KR20140002628A - 탄소-함유 지지체의 제조 방법 - Google Patents
탄소-함유 지지체의 제조 방법 Download PDFInfo
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- KR20140002628A KR20140002628A KR1020137009239A KR20137009239A KR20140002628A KR 20140002628 A KR20140002628 A KR 20140002628A KR 1020137009239 A KR1020137009239 A KR 1020137009239A KR 20137009239 A KR20137009239 A KR 20137009239A KR 20140002628 A KR20140002628 A KR 20140002628A
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- Prior art keywords
- carbon
- metal
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- carbide
- catalyst
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- 239000000203 mixture Substances 0.000 claims abstract description 58
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- 229910052792 caesium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- GFHNAMRJFCEERV-UHFFFAOYSA-L cobalt chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Co+2] GFHNAMRJFCEERV-UHFFFAOYSA-L 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011262 electrochemically active material Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- MINVSWONZWKMDC-UHFFFAOYSA-L mercuriooxysulfonyloxymercury Chemical compound [Hg+].[Hg+].[O-]S([O-])(=O)=O MINVSWONZWKMDC-UHFFFAOYSA-L 0.000 description 1
- RPZHFKHTXCZXQV-UHFFFAOYSA-N mercury(i) oxide Chemical compound O1[Hg][Hg]1 RPZHFKHTXCZXQV-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- PCLURTMBFDTLSK-UHFFFAOYSA-N nickel platinum Chemical compound [Ni].[Pt] PCLURTMBFDTLSK-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012713 reactive precursor Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 description 1
- MSKUQSSJMRFOEG-UHFFFAOYSA-N urea;vanadium Chemical compound [V].NC(N)=O MSKUQSSJMRFOEG-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10176553.5 | 2010-09-14 | ||
| EP10176553 | 2010-09-14 | ||
| PCT/IB2011/054014 WO2012035501A1 (en) | 2010-09-14 | 2011-09-14 | Process for producing carbon-comprising support |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140002628A true KR20140002628A (ko) | 2014-01-08 |
Family
ID=45831073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137009239A Withdrawn KR20140002628A (ko) | 2010-09-14 | 2011-09-14 | 탄소-함유 지지체의 제조 방법 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2616173A4 (https=) |
| JP (1) | JP2013539718A (https=) |
| KR (1) | KR20140002628A (https=) |
| CN (1) | CN103118779A (https=) |
| WO (1) | WO2012035501A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9780386B2 (en) | 2014-08-08 | 2017-10-03 | Samsung Electronics Co., Ltd. | Composite for lithium air battery, method of preparing the composite, and lithium air battery employing positive electrode including the composite |
| KR20220053289A (ko) * | 2020-10-22 | 2022-04-29 | 에쓰대시오일 주식회사 | 금속 수산화물층/텅스텐 카바이드 나노선 복합체, 이의 제조방법 및 상기 금속 수산화물층/텅스텐 카바이드 나노선 복합체를 포함하는 수소발생반응용 촉매 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013182535A1 (de) * | 2012-06-06 | 2013-12-12 | Basf Se | Verfahren zur herstellung von stickstoff-dotierten übergangsmetallkatalysatoren und ihre verwendung für die elektrochemische oxidation von s(iv) verbindungen |
| CN102773114B (zh) * | 2012-06-21 | 2014-02-26 | 黑龙江大学 | 石墨纳米薄片上负载氮化物的方法及其用途 |
| CN103359808B (zh) * | 2013-06-25 | 2015-03-04 | 广东工业大学 | 一种负载Pt、Ir的多孔碳化陶瓷膜管复合阳极及其制备方法和应用 |
| JP5706595B1 (ja) * | 2013-07-12 | 2015-04-22 | 昭和電工株式会社 | 酸素還元触媒、その用途およびその製造方法 |
| CN105377423A (zh) * | 2013-07-12 | 2016-03-02 | 昭和电工株式会社 | 氧还原催化剂及其用途 |
| KR101437390B1 (ko) | 2013-12-05 | 2014-09-04 | 대한민국 | 마이크로파 조사로 만든 자성을 띈 활성탄 및 그 제조방법 |
| JP2015150480A (ja) * | 2014-02-13 | 2015-08-24 | 国立研究開発法人産業技術総合研究所 | 燃料電池用触媒 |
| EP3119514A4 (en) * | 2014-03-18 | 2017-11-01 | Basf Se | A process for the production of a carbon supported catalyst |
| CN103920519B (zh) * | 2014-04-23 | 2016-03-30 | 西南大学 | 基于铁钨双金属氧化物增强氮掺杂石墨烯的氧还原电催化剂的制备方法 |
| JP6430168B2 (ja) * | 2014-08-05 | 2018-11-28 | 旭化成株式会社 | 炭素材料複合体、窒素含有炭素材料、及びそれらの製造方法 |
| EP3106543A1 (en) * | 2015-06-17 | 2016-12-21 | Basf Se | Modified carbon material for use in water electrolysis |
| CN105032460B (zh) | 2015-06-23 | 2018-02-02 | 华南理工大学 | 基于氮化物纳米粒子的低铂催化剂及其制备方法 |
| CN105132941B (zh) * | 2015-09-10 | 2017-11-07 | 北京航空航天大学 | 一种二硒化钼/炭黑复合析氢电催化材料及其制备方法 |
| CN105200450B (zh) * | 2015-09-10 | 2017-08-25 | 北京航空航天大学 | 一种二硫化钼/炭黑复合析氢电催化材料及其制备方法 |
| CN105944746B (zh) * | 2016-05-18 | 2018-09-14 | 中国科学院理化技术研究所 | 一种碳负载氮化镍催化剂及其制备方法和应用 |
| CN107768687B (zh) * | 2017-10-22 | 2020-05-15 | 苏州朗泰新能源科技有限公司 | 一种燃料电池催化剂及其制备方法 |
| CN109962232B (zh) * | 2017-12-22 | 2022-05-13 | 惠州比亚迪电子有限公司 | 正极活性材料、制备方法、正极和电池 |
| CN109994715B (zh) * | 2018-01-03 | 2021-08-24 | 国家纳米科学中心 | 一种自支撑电极及其制备方法和用途 |
| CN108435225B (zh) * | 2018-03-09 | 2020-12-11 | 浙江工业大学 | 一种Fe-N/C复合催化剂及其制备方法和应用 |
| CN109686982A (zh) * | 2019-01-29 | 2019-04-26 | 冯良荣 | 一种制备负载型碳氮化物的方法 |
| US11600812B2 (en) * | 2019-07-17 | 2023-03-07 | Phillips 66 Company | Electrode particles suitable for batteries |
| CN112705235B (zh) * | 2019-10-24 | 2023-08-08 | 中国石油化工股份有限公司 | 碳包覆碳化镍的纳米复合材料及其制备方法和应用 |
| CN115505954A (zh) * | 2021-06-04 | 2022-12-23 | 丰田自动车株式会社 | 铂基纳米异质材料及其制备方法 |
| CN113506885B (zh) * | 2021-06-25 | 2022-11-15 | 中自环保科技股份有限公司 | 一种氢燃料电池用石墨化碳载体、制备方法及其电池催化剂 |
| CN114538517B (zh) * | 2022-03-31 | 2023-12-22 | 洛阳师范学院 | 一种Mo2C和碳包夹的钼基异质结构材料及其制备方法和应用 |
| CN114990628B (zh) * | 2022-07-13 | 2023-10-20 | 山东大学 | 焦耳热快速合成的双功能电催化剂及其在高效水分解中的应用 |
| TW202411162A (zh) * | 2022-08-05 | 2024-03-16 | 日商Dic股份有限公司 | 碳化鉬、複合體、觸媒油墨、碳化鉬之製造方法、及複合體之製造方法 |
| CN116334682A (zh) * | 2023-02-17 | 2023-06-27 | 湖南中驰氢能科技有限公司 | 一种基于W、Mo、N共掺杂载体的低Pt酸性HER催化剂及其制备方法和应用 |
| CN119764453B (zh) * | 2024-12-30 | 2026-02-24 | 孝感楚能新能源创新科技有限公司 | 正极材料补钠剂分解用氮掺杂过渡金属碳化物催化剂及其制备方法和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7714575A (nl) * | 1977-12-30 | 1979-07-03 | Shell Int Research | Werkwijze voor het activeren van een katalysator voor brandstofcelelektroden. |
| US5240893A (en) * | 1992-06-05 | 1993-08-31 | General Motors Corporation | Method of preparing metal-heterocarbon-nitrogen catalyst for electrochemical cells |
| MX261990B (es) * | 2002-02-14 | 2008-11-07 | Monsanto Technology Llc | Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo. |
| US20030228972A1 (en) * | 2002-06-05 | 2003-12-11 | Birss Viola | Oxygen reduction catalyst |
| CN102276644B (zh) * | 2003-08-14 | 2014-09-03 | 孟山都技术公司 | 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途 |
| WO2006138282A2 (en) * | 2005-06-13 | 2006-12-28 | Enerage, Inc. | Supported metal electrocatalyst materials and the method for forming the same |
| CN100461511C (zh) * | 2006-10-13 | 2009-02-11 | 北京工业大学 | 一种直接甲醇燃料电池阴极非贵金属催化剂的制备方法 |
| ATE524843T1 (de) * | 2007-04-12 | 2011-09-15 | 3M Innovative Properties Co | Leistungsstarke und langlebige nichtedelmetall- brennstoffzellenkatalysatoren |
| CN101411975A (zh) * | 2007-10-19 | 2009-04-22 | 中国科学院大连化学物理研究所 | 一种炭载过渡金属碳化物催化剂在肼分解反应中的应用 |
-
2011
- 2011-09-14 KR KR1020137009239A patent/KR20140002628A/ko not_active Withdrawn
- 2011-09-14 WO PCT/IB2011/054014 patent/WO2012035501A1/en not_active Ceased
- 2011-09-14 JP JP2013528809A patent/JP2013539718A/ja active Pending
- 2011-09-14 EP EP11824677.6A patent/EP2616173A4/en not_active Withdrawn
- 2011-09-14 CN CN2011800437732A patent/CN103118779A/zh active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9780386B2 (en) | 2014-08-08 | 2017-10-03 | Samsung Electronics Co., Ltd. | Composite for lithium air battery, method of preparing the composite, and lithium air battery employing positive electrode including the composite |
| KR20220053289A (ko) * | 2020-10-22 | 2022-04-29 | 에쓰대시오일 주식회사 | 금속 수산화물층/텅스텐 카바이드 나노선 복합체, 이의 제조방법 및 상기 금속 수산화물층/텅스텐 카바이드 나노선 복합체를 포함하는 수소발생반응용 촉매 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2616173A1 (en) | 2013-07-24 |
| JP2013539718A (ja) | 2013-10-28 |
| EP2616173A4 (en) | 2014-07-16 |
| CN103118779A (zh) | 2013-05-22 |
| WO2012035501A1 (en) | 2012-03-22 |
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