KR840004775A - 수첨분해 촉매 및 수첨분해 방법 - Google Patents

수첨분해 촉매 및 수첨분해 방법 Download PDF

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Publication number
KR840004775A
KR840004775A KR1019830002182A KR830002182A KR840004775A KR 840004775 A KR840004775 A KR 840004775A KR 1019830002182 A KR1019830002182 A KR 1019830002182A KR 830002182 A KR830002182 A KR 830002182A KR 840004775 A KR840004775 A KR 840004775A
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KR
South Korea
Prior art keywords
catalyst
zeolite
hydrocracking
hydrogenation component
cobalt
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KR1019830002182A
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English (en)
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KR900005097B1 (ko
Inventor
버나드 라피에르 렌 (외 2)
Original Assignee
원본미기재
모빌 오일 코오포레이숀
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Publication of KR840004775A publication Critical patent/KR840004775A/ko
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Publication of KR900005097B1 publication Critical patent/KR900005097B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself

Abstract

내용 없음

Description

수첨분해 촉매 및 수첨분해 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 제올라이트성분 증가에 따른 유분선택성 증가를 나타냄.

Claims (14)

  1. 수소화 성분 및 산성 성분으로서 최소한 50:1의 실리카:알루미나비를 지니는 큰 기공 제올라이트로 구성되는 수첨분해 촉매.
  2. 제1항에 있어서, 큰 기공 제올라이트가 6옹그스트롱 이상의 격자 구조와 최소 6퍼센트의 탄화수소 흡착능력을 지니는 기공 격자 구조를 지니는 촉매.
  3. 제1항 또는 제2항에 있어서, 제올라이트는 0.5-2.0의 콘스트래인트율을 지니는 촉매.
  4. 제1항 또는 제3항에 있어서, 제올라이트가 최소한 100:1의 실리카:알루미나비를 지니는 촉매.
  5. 제4항에 있어서, 제올라이트가 최소한 200:1의 실리카:알루미나를 지니는 촉매.
  6. 제1항 또는 제5항까지에 있어서, 제올라이트가 제올라이트 Y인 촉매.
  7. 제1항 또는 제5항까지에 있어서, 제올라이트가 제올라이트 ZSM-20인 촉매.
  8. 제1항 또는 제7항까지에 있어서, 수소화 성분이 주기율표 ⅧA족의 희귀금속인 촉매.
  9. 제8항에 있어서, 수소화 성분이 폴리티늄, 파라듐, 이리디움 혹은 로듐인 촉매.
  10. 제1항에서 제8항까지에 있어서, 수소화 성분이 주기율표 VA, ⅥA 및 ⅦA족의 금속인 촉매.
  11. 제10항에 있어서, 수소화 성분이 닉켈, 코발트, 몰리브데늄 텅스텐 혹은 둘 이상의 이같은 금속의 혼합물로 구성되는 촉매.
  12. 제11항에 있어서, 수소화 성분이 코발트-닉켈, 코발트-몰리브데늄 혹은 닉켈-텅스텐인 촉매.
  13. 수소의 존재하에 수첨분해 조건으로 원료 탄화수소와 촉매를 접촉시키는 것으로 구성되는 수첨분해 방법.
  14. 제13항에 있어서, 원료가 수소 존재하에 230℃-500℃ 로 500-20,000KPa 및 0.1-20LHSV의 조건하에 촉매와 접촉시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830002182A 1982-05-18 1983-05-18 수첨분해 촉매 및 수첨분해 방법 KR900005097B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37942082A 1982-05-18 1982-05-18
US379420 1982-05-18

Publications (2)

Publication Number Publication Date
KR840004775A true KR840004775A (ko) 1984-10-24
KR900005097B1 KR900005097B1 (ko) 1990-07-19

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KR1019830002182A KR900005097B1 (ko) 1982-05-18 1983-05-18 수첨분해 촉매 및 수첨분해 방법

Country Status (21)

Country Link
EP (1) EP0098040B1 (ko)
JP (1) JPS58207949A (ko)
KR (1) KR900005097B1 (ko)
AT (1) ATE15614T1 (ko)
AU (1) AU563032B2 (ko)
BR (1) BR8302593A (ko)
CA (1) CA1204717A (ko)
DE (1) DE3360832D1 (ko)
DK (1) DK162075C (ko)
ES (1) ES8407088A1 (ko)
FI (1) FI72434C (ko)
GR (1) GR78563B (ko)
IN (1) IN159034B (ko)
MX (1) MX162402A (ko)
MY (1) MY8700290A (ko)
NO (1) NO158332C (ko)
NZ (1) NZ204090A (ko)
PH (1) PH20172A (ko)
PT (1) PT76707B (ko)
SG (1) SG76886G (ko)
ZA (1) ZA833586B (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2582665B1 (fr) * 1985-06-04 1988-08-05 Inst Francais Du Petrole Procede de craquage catalytique
US4898846A (en) * 1986-03-21 1990-02-06 W. R. Grace & Co.-Conn. Cracking catalysts with octane enhancement
US5108969A (en) * 1986-07-29 1992-04-28 Mobil Oil Corp. Low acidity catalyst for conversion of paraffins to olefins and/or aromatics
FR2619390A1 (fr) * 1987-08-14 1989-02-17 Shell Int Research Procede d'hydrogenation d'huiles hydrocarbonees
US4788375A (en) * 1987-11-27 1988-11-29 Mobil Oil Corporation Olefin conversion to lubricant range hydrocarbons
JPH0655951B2 (ja) * 1990-01-12 1994-07-27 ユーオーピー 中間留分の水添分解式製造方法及びそれに用いられる触媒組成物
JP2908959B2 (ja) * 1993-04-07 1999-06-23 出光興産株式会社 新規触媒組成物
US7192900B2 (en) 2002-11-27 2007-03-20 Shell Oil Company Hydrocracking catalyst
CN1839195A (zh) * 2003-06-26 2006-09-27 赫多特普索化工设备公司 碳氢化合物转化方法与催化剂
US20090048477A1 (en) * 2006-03-31 2009-02-19 Hiroyuki Seki Hydrocracking Catalyst, and Method for Production of Fuel Base Material
JP5303110B2 (ja) * 2006-11-28 2013-10-02 Ｊｘ日鉱日石エネルギー株式会社 液体燃料の製造方法
RU2451714C2 (ru) 2007-05-01 2012-05-27 Ниппон Ойл Корпорейшн Способ получения жидкого топлива

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1098361B (it) * 1977-08-17 1985-09-07 Mobil Oil Corp Procedimento per la preparazione di una zeolite alluminosilicatica cristallina
JPS5460294A (en) * 1977-10-21 1979-05-15 Asahi Glass Co Ltd Electrolysis of aqueous alkali chrolide
US4377468A (en) * 1979-01-22 1983-03-22 Mobil Oil Corporation Sulfur- and nitrogen-containing hydrocarbon feed hydrocracking over ZSM-20
US4247386A (en) * 1979-08-06 1981-01-27 Mobil Oil Corporation Conversion of hydrocarbons to olefins
CA1203191A (en) * 1982-02-11 1986-04-15 Susan Bradrick Middistillate production

Also Published As

Publication number Publication date
EP0098040A1 (en) 1984-01-11
ATE15614T1 (de) 1985-10-15
GR78563B (ko) 1984-09-27
ZA833586B (en) 1984-12-24
ES522481A0 (es) 1984-08-16
NO831713L (no) 1983-11-21
NZ204090A (en) 1986-02-21
CA1204717A (en) 1986-05-20
MY8700290A (en) 1987-12-31
IN159034B (ko) 1987-03-14
NO158332C (no) 1988-08-24
DK162075B (da) 1991-09-16
FI831723A0 (fi) 1983-05-17
JPS58207949A (ja) 1983-12-03
JPH0412317B2 (ko) 1992-03-04
DK220083D0 (da) 1983-05-17
SG76886G (en) 1987-02-27
KR900005097B1 (ko) 1990-07-19
AU1437683A (en) 1983-11-24
DK162075C (da) 1992-02-17
PT76707A (en) 1983-06-01
PT76707B (en) 1985-12-27
AU563032B2 (en) 1987-06-25
DK220083A (da) 1983-11-19
DE3360832D1 (en) 1985-10-24
FI831723L (fi) 1983-11-19
FI72434C (fi) 1987-06-08
MX162402A (es) 1991-05-06
NO158332B (no) 1988-05-16
EP0098040B1 (en) 1985-09-18
ES8407088A1 (es) 1984-08-16
FI72434B (fi) 1987-02-27
PH20172A (en) 1986-10-14
BR8302593A (pt) 1984-01-17

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