KR840001210A - 윤활유의 제조방법 - Google Patents

윤활유의 제조방법 Download PDF

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KR840001210A
KR840001210A KR1019820003562A KR820003562A KR840001210A KR 840001210 A KR840001210 A KR 840001210A KR 1019820003562 A KR1019820003562 A KR 1019820003562A KR 820003562 A KR820003562 A KR 820003562A KR 840001210 A KR840001210 A KR 840001210A
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zsm
catalyst
zeolite
nickel
cobalt
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KR1019820003562A
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KR880000065B1 (ko
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마이클 올렉 스테펜 (외 1)
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에드워드 에취·밸런스
모빌 오일 코오포레이숀
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

윤활유의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 탄화수소 유분을 부분적으로 탈랍하기에 충분한 조건하에서 비점이204°-566℃인 밀랍 탄화수소 유분을 탈랍촉매와 접촉시킨후, 얻어진 반응 생성물을 수소와 접촉시킨 다음, ZSM-5, ZSM-11, ZSM-23 및 ZSM-35로부터 선정된 하나이상의 제오라이트와 수소화 성분으로 구성된 촉매를 수소처리하는 것으로 구성되고 점도지수가 높은 윤활유의 제조방법.
  2. 제1항에 있어서, 반응생성물은 온도 218°-316℃, 수소분압 1136-10,443kPa(150-1500psig), LHSV 0.1-4.0 및 반응생성물 890Nl/l(배러당 수소 500-5000scf)에서 접촉시키는 것을 특징으로 하는 방법.
  3. 제1항 또는 2항에 있어서, 수소화 성분이 텅스텐, 몰리브덴, 니켈, 코발트, 백금, 팔라듐 및 이들의 혼합물로부터 니켈, 코발트, 백금, 팔라듐 및 이들의 혼합물로부터 선정된 하나이상의 금속성분을 갖는 것을 특징으로 하는 방법.
  4. 제3항에 있어서, 수소화성분이 원소로서, 또는 산화물 또는 황화물로서 코발트 또는 니켈과 몰리브덴을 함유하는 것을 특징으로 하는 방법.
  5. 제1항 내지 4항중 어느 하나에 있어서, 수소처리 촉매가 제오라이트, 수소화 성분 및 다공성 매트릭스를 함유하는 것을 특징으로 하는 방법.
  6. 제5항에 있어서, 다공성 매트릭스가 알루미나인 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 수소화 촉매가 별도의 입자로서 혼합된 제오라이트와 수소화 성분을 함유하는 것을 특징으로 하는 방법.
  8. 제1항 내지 제7항중 어느 하나에 있어서, 제오라이트가 ZSM-5인 것을 특징으로 하는 방법.
  9. 제1항 내지 7항중 어느 하나에 있어서, 제로아리트가 ZSM-11인 것을 특징으로 하는 방법.
  10. 제1항 내지 7항중 어느 하나에 있어서, 제오라이트가 ZSM-23인 것을 특징으로 하는 방법.
  11. 제1항 내지 7항중 어느 하나에 있어서, 제오라이트가 ZSM-35인 것을 특징으로 하는 방법.
  12. 제1항 내지 11항중 어느 하나에 있어서, 밀랍 탄화수소 유분의 비점이 316°-566℃인 것을 특징으로 하는 방법.
  13. 제1항 내지 12항중 어느 하나에 있어서, 수소처리 촉매중 원소로서, 산화물 또는 황화물 형태로서의 금속함량이 0.05-25중량%이고, 제오라이트 함량은 5-40중량%인 것을 특징으로 하는 방법.
  14. ZSM-5, ZSM-11, ZSM-23 및 ZSM-35로부터 선정된 하나 이상의 제오라이트와 다공성 매트릭스 위에 형성된 수소화 금속 성분으로 구성된 수소처리 촉매 조성물.
  15. 제14항에 있어서, 제오라이트가 ZSM-5인 촉매.
  16. 제14항에 있어서, 제오라이트가 ZSM-11인 촉매.
  17. 제14항에 있어서, 제오라이트가 ZSM-23인 촉매.
  18. 제14항에 있어서, 제오라이트가 ZSM-35인 촉매.
  19. 제14항 내지 18항중 어느 하나에 있어서, 다공성 매트릭스가 알루미나인 촉매.
  20. 제14항 내지 19항중 어느 하나에 있어서, 수소화 금속이 원소형태, 황화물 또는 산화물 형태로서 텅스텐, 몰리브덴, 니켈, 코발트, 백금 및 팔라듐으로부터 선정된 하나이상의 금속인 촉매.
  21. 제20항에 있어서, 수소화 성분이 원소, 황화물 또는 산화물형태로서 몰리브덴과 코발트 또는 니켈인 촉매.
  22. 제14항 내지 21항중 어느 하나에 있어서, 원소, 산화물 또는 황화물 형태로서 금속함량은 0.05-25 중량%이고, 수소처리 촉매중 제오라리트 함량은 5-40중량%인 촉매 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8203562A 1981-08-07 1982-08-07 윤활유의 제조방법 KR880000065B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US29075981A 1981-08-07 1981-08-07
US290,759 1981-08-07
US290759 1981-08-07

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KR840001210A true KR840001210A (ko) 1984-03-28
KR880000065B1 KR880000065B1 (ko) 1988-02-22

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EP (1) EP0072220B1 (ko)
JP (1) JPS5834892A (ko)
KR (1) KR880000065B1 (ko)
AT (1) ATE18918T1 (ko)
CA (1) CA1203225A (ko)
DE (1) DE3270263D1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100426263B1 (ko) * 1995-04-28 2004-05-31 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 윤활용 기재오일을 생성하는 방법

Families Citing this family (8)

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Publication number Priority date Publication date Assignee Title
CA1232855A (en) * 1982-07-22 1988-02-16 Tsoung-Yuan Hydroisomerization of catalytically dewaxed lubricating oils
JPH06916B2 (ja) * 1984-06-01 1994-01-05 東燃株式会社 低流動点潤滑油基油の製造方法
AU586980B2 (en) * 1984-10-29 1989-08-03 Mobil Oil Corporation An improved process and apparatus for the dewaxing of heavy distillates and residual liquids
US4695364A (en) * 1984-12-24 1987-09-22 Mobil Oil Corporation Lube or light distillate hydrodewaxing method and apparatus with light product removal and enhanced lube yields
LU86288A1 (fr) * 1986-02-03 1987-09-10 Labofina Sa Procede de traitement des gasoils
IT1311512B1 (it) 1999-03-12 2002-03-13 Agip Petroli Composizione catalitica per l'upgrading di miscele idrocarburiche.
US6530373B1 (en) 2000-08-04 2003-03-11 Mallinckrodt Inc. Respirator mask
US10406511B2 (en) * 2016-04-11 2019-09-10 Enerkem, Inc. Hybrid extruded mixed zeolite catalysts for synthesis of light olefins

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Publication number Priority date Publication date Assignee Title
US3438887A (en) * 1967-07-11 1969-04-15 Texaco Inc Production of lubricating oils
US3645914A (en) * 1969-03-19 1972-02-29 Mobil Oil Corp Conversion of inorganic oxides into extrudable binders
US3788972A (en) * 1971-11-22 1974-01-29 Exxon Research Engineering Co Process for the manufacture of lubricating oils by hydrocracking
US4191638A (en) * 1972-06-13 1980-03-04 Mobil Oil Corporation Reforming catalysts
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
CA1117455A (en) * 1977-12-20 1982-02-02 Mobil Oil Corporation Manufacture of lube base stock oil
US4330396A (en) * 1978-10-18 1982-05-18 Chevron Research Company Cyclic process for upgrading a hydrocarbon or hydrocarbon-forming feed using a ZSM-5 zeolite
AU539269B2 (en) * 1979-10-15 1984-09-20 Mobil Oil Corp. Preparing a zeolite containing group 8 metal catalyst
US4292166A (en) * 1980-07-07 1981-09-29 Mobil Oil Corporation Catalytic process for manufacture of lubricating oils

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100426263B1 (ko) * 1995-04-28 2004-05-31 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 윤활용 기재오일을 생성하는 방법

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ATE18918T1 (de) 1986-04-15
JPS5834892A (ja) 1983-03-01
EP0072220B1 (en) 1986-04-02
CA1203225A (en) 1986-04-15
EP0072220A1 (en) 1983-02-16
KR880000065B1 (ko) 1988-02-22
DE3270263D1 (en) 1986-05-07

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