GB1121443A - A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils - Google Patents

A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils

Info

Publication number
GB1121443A
GB1121443A GB13785/66A GB1378566A GB1121443A GB 1121443 A GB1121443 A GB 1121443A GB 13785/66 A GB13785/66 A GB 13785/66A GB 1378566 A GB1378566 A GB 1378566A GB 1121443 A GB1121443 A GB 1121443A
Authority
GB
United Kingdom
Prior art keywords
oil
hydrogen
reaction zone
catalyst
lubricating oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13785/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1121443A publication Critical patent/GB1121443A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A process for the preparation of a lubricating oil fraction or fractions having a high viscosity index by hydrocracking of hydrocarbon oil having a boiling range at least partly above the final boiling point of lubricating oil comprises contacting the oil, in a first reaction zone and in the presence of hydrogen or a hydrogen-containing gas, at a temperature of between 250 DEG and 475 DEG C., a liquid hourly space velocity of from 0.4 to 5 litres of oil per hour per litre of catalyst, a pressure of from 50 to 500 atmospheres and an oil to hydrogen ratio of from 250 to 5,000 N litres of hydrogen per kilogram of oil, with a catalyst containing a hydrogenation component and an acid-acting cracking component, this contacting being carried out under such conditions that the percentage by weight of hydrocarbons having a boiling range of between 370 DEG and 525 DEG C. in the hydrocarbon mixture leaving the first reaction zone is at least 5 and at most 50 higher than the percentage by weight of the corresponding hydrocarbons in the hydrocarbon oil introduced into the first reaction zone; subsequently separating a hydrogen-containing gas and at least one hydrocarbon fraction having a final boiling point of between 370 DEG and 525 DEG C. from the reaction product; contacting at least part of the remaining reaction product, likewise in the presence of hydrogen or a hydrogen-containing gas, in a second reaction zone and at a temperature of from 325 DEG to 450 DEG C., a liquid hourly space velocity of from 0.2 to 5 litres of oil per hour per litre of catalyst, a pressure of from 50 to 500 atmospheres and a hydrogen to oil ratio of from 250 to 5,000 N litres of hydrogen per kilogram of oil, with a catalyst likewise containing a hydrogenation component and an acid-acting cracking component, this contacting being carried out under such conditions that the reaction mixture, when leaving the second reaction zone after the separation of normally gaseous components, contains 20 to 75% by weight of hydrocarbons having boiling points above 525 DEG C; and separating at least one lubricating oil fraction having a boiling range of between 370 DEG and 525 DEG C. from the reaction mixture of the second reaction zone. The feed stock may be pretreated to reduce the content of nitrogen compounds and carbonaceous components with sulphuric acid or by hydrogenation. Sulphur compounds such as hydrogen sulphide may be added to the feedstock in the first and/or second reaction zone. The catalyst in both zones may comprise cobalt, nickel, tungsten, molybdenum, platinum, palladium, copper and/or silver and/or the sulphides and/or oxides thereof supported on silica, alumina, magnesia, zirconia, titania and/or boria and may also contain a small amount of fluorine. An example describes the preparation of lubricating oil from a residual oil.
GB13785/66A 1965-03-31 1966-03-29 A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils Expired GB1121443A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL656504066A NL144326B (en) 1965-03-31 1965-03-31 METHOD FOR HYDROGENATING CRACKING OF A HYDROCARBON OIL.

Publications (1)

Publication Number Publication Date
GB1121443A true GB1121443A (en) 1968-07-24

Family

ID=19792799

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13785/66A Expired GB1121443A (en) 1965-03-31 1966-03-29 A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils

Country Status (9)

Country Link
US (1) US3444071A (en)
BE (1) BE678609A (en)
CH (1) CH479687A (en)
DE (1) DE1276264B (en)
ES (1) ES324827A1 (en)
GB (1) GB1121443A (en)
NL (1) NL144326B (en)
NO (1) NO115222B (en)
SE (1) SE308936B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5358628A (en) * 1990-07-05 1994-10-25 Mobil Oil Corporation Production of high viscosity index lubricants

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3617484A (en) * 1968-11-29 1971-11-02 Sun Oil Co Increasing the v.i. of hydrocracked light lubes
BE754805A (en) * 1969-09-05 1971-02-15 Atlantic Richfield Co PERFECTED PROCESS FOR PREPARATION OF LUBRICATING MINERAL OIL FROM NEW RAW MATERIALS
US3617482A (en) * 1969-11-10 1971-11-02 Chevron Res Process for the production of lubricating oils
US3666657A (en) * 1970-11-16 1972-05-30 Sun Oil Co Pennsylvania Oil stabilizing sequential hydrocracking and hydrogenation treatment
US3992283A (en) * 1974-09-23 1976-11-16 Universal Oil Products Company Hydrocracking process for the maximization of an improved viscosity lube oil
US4419271A (en) * 1979-10-15 1983-12-06 Union Oil Company Of California Hydrocarbon conversion catalyst
US4743354A (en) * 1979-10-15 1988-05-10 Union Oil Company Of California Process for producing a product hydrocarbon having a reduced content of normal paraffins
US4743355A (en) * 1979-10-15 1988-05-10 Union Oil Company Of California Process for producing a high quality lube oil stock
US4592828A (en) * 1984-05-07 1986-06-03 Mobil Oil Corporation Process for upgrading petroleum residua
US5250588A (en) * 1990-01-16 1993-10-05 Ceram Sna Inc. Organic friction material composition for use to produce friction linings

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3047490A (en) * 1958-11-04 1962-07-31 Phillips Petroleum Co Hydrocracking process
FR1327395A (en) * 1962-05-29 1963-05-17 California Research Corp Process for the hydrogenating cracking of petroleum hydrocarbons
US3242068A (en) * 1962-12-24 1966-03-22 Chevron Res Production of lubricating oil
US3308055A (en) * 1964-04-13 1967-03-07 Chevron Res Hydrocracking process producing lubricating oil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5358628A (en) * 1990-07-05 1994-10-25 Mobil Oil Corporation Production of high viscosity index lubricants

Also Published As

Publication number Publication date
NL144326B (en) 1974-12-16
ES324827A1 (en) 1967-02-16
DE1276264B (en) 1968-08-29
SE308936B (en) 1969-03-03
US3444071A (en) 1969-05-13
BE678609A (en) 1966-09-29
CH479687A (en) 1969-10-15
NO115222B (en) 1968-09-02
NL6504066A (en) 1966-10-03

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