KR850003719A - 시아노피라졸 제초제에 대한 개량 - Google Patents

시아노피라졸 제초제에 대한 개량 Download PDF

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Publication number
KR850003719A
KR850003719A KR1019840006917A KR840006917A KR850003719A KR 850003719 A KR850003719 A KR 850003719A KR 1019840006917 A KR1019840006917 A KR 1019840006917A KR 840006917 A KR840006917 A KR 840006917A KR 850003719 A KR850003719 A KR 850003719A
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KR
South Korea
Prior art keywords
compound
formula
alkoxy
alkyl
cyano
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KR1019840006917A
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English (en)
Inventor
리챠드 벡크 제임스
Original Assignee
메어리 앤 럭커
일라이 릴리 앤드 캄파니
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Application filed by 메어리 앤 럭커, 일라이 릴리 앤드 캄파니 filed Critical 메어리 앤 럭커
Publication of KR850003719A publication Critical patent/KR850003719A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/38—Nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

시아노피라졸 제초제에 대한 개량
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. (a)다음 구조식의 니트릴을
    구조식 NHR2R3(여기에서 R1,R2,R3및 R5는 후술하는 바와 같다)와 반응시키고; (b)얻어진 다음 구조식의 아마이드
    (상기식에서 R1,R2,R3및 R6는 후술하는 바와 같다)를 알카리금속 시아나이드와 반응시킨 후 (c)X가 S인 구조식(b)화합물을 제조하는 경우, 임의로 반응(a) 또는 (b)의 생성물을 리아화하여 다음 구조식 (Ⅰ)의 화합물을 제조하는 방법.
    상기식에서, R1은 C1-C6알킬, C5-C6사이클로알킬,
    R2와 R3는 각각 독립적으로 수소, C1-C4알킬, C3-C4알케닐, C3-C4알키닐, C3-C4사이클로알킬 또는 C1-C3알콕시이거나; 또는 R2와 R3는 인접한 질소원자와 함께 피페리딘, 모르포린 또는 피롤리딘 링을 형성한다; 각 R4는 각각 독립적으로 할로겐, C1-C4알킬, C1-C4알콕시,C1-C4할로알킬, C1-C4할로알콕시 또는 시아노; R5는 상기 아민에 의하여 치환될 수 있는기; R6는 할로겐; X는 0 또는 S이고; m은 0-3이다. 단, R4가 C1-C4알킬인 경우, 이 치환체는 페닐링의 2 또는 6위치가 아닌 곳에 위치하며; R2가 C1-C3알콕시인 경우 R3는 C1-C3알콕시는 아니다.
  2. 제1항에서, R1이
    인 화합물을 제조하는 방법.
  3. 제1항 또는 2항에서, X가 산소인 구조식(Ⅰ)화합물을 제조하는 방법.
  4. 제1-3항에서, -NR2R3가 -NHCH3또는 -NH사이클로알킬인 구조식(Ⅰ)화합물을 제조하는 방법.
  5. 제1항에서, 5-시아노-1-페닐-N-메틸-1H-피라졸-4-카복시마이드를 제조하는 방법.
  6. 제1항에서, 5-시아노-1-t-부틸-N-메틸-1H-피라졸-4-카복시마이드를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840006917A 1983-11-07 1984-11-05 시아노피라졸 제초제에 대한 개량 KR850003719A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54913383A 1983-11-07 1983-11-07
US???549133 1983-11-07

Publications (1)

Publication Number Publication Date
KR850003719A true KR850003719A (ko) 1985-06-26

Family

ID=24191805

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019840006917A KR850003719A (ko) 1983-11-07 1984-11-05 시아노피라졸 제초제에 대한 개량

Country Status (27)

Country Link
EP (1) EP0151867B1 (ko)
JP (1) JPS60172968A (ko)
KR (1) KR850003719A (ko)
AR (1) AR240808A1 (ko)
AT (1) ATE49404T1 (ko)
AU (1) AU572913B2 (ko)
BR (1) BR8405645A (ko)
CA (1) CA1227483A (ko)
CY (1) CY1517A (ko)
DE (1) DE3480999D1 (ko)
DK (1) DK527784A (ko)
EG (1) EG17046A (ko)
ES (2) ES537400A0 (ko)
FI (1) FI844348L (ko)
GB (1) GB2149403B (ko)
GR (1) GR80848B (ko)
GT (1) GT198400140A (ko)
HK (1) HK2090A (ko)
HU (1) HU196112B (ko)
IL (1) IL73418A (ko)
MY (1) MY101849A (ko)
NZ (1) NZ210124A (ko)
PH (1) PH22069A (ko)
PT (1) PT79463B (ko)
SG (1) SG75889G (ko)
SU (2) SU1422996A3 (ko)
ZA (1) ZA848666B (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3520330A1 (de) * 1985-06-07 1986-12-11 Bayer Ag, 5090 Leverkusen 5-amino-1-pyridyl-pyrazole
DE3682711D1 (de) * 1985-06-18 1992-01-16 Ici Plc Als fungizide verwendbare heterocyclische verbindungen.
DE3540839A1 (de) * 1985-11-18 1987-05-27 Bayer Ag 1-aryl-pyrazole
KR870008849A (ko) * 1986-03-19 1987-10-21 메어리 앤 턱커 생식자 박멸효능을 갖는 피라졸류
US4801326A (en) * 1986-03-19 1989-01-31 Eli Lilly And Company 1-phenylpyrazole-4,5-dicarboxylic acid derivatives, composition containing them, and pollen formation inhibiting method of using them
DE3751686T2 (de) * 1986-12-16 1996-06-13 Zeneca Ltd Pyrrol-Derivate und ihre Verwendung in der Landwirtschaft
DE3934924C2 (de) * 1989-10-20 1994-01-27 Huels Chemische Werke Ag Verfahren zur Herstellung von 4-Alkoxycarbonyl-3-chlormethyl-2H-pyrazolen
DE4007566C2 (de) * 1990-03-09 1998-07-16 Siemens Ag Leistungsverstärker für die Speisung einer Induktivität mit geschalteten Transistoren
JPH0813382B2 (ja) * 1991-03-28 1996-02-14 橋本フォーミング工業株式会社 矯正曲げ加工方法及びその装置
WO1992019615A2 (en) * 1991-04-24 1992-11-12 E.I. Du Pont De Nemours And Company Fungicidal pyrazoles, pyrazolines and tetrahydropyridazines
ID21775A (id) * 1996-10-25 1999-07-22 Yoshitomi Pharmaceutical Senyawa-senyawa 1-fenilpirazol dan penggunaan farmasinya
EP1275301A1 (en) * 2001-07-10 2003-01-15 Bayer CropScience S.A. Trisubstituted heterocyclic compounds and their use as fungicides
AU2003292820A1 (en) * 2002-12-27 2004-07-29 Sankyo Agro Company, Limited 4-amino-5-methylpyrazole derivatives and process for production thereof
WO2009116151A1 (ja) * 2008-03-19 2009-09-24 アグロカネショウ株式会社 １-フェニル-５-ジフルオロメチルピラゾール-４-カルボキサミド誘導体及びこれを有効成分とする除草剤
CN104628645B (zh) * 2014-12-23 2017-01-25 浙江工业大学 一种含吡唑双酰肼类化合物及其制备方法和应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4134987A (en) * 1976-01-14 1979-01-16 Huppatz John L Compounds and compositions
CA1156661A (en) * 1980-02-25 1983-11-08 Hoffmann-La Roche Limited Phenoxy-aminopropanol derivatives
EP0178035B1 (en) * 1984-05-12 1990-01-03 FISONS plc Anti-inflammatory 1,n-diarylpyrazol-3-amines, compositions containing them and processes for their preparation

Also Published As

Publication number Publication date
ES8603837A1 (es) 1986-01-01
JPS60172968A (ja) 1985-09-06
ES546905A0 (es) 1986-03-01
BR8405645A (pt) 1985-09-10
NZ210124A (en) 1987-06-30
FI844348A0 (fi) 1984-11-06
EP0151867B1 (en) 1990-01-10
HUT36345A (en) 1985-09-30
PH22069A (en) 1988-05-20
ES537400A0 (es) 1986-01-01
FI844348L (fi) 1985-05-08
EP0151867A2 (en) 1985-08-21
GB2149403B (en) 1987-10-28
SU1422996A3 (ru) 1988-09-07
SU1447281A3 (ru) 1988-12-23
DK527784A (da) 1985-05-08
EG17046A (en) 1991-03-30
GR80848B (en) 1985-03-05
AR240808A1 (es) 1991-02-28
IL73418A (en) 1988-02-29
ZA848666B (en) 1986-01-29
EP0151867A3 (en) 1987-04-01
DE3480999D1 (de) 1990-02-15
GB2149403A (en) 1985-06-12
AU572913B2 (en) 1988-05-19
AU3514884A (en) 1985-05-16
PT79463A (en) 1984-12-01
GB8427972D0 (en) 1984-12-12
MY101849A (en) 1992-01-31
DK527784D0 (da) 1984-11-06
ATE49404T1 (de) 1990-01-15
IL73418A0 (en) 1985-02-28
GT198400140A (es) 1986-04-29
PT79463B (en) 1986-12-11
AR240808A2 (es) 1991-02-28
SG75889G (en) 1990-04-20
CA1227483A (en) 1987-09-29
HK2090A (en) 1990-01-19
HU196112B (en) 1988-10-28
CY1517A (en) 1990-11-16
ES8604886A1 (es) 1986-03-01

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