tetrazolinone herbicides

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EP0263299A1 (de) 1988-04-13
EP0263299B1 (de) 1990-11-07
BR8704655A (pt) 1988-04-26
DE3766066D1 (de) 1990-12-13
US4804394A (en) 1989-02-14

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