KR850001755A - 디히드로 이미다조피롤로피리딘류의 제조방법 - Google Patents

디히드로 이미다조피롤로피리딘류의 제조방법 Download PDF

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KR850001755A
KR850001755A KR1019840004596A KR840004596A KR850001755A KR 850001755 A KR850001755 A KR 850001755A KR 1019840004596 A KR1019840004596 A KR 1019840004596A KR 840004596 A KR840004596 A KR 840004596A KR 850001755 A KR850001755 A KR 850001755A
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alkyl
hydrogen
halogen
phenyl
ocf
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를스 마리너스
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죤 제이 헤이간
아메리칸 사이아나밋드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/12—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains three hetero rings
    • C07D471/14—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/12—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains three hetero rings
    • C07D491/14—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
    • C07D495/14—Ortho-condensed systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Pyridine Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

디히드로 이미다조피롤로피리딘류의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 다음 일반식의 화합물을 1몸당량 이상의 초산무수물과 피리딘 및 아세토니트릴 존재하에 반응시킴으로써,
    다음 일반식을 가지는 화합물을 제조하는 방법.
    위 식에서 R1과 R2는 C1-C3알킬 또는 시클를프를필이나 R1과 R2에서 탄소원자수의 합계는 2 내지 5이고 R1과 R2는 이들이 부착된 탄소와 함께 메틸을 임의치환된 C3-C6시클를알킬고리를 형성할 수 있고, W는 산소 또는 황이고, X는 수소, 할를겐 또는 메틸이고, Y와 Z는 수소, 할를겐, C1-C6알킬, C1-C4히드록시알킬, C1-C6알콕시, C1-C4알킬리오, 페녹시, C1-C4할를알킬, OCF2CHF|2,OCF3,OCHF2, 니트를, 시아노, NR4R5,1-3개의 할를겐으를 임의치환된 C3-C8직쇄 또는 분지쇄 알케닐옥시 혹은 알키닐옥시 또는 C1-C4알킬, C1-C4알콕시 혹은 할를겐으로 임의치환된 페닐이고; R4는 수소 또는 C1-C4알킬이고, R5는 C1-C4알킬이고, Y와 Z는 함께 다음과 같은 구조를 형성할 수 있으며,
    (1) X가 수소이면 n이 2,3 또는 4인 -(CH2)n-
    (2)또는
    (여기에서 L,M,R7및 R8은 수소, 할를겐, C1-C4알킬, C1-C4알콕시, C1-C4알킬리오, C1-C4알킬설포닐, C1-C4할를알킬, NO2,CN, 페닐, 페녹시, 아미노, OCF3,OCHF2,OCF2CHF2,C1-C4알킬아미노, 디알킬(C1-C4)아미노, 클를를페닐, 메틸페닐, 1-3개의 할를겐를 임의치환된 C3-C8직쇄 또는 분지쇄 알케닐옥시 혹은 알키닐옥시, 또는 C1,CF3,NO2혹은 CH3기를 임의치환된 페녹시이며, L,M,R7또는 R8중의 하나만이 수소, 할를겐, C1-C4알킬 혹은 C1-C4알콕시 이외의 치환분을 나타낼 수 있다).
    (3)또는
    (위식에서 B는 산소 또는 황이고 R9및 R10은 수소, 할를겐, 페닐 또는 C1-C|4알킬이고, R11및 R12는 수소, C1-C4알킬 또는 페닐이다.)
    R1과 R2가 서로 다를 때는 시스- 또는 트랜스 이성체 혹은 그들의 혼합물이나 광학이성체(시스-또는 트랜스-또는 이들의 혼합물)가 생성된다.
  2. 다음 일반식의 화합물을 동몰량 이상의 소디움보를하이드라이드 또는 리륨보를하이드와 반응시킴으로써,
    다음 일반식의 화합물을 제조하는 방법.
    위 식에서 R1과 R2는 C1-C3알킬 또는 시클를프를필이나 R1과 R2에서 탄소원자수의 합계는 2 내지 5이고 R1과 R2는 이들이 부착된 탄소와 함께 메틸을 임의치환된 C3-C6시클를알킬고리를 형성할 수 있고, W는 산소 또는 황이고, X는 수소, 할로겐 또는 메틸이고, Y와 Z는 수소, 할로겐, C1-C6알킬, C1-C4히드록시알킬, C1-C6알콕시, C1-C4알킬리오, 페녹시, C1-C4할로알킬, OCF2CHF2,OCF3,OCHF2, 니트로, 시아노, NR4R5, 1-3개의 할로겐으로 임의치환된 C3-C8직쇄 또는 분지쇄 알케닐옥시 혹은 알키닐옥시 또는 C1-C4알킬, C1-C4알콕시 혹은 할로겐으로 임의치환된 페닐이고, R4는 수소 또는 C1-C4알킬이고, R5는 C1-C4알킬이고, Y와 Z는 함께 다음과 같은 구조를 형성할 수 있으며,
    (1) X가 수소이면 n이 2,3 또는 4인 -(CH2)n-
    (2)또는
    (여기에서 L,M,R7및 R8은 수소, 할로겐, C1-C4알킬, C1-C4알콕시, C1-C4알킬리오, C1-C4알킬설포닐, C1-C4할로알킬, NO2,CN, 페닐, 페녹시, 아미노, OCF3,OCHF2,OCF2CHF2,C1-C4알킬아미노, 디알킬(C1-C4)아미노, 클로로페닐, 메틸페닐, 1-3개의 할로겐으로 임의치환된 C3-C8직쇄 또는 분지쇄 알케닐옥시 혹은 알키닐옥시, 또는 C1,CF3,NO2혹은 CH3기를 임의치환된 페녹시이며, L,M,R7또는 R8중의 하나만이 수소, 할로겐, C1-C4알킬 혹은 C1-C4알콕시 이외의 치환분을 나타낼 수 있다).
    (3)또는(위식에서 B는 산소 또는 황이고 R9및 R10은 수소, 할로겐, 페닐 또는 C1-C4알킬이고, R11및 R12는 수소, C1-C4알킬 또는 페닐이다.)
    R1과 R2가 서로 다를 때는 시스- 또는 트랜스 이성체 혹은 그들의 혼합물이나 광학이성체(시스-또는 트랜스-또는 이들의 혼합물)가 생성된다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840004596A 1983-08-02 1984-08-01 디히드로 이미다조피롤로피리딘류 및 그의 유도체 KR900004996B1 (ko)

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US51960383A 1983-08-02 1983-08-02
US519603 1983-08-02
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EP (2) EP0133309B1 (ko)
JP (2) JPH0670054B2 (ko)
KR (1) KR900004996B1 (ko)
AR (1) AR241812A1 (ko)
AT (2) ATE48134T1 (ko)
AU (1) AU570256B2 (ko)
BR (1) BR8403838A (ko)
CA (1) CA1337349C (ko)
DE (2) DE3485928T2 (ko)
DK (2) DK168599B1 (ko)
ES (1) ES8604221A1 (ko)
HU (2) HU199472B (ko)
IL (1) IL72601A (ko)
YU (2) YU45904B (ko)
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KR100893453B1 (ko) * 2002-09-24 2009-04-17 두산인프라코어 주식회사 축관통 냉각구조를 갖는 고속 회전 테이블

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DE3520390A1 (de) * 1984-07-07 1986-02-06 Bayer Ag, 5090 Leverkusen Imidazo-pyrrolo-pyridin-derivate
EP0183993A3 (de) * 1984-11-16 1987-12-09 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft 2H-Imidazo[1',2':1,2]pyrrolo[3,4-b]pyridine und deren Verwendung als Unkrautbekämpfungsmittel
EP0195745B1 (de) * 1985-03-12 1990-09-12 Ciba-Geigy Ag Heterocyclisch kondensierte Pyridin-Verbindungen als Herbizide
EP0213079A3 (de) * 1985-08-23 1987-08-05 Ciba-Geigy Ag Thienylalkylester von alpha-Imidazolinon-nicotin- und -benzoesäuren
DE3534948A1 (de) * 1985-10-01 1987-04-09 Bayer Ag Fungizide und wachstumsregulatorische mittel
EP0227932B1 (en) * 1985-12-13 1993-01-13 American Cyanamid Company Novel fused pyridine compounds, intermediates for the preparation of, and use of said compounds as herbicidal agents
DK41387A (da) * 1986-02-21 1987-08-22 Hoffmann La Roche Glyphosatholdigt ukrudtsbekaempelsesmiddel
GB2174395A (en) * 1986-05-09 1986-11-05 American Cyanimid Co Herbicidal 2-(2-imidazolin-2-yl)pyridine derivatives
DE3751524T2 (de) * 1986-07-28 1996-06-13 American Cyanamid Co 5(und/oder6) Substituierte 2-(2-Imidazolin-2-yl)nicotinsäuren, Ester und Salze, verwendbar als herbizide Mittel und Zwischenverbindungen für die Herstellung dieser Nikotinsäuren, Ester und Salze.
US4895588A (en) * 1987-07-01 1990-01-23 Ciba-Geigy Corporation Substituted imidazolones having herbicidal activity
EP0322616A3 (en) * 1987-12-31 1989-10-18 American Cyanamid Company Novel 5(and/or 6)substituted 2-(2-imidazolin-2-yl)nicotinic acids, esters and salts, useful as herbicidal agents and nivel intermediates for the preparation of said nicotinic acids, esters and salts
CN100415738C (zh) * 2004-12-21 2008-09-03 浙江工业大学 一种含吡唑双杂环化合物、制备方法及其应用

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GB1547660A (en) * 1976-12-23 1979-06-27 American Cyanamid Co Substituted dihydroimidazoisoindoles and their use as herbicides
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IL62794A0 (en) * 1980-06-02 1981-07-31 American Cyanamid Co Substituted nicotinic acid esters and salts thereof and their use as herbicidal agents
IN153523B (ko) * 1980-06-02 1984-07-21 American Cyanamid Co
JPS5724369A (en) * 1980-07-19 1982-02-08 Tokyo Kinzoku Kogyo Kk Pyrimidine derivative and its preparation
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100893453B1 (ko) * 2002-09-24 2009-04-17 두산인프라코어 주식회사 축관통 냉각구조를 갖는 고속 회전 테이블

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EP0277661A1 (en) 1988-08-10
HUT36679A (en) 1985-10-28
KR900004996B1 (ko) 1990-07-16
DE3480541D1 (en) 1989-12-28
JPS6069083A (ja) 1985-04-19
DK168599B1 (da) 1994-05-02
CA1337349C (en) 1995-10-17
DK170703B1 (da) 1995-12-11
IL72601A (en) 1990-04-29
YU45805B (sh) 1992-07-20
EP0133309A1 (en) 1985-02-20
YU197986A (en) 1988-04-30
ATE80631T1 (de) 1992-10-15
ATE48134T1 (de) 1989-12-15
AR241812A1 (es) 1992-12-30
ES534790A0 (es) 1986-02-01
EP0133309B1 (en) 1989-11-23
DK373884A (da) 1985-02-03
JPH0714933B2 (ja) 1995-02-22
DK232790D0 (da) 1990-09-26
BR8403838A (pt) 1985-07-09
AU570256B2 (en) 1988-03-10
YU45904B (sh) 1992-09-07
HU199472B (en) 1990-02-28
ES8604221A1 (es) 1986-02-01
HU196999B (en) 1989-02-28
DK373884D0 (da) 1984-08-01
ZA845959B (en) 1985-03-27
JPH0670054B2 (ja) 1994-09-07
AU3139284A (en) 1985-02-07
DK232790A (da) 1990-09-26
IL72601A0 (en) 1984-11-30
JPH06116264A (ja) 1994-04-26
EP0277661B1 (en) 1992-09-16
YU135784A (en) 1987-02-28
DE3485928D1 (de) 1992-10-22
DE3485928T2 (de) 1993-03-25

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