KR860003999A - 저급 알코올로부터 에탄올 및 고급알코올의 제조방법 - Google Patents

저급 알코올로부터 에탄올 및 고급알코올의 제조방법 Download PDF

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Publication number
KR860003999A
KR860003999A KR1019850005474A KR850005474A KR860003999A KR 860003999 A KR860003999 A KR 860003999A KR 1019850005474 A KR1019850005474 A KR 1019850005474A KR 850005474 A KR850005474 A KR 850005474A KR 860003999 A KR860003999 A KR 860003999A
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South Korea
Prior art keywords
alcohol
catalyst
component
methanol
molybdenum
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KR1019850005474A
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English (en)
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제이. 쿠아데러 죠지 (외 3)
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리차드 지. 워터맨
더 다우 케미칼 캄파니
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Application filed by 리차드 지. 워터맨, 더 다우 케미칼 캄파니 filed Critical 리차드 지. 워터맨
Publication of KR860003999A publication Critical patent/KR860003999A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

저급 알코올로부터 에탄올 및 고급알코올의 제조방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. (1) 수소; (2) 일산화탄소; (3) (a)유리 또는 결합형의 몰리브덴, 텅스텐, 또는 이의 혼합물의 제1성분 및 (b)유리 또는 결합형의 알칼리 또는 알칼리토 원소, 또는 이의 혼합물의 제2성분을 함유하는 불균일질 촉매; 및 (4) 1종 이상의 저급 알코올을 반응시킴을 특징으로 하는 생성 알코올중의 탄소원자수가 출발 알코올중의 탄소원자수와 비교하여 증가하는 조건하에서의 고급 알코올의 제조방법.
  2. 제1항에 있어서, 촉매가 유리 또는 결합형의 코발트, 니켈 또는 철, 또는 이의 혼합물의 제3성분을 갖는 방법.
  3. 제1 또는 2항에 있어서, 촉매가 지지체인 추가성분을 갖는 방법.
  4. 제1,2 또는 3항에 있어서, 촉매중의 제1성분이 몰리브덴인 방법.
  5. 제2항에 있어서, 촉매가 몰리브덴 술피드 및 코발트 술피드를 함유하는 방법.
  6. 제1,2 또는 3항에 있어서, 제4반응물이 메탄올 함유하는 방법.
  7. 제6항에 있어서, 제4반응물이 메탄올 및 고급알코올을 함유하는 혼합 알코올 생성물을 분별 증류시켜 수득된 메탄올을 함유하는 방법.
  8. 제1항에 있어서, 수소 및 일산화탄소가 약 0.7:1 내지 약 3:1의 몰비로 존재하는 방법.
  9. 제1항에 있어서, 반응을 약 200°내지 약 400℃의 온도에서 수행하는 방법.
  10. 제1항에 있어서, 반응을 약 500psig(3.55MPa)내지 약 10,000psig(69.1MPa)의 압력하에서 수행하는 방법.
  11. 제1항에 있어서, 제4반응물 알코올의 적어도 25중량%를 고급알코올로 전환시키는 방법.
  12. 제1 내지 11항중 어느 한항에 있어서, 메탄올을 에탄올 및 다른 고급 알코올로 전환시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850005474A 1984-11-05 1985-07-30 저급 알코올로부터 에탄올 및 고급알코올의 제조방법 KR860003999A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US66859884A 1984-11-05 1984-11-05
US668.598 1984-11-05

Publications (1)

Publication Number Publication Date
KR860003999A true KR860003999A (ko) 1986-06-16

Family

ID=24682994

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850005474A KR860003999A (ko) 1984-11-05 1985-07-30 저급 알코올로부터 에탄올 및 고급알코올의 제조방법

Country Status (14)

Country Link
EP (1) EP0180719B1 (ko)
JP (1) JPS61115038A (ko)
KR (1) KR860003999A (ko)
CN (1) CN1007346B (ko)
AU (1) AU574809B2 (ko)
BR (1) BR8503591A (ko)
CA (1) CA1268189A (ko)
DE (1) DE3576685D1 (ko)
EG (1) EG17829A (ko)
NO (1) NO852992L (ko)
PL (1) PL254734A1 (ko)
SU (1) SU1510716A3 (ko)
YU (1) YU124485A (ko)
ZA (1) ZA855550B (ko)

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DE3776564D1 (de) * 1987-04-24 1992-03-12 Amoco Corp Umsatz von synthesegas.
GB2210615A (en) * 1987-10-08 1989-06-14 Coal Ind Alcohol synthesis process
US4886651A (en) * 1988-05-18 1989-12-12 Air Products And Chemicals, Inc. Process for co-production of higher alcohols, methanol and ammonia
TW200519073A (en) 2003-08-21 2005-06-16 Pearson Technologies Inc Process and apparatus for the production of useful products from carbonaceous feedstock
EA200702380A1 (ru) 2005-05-20 2008-06-30 Бп Кемикэлз Лимитед Способ превращения синтез-газа в оксигенаты
GB0510356D0 (en) 2005-05-20 2005-06-29 Bp Chem Int Ltd Process for the conversion of synthesis gas to oxygenate
CN101203473B (zh) * 2005-05-20 2011-11-30 英国石油化学品有限公司 将合成气体转化为含氧化合物的方法
KR20080109924A (ko) 2006-04-13 2008-12-17 다우 글로벌 테크놀로지스 인크. 탄소 가치 이용율이 개선된 혼합 알콜 합성
CN101460439B (zh) * 2006-06-01 2015-05-06 英国石油化学品有限公司 用于将合成气转化为氧化物的方法
CN101310856B (zh) 2007-05-24 2010-10-13 中国科学院大连化学物理研究所 一种co加氢直接合成高碳伯醇的催化剂及其制备方法
EP2403639A2 (en) * 2009-03-06 2012-01-11 Albemarle Europe Sprl. Bulk sulfidic mixed metal catalyst and methods for its manufacture and use in converting syngas to alcohol
SG10201606962SA (en) * 2011-08-22 2016-10-28 Albemarle Corp Methods and apparatus for sulfur management in catalytic mixed-alcohol synthesis
BR112015019704B1 (pt) * 2013-02-19 2021-09-14 Rescurve, Llc Método e sistema de destilação reativa
US10081588B2 (en) 2013-12-04 2018-09-25 Rescurve, Llc Production of butyl acetate from ethanol
CA2994846C (en) 2015-08-19 2024-02-20 Rescurve, Llc Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols
CN109294812B (zh) * 2018-11-20 2022-02-11 广西壮族自治区农业科学院农产品加工研究所 一种低甲醇香蕉酒的制备方法
CN113019404B (zh) * 2021-03-23 2022-02-18 中国科学院兰州化学物理研究所 用于合成高碳醇的镍基催化剂及其制备方法与应用
CN115007154B (zh) * 2022-06-16 2023-10-24 广东工业大学 木质素衍生镍基催化剂及其制备方法和应用
CN115228479B (zh) * 2022-07-05 2023-10-24 广东工业大学 一种碱金属改性NiSn材料及其制备方法和应用

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* Cited by examiner, † Cited by third party
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US4272410A (en) * 1979-05-14 1981-06-09 Ethyl Corporation Catalyst for preparation of oxygenates from carbon monoxide and hydrogen
DE3045891C2 (de) * 1980-12-05 1983-03-03 Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln Verfahren zur Herstellung von Acetaldehyd und Ethanol
DE3485330D1 (de) * 1983-03-18 1992-01-23 Dow Chemical Co Katalytisches verfahren zur herstellung einer alkoholmischung aus wasserstoff und kohlenmonoxid.
US4625050A (en) * 1983-06-23 1986-11-25 Chevron Research Company Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst

Also Published As

Publication number Publication date
AU4513585A (en) 1986-05-15
PL254734A1 (en) 1987-02-09
ZA855550B (en) 1987-03-25
JPS61115038A (ja) 1986-06-02
EP0180719B1 (en) 1990-03-21
AU574809B2 (en) 1988-07-14
CA1268189A (en) 1990-04-24
EP0180719A3 (en) 1987-07-15
EG17829A (en) 1990-12-30
CN85105799A (zh) 1986-11-19
BR8503591A (pt) 1986-09-16
NO852992L (no) 1986-05-06
YU124485A (en) 1987-12-31
EP0180719A2 (en) 1986-05-14
CN1007346B (zh) 1990-03-28
SU1510716A3 (ru) 1989-09-23
DE3576685D1 (de) 1990-04-26

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