KR880000390B1 - 옥살산 디에스테르의 수소화 반응에 유용한 수소화반응 촉매 조성물 - Google Patents

옥살산 디에스테르의 수소화 반응에 유용한 수소화반응 촉매 조성물 Download PDF

Info

Publication number
KR880000390B1
KR880000390B1 KR8201915A KR820001915A KR880000390B1 KR 880000390 B1 KR880000390 B1 KR 880000390B1 KR 8201915 A KR8201915 A KR 8201915A KR 820001915 A KR820001915 A KR 820001915A KR 880000390 B1 KR880000390 B1 KR 880000390B1
Authority
KR
South Korea
Prior art keywords
copper
hydrogenation
catalyst
oxalate
catalyst composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
KR8201915A
Other languages
English (en)
Korean (ko)
Other versions
KR830009807A (ko
Inventor
하루히꼬 미야자끼
다이조 우다
고오이찌 히라이
야스오 나까무라
하루미 이께자와
다까노리 쓰찌에
Original Assignee
미즈노 가즈오
우베고오산 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 미즈노 가즈오, 우베고오산 가부시끼가이샤 filed Critical 미즈노 가즈오
Publication of KR830009807A publication Critical patent/KR830009807A/ko
Application granted granted Critical
Publication of KR880000390B1 publication Critical patent/KR880000390B1/ko
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR8201915A 1981-04-30 1982-04-30 옥살산 디에스테르의 수소화 반응에 유용한 수소화반응 촉매 조성물 Expired KR880000390B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP64,015 1981-04-30
JP56064015A JPS6045938B2 (ja) 1981-04-30 1981-04-30 シュウ酸ジエステルの水素添加触媒の製造法
JP64015 1981-04-30

Publications (2)

Publication Number Publication Date
KR830009807A KR830009807A (ko) 1983-12-23
KR880000390B1 true KR880000390B1 (ko) 1988-03-21

Family

ID=13245915

Family Applications (1)

Application Number Title Priority Date Filing Date
KR8201915A Expired KR880000390B1 (ko) 1981-04-30 1982-04-30 옥살산 디에스테르의 수소화 반응에 유용한 수소화반응 촉매 조성물

Country Status (12)

Country Link
US (2) US4440873A (enExample)
EP (1) EP0064241B1 (enExample)
JP (1) JPS6045938B2 (enExample)
KR (1) KR880000390B1 (enExample)
AU (1) AU545198B2 (enExample)
BR (1) BR8202478A (enExample)
CA (1) CA1187067A (enExample)
DE (1) DE3265984D1 (enExample)
GB (1) GB2099715B (enExample)
IN (1) IN157792B (enExample)
MY (1) MY8700343A (enExample)
ZA (1) ZA822887B (enExample)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58193735A (ja) * 1982-05-06 1983-11-11 Ube Ind Ltd 低級ヒドロキシカルボン酸エステルの水素添加用触媒の製法
JPS58207945A (ja) * 1982-05-28 1983-12-03 Ube Ind Ltd シユウ酸ジエステルの水素添加用触媒
CA1238627A (en) * 1984-01-27 1988-06-28 Koichi Hirai Process for producing ethylene glycol, catalyst composition therefor and process for producing the catalyst composition
DE3503587A1 (de) * 1985-02-02 1986-08-07 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung eines kupfer und siliciumoxid enthaltenden katalysators
US4649226A (en) * 1986-03-27 1987-03-10 Union Carbide Corporation Hydrogenation of alkyl oxalates
EP0614875A1 (en) * 1993-03-12 1994-09-14 Ube Industries, Ltd. Method of producing a glycolic acid ester
US6455742B1 (en) 1999-09-02 2002-09-24 Wisconsin Alumni Research Foundation Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids
JP3392812B2 (ja) * 2000-06-07 2003-03-31 花王株式会社 ヒドロキシカルボン酸エステルの製造法
EP1211234A3 (en) 2000-11-29 2003-11-26 Samsung Electronics Co., Ltd. Process for preparing 1,3-alkandiols from 3-hydroxyesters
US6617478B2 (en) 2000-11-29 2003-09-09 Samsung Electronics Co., Ltd. Process for preparing a 1,3-alkandiol from 3-hydroxyester
KR100453296B1 (ko) * 2000-11-29 2004-10-15 삼성전자주식회사 3-하이드록시에스터 화합물로부터 1,3-알칸디올을제조하는 방법
KR100457416B1 (ko) * 2001-11-01 2004-11-18 삼성전자주식회사 3-히드록시에스터 화합물로부터 1,3-알칸디올을 제조하는방법
BRPI0913770B1 (pt) * 2008-12-18 2017-09-12 China Petroleum & Chemical Corporation Process for the production of ethylene glycol from an oxalate
CN101879448B (zh) 2010-06-24 2012-05-23 天津大学 用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法
WO2012074841A2 (en) * 2010-11-30 2012-06-07 Basf Corporation Copper chromite hydrogenation catalysts for production of fatty alcohols
WO2012113267A1 (zh) 2011-02-25 2012-08-30 中国石油化工股份有限公司 草酸酯通过流化床催化反应生产乙二醇的方法
CN102380381B (zh) * 2011-09-09 2013-05-01 久泰能源科技有限公司 一种纳米级超细乙二醇铜硅催化剂
CN103372453B (zh) * 2012-04-27 2015-06-03 上海浦景化工技术股份有限公司 一种用于羟基乙酸甲酯合成的催化剂及其制备方法
CN103785408B (zh) * 2014-02-12 2016-05-04 常州大学 一种草酸二甲酯加氢制备乙醇酸甲酯的催化剂及合成方法
KR20160015839A (ko) 2014-07-31 2016-02-15 삼성전자주식회사 수소화 촉매를 제조하는 방법 및 이를 이용하여 락톤으로부터 디올을 제조하는 방법
CN105777494B (zh) * 2014-12-24 2018-06-12 高化学技术株式会社 乙二醇的制备方法
CN104785261B (zh) * 2015-03-19 2017-01-11 河南能源化工集团研究院有限公司 一种混合硅源法合成草酸酯加氢催化剂及其制备方法
JP6790066B6 (ja) * 2015-07-29 2020-12-16 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ モノエチレングリコールの製造方法
JP2017171599A (ja) * 2016-03-23 2017-09-28 高化学技術株式会社 固体触媒、及びその固体触媒を用いたエチレングリコールの製造方法
CN107866224A (zh) * 2016-09-26 2018-04-03 上海华谊能源化工有限公司 催化剂及其制备方法和用途
US10266467B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols
US10544077B2 (en) 2017-08-02 2020-01-28 Eastman Chemical Company Process for making formic acid utilizing higher-boiling formate esters
US10266466B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Iron-catalyzed transfer hydrogenation of esters to alcohols
US10435349B2 (en) 2017-08-02 2019-10-08 Eastman Chemical Company Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
US10570081B2 (en) 2017-08-02 2020-02-25 Eastman Chemical Company Process for making formic acid utilizing lower-boiling formate esters
CN107519920A (zh) * 2017-08-22 2017-12-29 无锡威孚环保催化剂有限公司 旋蒸法负载铜制备Cu‑SSZ‑13分子筛催化剂的方法
CN107537552A (zh) * 2017-09-19 2018-01-05 河南能源化工集团研究院有限公司 一种草酸酯加氢制乙二醇单甲醚催化剂的制备方法
CN118751278A (zh) * 2024-06-26 2024-10-11 大连理工大学 一种抗烧结Cu-Beta沸石催化剂的制备方法和应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2305104A (en) * 1939-10-25 1942-12-15 Du Pont Hydrogenation of alkyl glycolates
GB575380A (en) * 1940-08-16 1946-02-15 Du Pont Improvements in and relating to the production of ethylene glycol
US2386518A (en) * 1943-03-04 1945-10-09 Phillips Petroleum Co Supported catalysts and process for preparation thereof
US2891094A (en) * 1955-02-17 1959-06-16 American Cyanamid Co New catalyst for reducing nitrobenzene and the process of reducing nitrobenzene thereover
BE572433A (enExample) * 1958-11-11 1900-01-01
NL132671C (enExample) * 1960-02-09
US3637528A (en) * 1967-12-06 1972-01-25 Du Pont Low temperature-shift catalyst
US3886219A (en) * 1969-01-14 1975-05-27 Huels Chemische Werke Ag Process for preparing saturated alcohols
US3888845A (en) * 1970-03-09 1975-06-10 Teijin Ltd Process for producing epsilon-caprolactam
NL7203934A (enExample) * 1972-03-24 1973-09-26
GB1426437A (en) * 1972-10-16 1976-02-25 Gte International Inc Exchange switching system
US4184982A (en) * 1977-06-14 1980-01-22 Basf Aktiengesellschaft Preparation of a silicate hydrogenation catalyst
US4174300A (en) * 1978-01-30 1979-11-13 The United States Of America, As Represented By The Secretary Of Agriculture Preparation of highly active copper-silica catalysts
US4199479A (en) * 1978-02-24 1980-04-22 Chevron Research Company Hydrogenation catalyst
IT1099070B (it) * 1978-09-14 1985-09-18 Montedison Spa Processo per la idrogenazione catalitica degli esteri ossalici
JPS58193735A (ja) * 1982-05-06 1983-11-11 Ube Ind Ltd 低級ヒドロキシカルボン酸エステルの水素添加用触媒の製法

Also Published As

Publication number Publication date
GB2099715B (en) 1984-12-12
KR830009807A (ko) 1983-12-23
IN157792B (enExample) 1986-06-21
EP0064241B1 (en) 1985-09-04
BR8202478A (pt) 1983-04-12
EP0064241A1 (en) 1982-11-10
ZA822887B (en) 1983-03-30
US4585890A (en) 1986-04-29
MY8700343A (en) 1987-12-31
DE3265984D1 (en) 1985-10-10
GB2099715A (en) 1982-12-15
JPS6045938B2 (ja) 1985-10-12
CA1187067A (en) 1985-05-14
US4440873A (en) 1984-04-03
AU545198B2 (en) 1985-07-04
JPS57180432A (en) 1982-11-06
AU8304682A (en) 1982-11-04

Similar Documents

Publication Publication Date Title
KR880000390B1 (ko) 옥살산 디에스테르의 수소화 반응에 유용한 수소화반응 촉매 조성물
JPH0829249B2 (ja) 銅−酸化亜鉛−酸化アルミニウムを含有する触媒、その製造方法およびそれをアルデヒドのアルコールへの水素化に使用する方法
CA1206135A (en) Process for producing lower alkylene glycol, catalyst composition used therefor and process for production thereof
CN114054041A (zh) 草酸二甲酯加氢催化剂、其制法及应用
KR20010041628A (ko) 지방족 알파, 오메가-디니트릴의 수소화 방법
JP4588848B2 (ja) アルコキシジヒドロピランからのペンタンジオールの製造方法
JP4123525B2 (ja) ガンマ−ブチロラクトンの製造方法
US5663458A (en) Process for producing α-phenylethyl alcohol
US4614728A (en) Catalyst composition for producing ethylene glycol and process for producing the catalyst composition
EP0097262B1 (en) A hydrogenation catalyst composition for the hydrogenation of an oxalate diester, a process for preparing same and the use thereof
GB2047219A (en) Copper chromite catalyst and its use in preparation of furfuryl alcohol from furfural by batch or liquid phase process
JPH09221437A (ja) エタノールの製造方法
JPH03857B2 (enExample)
KR100283975B1 (ko) 아민의 제조방법
KR100455665B1 (ko) 구리 성분 함유 산폐액을 사용한, 수소화 및 탈수소화반응용 구리/실리카 촉매의 제조 방법
JPH07106991B2 (ja) 部分水素化方法
KR100738232B1 (ko) 혼합 금속 산화물 촉매의 제조 방법 및 상기 촉매를 사용한장쇄 지방족 삼차 아민의 제조방법
JPH09136849A (ja) α−フェニルエチルアルコールの製造方法
JP3970489B2 (ja) Ｎ，ｎ−ジメチル−ｎ−アルキルアミンの製法
JP3021700B2 (ja) ラクトンの製造方法
JP3392812B2 (ja) ヒドロキシカルボン酸エステルの製造法
JPS6038177B2 (ja) シユウ酸ジエステルの水素添加触媒の製法
JPH05331100A (ja) Ｄｌ−グリセリン酸又はその塩の製造方法
JPH0977711A (ja) α−フェニルエチルアルコールの製造方法
JPS62192335A (ja) ジアセトンアルコ−ルの製造方法

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1605 Publication of application before grant of patent

St.27 status event code: A-2-2-Q10-Q13-nap-PG1605

PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 19950322

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 19950322

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301