KR890003929A - 탄화수소 오일의 수소화 방법 및 이로부터 얻은 케로젠 분류물 순환오일 또는 수소첨가 분해 생성불 - Google Patents

탄화수소 오일의 수소화 방법 및 이로부터 얻은 케로젠 분류물 순환오일 또는 수소첨가 분해 생성불 Download PDF

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KR890003929A
KR890003929A KR1019880010323A KR880010323A KR890003929A KR 890003929 A KR890003929 A KR 890003929A KR 1019880010323 A KR1019880010323 A KR 1019880010323A KR 880010323 A KR880010323 A KR 880010323A KR 890003929 A KR890003929 A KR 890003929A
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process according
boiling point
catalyst
hydrogenation
hydrogenated
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KR1019880010323A
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KR970001186B1 (ko
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코르넬리스 민더하우트 요하네스
위시엥 쟈그
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오노 알버어스
셀 인터나쵸나아레 레시아치 마아츠 샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/54—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

탄화수소 오일의 수소화 방법 및 이로부터 얻은 케로젠 분류물 순환 오일 또는 수소첨가 분해 생성불
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 24.20-24.30°A의 단위 셀크기 및 적어도 25의 SiO2/Al2O3몰 비율을 갖는 개질된 Y-형 제올라이트를 포함하는 지지체 상에 하나 또는그 이상의VIII즉 귀금속(들)을 포함하는 촉매를 사용하여 상당한 수소화를 일으키는 조건하에서 수소화가능한 성분들을 함유하고 130-520℃의 비점을 갖는 탄화수소 오일을 수소화 접촉시키고 원료의 90%W비점-원료의 최종 비점의 비점 범위를 갖고, 원료의 90%W비점-원료의 최종 비점의 비점 범위를 가지며 중량 기준으로 적어도 50%의 물질을 함유하고 있는 적어도 하나의 분류물을 함유하는 생성물을 회수하는 것으로 구성되는 탄호수소 오일의 수소화 방법.
  2. 제1항에 있어서, 24.22-24.28°A의 단위 셀 크기를 갖는 개질된 Y-제올라이트를 기재로 하는 촉매를 사용하는 방법.
  3. 제1항 또는 제2항에 있어서, 35를 넘는 SiO2/Al2O3몰 비율을 갖는 개질된 Y-제올라이트를 기재로 하는 촉매를 사용하는 방법.
  4. 제3항에 있어서, 35-60위 SiO2/Al2O3몰 비율을 갖는 개질된 Y-제올라이트를 기재로 하는 촉매를 사용하는 방법.
  5. 제1항에 내지 제4항중 어느 한항에 있어서, Y-형 제올라이트를 탈알루미나화시켜 얻어진 촉매 지지체를 사용하는 방법.
  6. 제1항에 내지 제5항중 어느 한항에 있어서, 귀금속(들)으로서 백금 및/또는 팔라듐을 함유하는 촉매를 사용하는 방법.
  7. 제6항에 있어서, 제올라이트 상 0.05-3%W의 귀금속(들)을 사용하는 방법.
  8. 제7항에 있어서, 0.25-0.75몰 비율의 백금 및 팔라듐을 사용하는 방법.
  9. 제1항 내지 제8항중 어느 한항에 있어서, 예비처리시킨 원료를 사용하는 방법.
  10. 제9항에 있어서, 예비처리가 무정형 담체상 VI족 및/또는 VIII족 금속 화합물을 사용하는 수소 처리를 포함하는방법.
  11. 제10항에 있어서, 원료의 황 및 질소 수준을 각각 1000ppmw및 50ppmw이하로 감소시키기 위한 그런 방식으로 수소 처리를 수행하는방법.
  12. 제1항에 내지 제11항중 어느 한항에 있어서 , 150-350℃의 온도에서 수소화물 수행하는 방법.
  13. 제12항에 있어서, 200-325℃, 특히 225-300℃의 온도에서 수소화를수행하는 방법.
  14. 제1항 내지 제13항중 어느 한항에있어서, 수소화가능한성분의 총량의 적어도 70%가 수소화되는 방법.
  15. 제14항에있어서, 수소화가능한 성분의 총량의 적어도 80%,특히 90%이상의 수소화되는 방법.
  16. 제1항 내지 제15항중 어느 한항에 있어서, 20-250바아, 바람직하게는 20-200바아, 특히 30-100바아 범위의 수소 부분 압력에서 수소화를 수행하는 방법.
  17. 제1항 내지 제16항중 어느 한항에 있어서,케로젠 원료가 수소화되는 방법.
  18. 제1항 내지 제16항중 어느 한항에 있어서,수소첨가 분해법에 의해 얻어진 순환오일 또는 생성물이 수소화되는 방법.
  19. 제1항 내지 제17항중 어느 한항에 청구된 방법에 의해얻어지는 케로젠 분류물.
  20. 제1항 내지 제16항 또는 제18항중 어느 한항에 청구된 방법에 의해 얻어진 순환 오일 또는 수소첨가 분해 생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880010323A 1987-08-14 1988-08-11 탄화수소 오일의 수소화 방법 및 이로부터 얻은 케로젠 분획물, 순환오일 또는 수소화 분해 생성물 KR970001186B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8711591A FR2619390A1 (fr) 1987-08-14 1987-08-14 Procede d'hydrogenation d'huiles hydrocarbonees
FR8711591 1987-08-14

Publications (2)

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KR890003929A true KR890003929A (ko) 1989-04-18
KR970001186B1 KR970001186B1 (ko) 1997-01-29

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Country Status (15)

Country Link
US (1) US4960505A (ko)
EP (1) EP0303332B1 (ko)
JP (1) JP2881692B2 (ko)
KR (1) KR970001186B1 (ko)
AR (1) AR240742A1 (ko)
AU (1) AU602115B2 (ko)
BR (1) BR8804053A (ko)
CA (1) CA1311435C (ko)
DE (1) DE3865580D1 (ko)
ES (1) ES2025279B3 (ko)
FR (1) FR2619390A1 (ko)
MX (1) MX170167B (ko)
PH (1) PH27017A (ko)
SG (1) SG95992G (ko)
ZA (1) ZA885921B (ko)

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Publication number Publication date
EP0303332A1 (en) 1989-02-15
CA1311435C (en) 1992-12-15
KR970001186B1 (ko) 1997-01-29
DE3865580D1 (de) 1991-11-21
BR8804053A (pt) 1990-03-20
FR2619390A1 (fr) 1989-02-17
JPS6466292A (en) 1989-03-13
AU2096188A (en) 1989-02-16
MX170167B (es) 1993-08-10
EP0303332B1 (en) 1991-10-16
AU602115B2 (en) 1990-09-27
PH27017A (en) 1993-02-01
ES2025279B3 (es) 1992-03-16
ZA885921B (en) 1989-04-26
US4960505A (en) 1990-10-02
JP2881692B2 (ja) 1999-04-12
SG95992G (en) 1992-12-04
AR240742A1 (es) 1990-10-31

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