KR20040097336A - 아미노 하이드록시벤조페논의 유기실리콘 유도체 및 이의화장품 제조에서 uv-a 필터로서의 용도 - Google Patents
아미노 하이드록시벤조페논의 유기실리콘 유도체 및 이의화장품 제조에서 uv-a 필터로서의 용도 Download PDFInfo
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- KR20040097336A KR20040097336A KR10-2004-7016207A KR20047016207A KR20040097336A KR 20040097336 A KR20040097336 A KR 20040097336A KR 20047016207 A KR20047016207 A KR 20047016207A KR 20040097336 A KR20040097336 A KR 20040097336A
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- South Korea
- Prior art keywords
- formula
- organosilicon compound
- derivatives
- acid
- hydrogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
Abstract
Description
Claims (8)
- 하기 화학식 I의 단위 및 선택적으로 하기 화학식 II의 단위를 포함하는 유기실리콘 화합물:화학식 I상기 식에서,a는 0, 1 또는 2이고;R1은 수소, 포화 또는 불포화 C1-C30탄화수소 기, 또는 트라이메틸실릴옥시 기이고;Z는 하기 화학식 III의 아미노 치환된 하이드록시벤조페논이다:화학식 III[상기 식에서,R3및 R4는 독립적으로 수소, C1-C20알킬, C2-C20알케닐, C3-C10사이클로알킬 또는 C3-C10사이클로알켄일이거나, 또는 R3및 R4는 이들이 부착된 질소 원자와 함께 5내지 6원의 고리를 형성하고;X는 -O- 또는 -NR5-이고, 여기에서 R5는 수소, C1-C20알킬, C2-C20알켄일, C3-C10사이클로알킬 또는 C3-C10사이클로알켄일이고;Y는 2가의 C3-C12알킬렌 또는 알켄일렌 사슬이다]화학식 II상기 식에서,b는 0, 1, 2 또는 3이고;R2는 수소, 포화 또는 불포화 C1-C30탄화수소 기 또는 트라이메틸실릴옥시 기이다.
- 하기 화학식 IVa의 하나의 구조단위, 하기 화학식 IVb의 하나의 구조단위, 하기 화학식 IVc의 s개 단위(이때, s는 0 내지 50의 정수이다) 및 하기 화학식 IVd의 r개 단위(이때, r은 0 내지 200의 정수이다)를 포함하는 선형 다이-유기실록산 중합체:화학식 IVa화학식 IVb화학식 IVc화학식 IVd상기 식에서,Z는 제 1 항에서 정의한 바와 같고;R1, R6, R7, R8, R9, R10및 R11은 독립적으로 제 1 항에서 R2에 대해 정의한 바와 같고;B 및 B'은 독립적으로 Z 기 또는 R2기이고;단, s가 0일 경우 B 및 B' 중 하나 이상은 Z이다.
- 하기 화학식 VI의 단위 및 선택적으로 제 1 항에 따른 화학식 II의 단위를 포함하는 유기실리콘 화합물을 하기 화학식 VII의 화합물과 반응(수소규소화 반응)시키는것을 포함하는, 제 1 항에 따른 유기실리콘 화합물의 제조방법:화학식 VI[상기 식에서,a는 0, 1 또는 2이고;R1은 수소, 포화 또는 불포화 C1-C30탄화수소 기 또는 트라이메틸실릴옥시 기이다]화학식 VII[상기 식에서,R3, R4및 X는 제 1 항에서 정의한 바와 같고;Y'은 제 1 항에서 Y에 대해 정의한 바와 동일하되, 이중 또는 삼중 결합으로 종결된다].
- 제 1 항에 따른 유기실리콘 화합물을 미용적으로 허용되는 보조제 및 첨가제와 함께 포함하는 화장품 조성물.
- 제 1 항에 따른 유기실리콘 화합물을 포함하는, UV-A 조사의 역할로부터 비롯되거나 이와 관련된 손상에 대해 인체 모발 및/또는 피부를 보호하기 위한 화장품 조성물.
- 유효량의 제 1 항에 따른 유기실리콘 화합물을 국소적으로 적용하는 것을 포함하는, UV-A 조사의 역할로부터 비롯되거나 이와 관련된 손상에 대해 인체 모발 및/또는 피부를 보호하는 방법.
- UV-A 조사의 역할로부터 비롯되거나 이와 관련된 손상에 대해 인체 모발 및/또는 피부를 보호하기 위한, 제 1 항에 따른 유기실리콘 화합물의 용도.
- 실질적으로 상기에서 개시한 바, 특히 실시예로서 언급한 바와 같은 발명.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02008419.0 | 2002-04-12 | ||
EP02008419 | 2002-04-12 | ||
PCT/EP2003/003095 WO2003086340A1 (en) | 2002-04-12 | 2003-03-25 | Organosilicone derivatives of amino hydroxybenzophenones and their use as uv-a filters in cosmetic preparations |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20040097336A true KR20040097336A (ko) | 2004-11-17 |
KR100929303B1 KR100929303B1 (ko) | 2009-11-27 |
Family
ID=29225587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020047016207A KR100929303B1 (ko) | 2002-04-12 | 2003-03-25 | 아미노 하이드록시벤조페논의 유기실리콘 유도체 및 이의 화장품 제조에서 uv-a 필터로서의 용도 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7388102B2 (ko) |
EP (1) | EP1494642B1 (ko) |
JP (1) | JP4349915B2 (ko) |
KR (1) | KR100929303B1 (ko) |
CN (1) | CN100424076C (ko) |
AT (1) | ATE460152T1 (ko) |
AU (1) | AU2003226709A1 (ko) |
BR (1) | BRPI0309195B8 (ko) |
DE (1) | DE60331637D1 (ko) |
ES (1) | ES2341441T3 (ko) |
WO (1) | WO2003086340A1 (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2004290493B2 (en) * | 2003-11-05 | 2009-09-24 | Dsm Ip Assets B.V. | Light protecting composition with reduced total amount of UV filter containing a polysiloxane-based UV filter |
KR101123520B1 (ko) * | 2003-12-04 | 2012-03-13 | 디에스엠 아이피 어셋츠 비.브이. | 자외선 필터 활성을 갖는 미세캡슐 및 그의 제조방법 |
KR101256248B1 (ko) * | 2005-03-23 | 2013-04-18 | 디에스엠 아이피 어셋츠 비.브이. | 폴리실록세인으로 코팅된 금속 산화물 입자 |
CN101189045B (zh) * | 2005-05-31 | 2013-07-24 | 帝斯曼知识产权资产管理有限公司 | 新颖的聚硅氧烷遮光剂 |
EP1981895B1 (en) * | 2006-02-09 | 2016-04-27 | Basf Se | Hydroxybenzophenone derivatives |
JP5878783B2 (ja) * | 2012-02-20 | 2016-03-08 | ポーラ化成工業株式会社 | 乳化形化粧料 |
CN105339344B (zh) * | 2013-06-27 | 2018-04-20 | 帝斯曼知识产权资产管理有限公司 | 生产2‑(4‑n,n‑二烷基氨基‑2‑羟基苯甲酰基)苯甲酸酯的方法 |
EP3013788B1 (en) | 2013-06-27 | 2019-02-27 | DSM IP Assets B.V. | Method for producing 2-(4-n,n-dialkylamino-2-hydroxybenzoyl) benzoates |
FR3015896B1 (fr) * | 2013-12-31 | 2017-10-13 | Novance | Solubilisation de filtres uv |
KR101833612B1 (ko) * | 2016-03-30 | 2018-02-28 | 선진뷰티사이언스(주) | 다량의 유기계 자외선 차단제를 함유하는 고분자 복합입자 및 그의 제조방법 |
CN110204668B (zh) * | 2019-05-15 | 2021-09-24 | 大连理工大学 | 一类适用于硅氢加成化学反应的双硅氢功能化线形聚合物及其制备方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1527781A (fr) * | 1966-12-23 | 1968-06-07 | Rhone Poulenc Sa | Nouveaux composés organosiliciques à fonctions ester |
US5270426A (en) * | 1990-01-22 | 1993-12-14 | Shin-Etsu Chemical Co., Ltd. | Organosilicon compound |
JP2527093B2 (ja) * | 1990-09-25 | 1996-08-21 | 信越化学工業株式会社 | 有機珪素化合物及び化粧料 |
FR2684551B1 (fr) * | 1991-12-05 | 1995-04-21 | Oreal | Huile cosmetique filtrante contenant une silicone filtre et un melange d'une silicone volatile et d'une huile de silicone ou d'une gomme de silicone et emulsion cosmetique filtrante contenant une telle huile. |
JP3428104B2 (ja) * | 1993-11-25 | 2003-07-22 | 株式会社資生堂 | ベンゾフェノン誘導体、紫外線吸収剤及び皮膚外用剤 |
FR2727115B1 (fr) | 1994-11-17 | 1996-12-27 | Oreal | Nouveaux filtres solaires, compositions cosmetiques photoprotectrices les contenant et utilisations |
US6114561A (en) * | 1998-03-16 | 2000-09-05 | O'lenick, Jr.; Anthony J. | Silicone sunscreening esters |
FR2782516B1 (fr) * | 1998-08-21 | 2001-09-07 | Oreal | Procede de photostabilisation de filtres solaires derives du dibenzoylmethane, compositions cosmetiques filtrantes photostabilisees ainsi obtenues et leurs utilisation |
DE19917906A1 (de) * | 1999-04-20 | 2000-10-26 | Basf Ag | Verwendung von aminosubstituierten Hydroxybenzophenonen als photostabile UV-Filter in kosmetischen und pharmazeutischen Zubereitungen |
DE10012408A1 (de) * | 2000-03-15 | 2001-09-20 | Basf Ag | Verwendung von Lichtschutzmittelkombinationen, die als wesentlichen Bestandteil aminosubstituierte Hydroxybenzophenone enthalten als photostabile UV-Filter in kosmetischen und pharmazeutischen Zubereitungen |
DE10015086A1 (de) * | 2000-03-28 | 2001-10-04 | Basf Ag | Textilfaseraffine UV-Absorber-Mischung |
-
2003
- 2003-03-25 KR KR1020047016207A patent/KR100929303B1/ko active IP Right Grant
- 2003-03-25 EP EP03746278A patent/EP1494642B1/en not_active Expired - Lifetime
- 2003-03-25 DE DE60331637T patent/DE60331637D1/de not_active Expired - Lifetime
- 2003-03-25 ES ES03746278T patent/ES2341441T3/es not_active Expired - Lifetime
- 2003-03-25 BR BRPI0309195A patent/BRPI0309195B8/pt not_active IP Right Cessation
- 2003-03-25 JP JP2003583364A patent/JP4349915B2/ja not_active Expired - Fee Related
- 2003-03-25 WO PCT/EP2003/003095 patent/WO2003086340A1/en active Application Filing
- 2003-03-25 US US10/511,020 patent/US7388102B2/en not_active Expired - Lifetime
- 2003-03-25 CN CNB038083205A patent/CN100424076C/zh not_active Expired - Fee Related
- 2003-03-25 AU AU2003226709A patent/AU2003226709A1/en not_active Abandoned
- 2003-03-25 AT AT03746278T patent/ATE460152T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1646091A (zh) | 2005-07-27 |
AU2003226709A1 (en) | 2003-10-27 |
KR100929303B1 (ko) | 2009-11-27 |
US7388102B2 (en) | 2008-06-17 |
CN100424076C (zh) | 2008-10-08 |
JP4349915B2 (ja) | 2009-10-21 |
EP1494642A1 (en) | 2005-01-12 |
ATE460152T1 (de) | 2010-03-15 |
BR0309195A (pt) | 2005-02-09 |
WO2003086340A1 (en) | 2003-10-23 |
US20050255066A1 (en) | 2005-11-17 |
EP1494642B1 (en) | 2010-03-10 |
BRPI0309195B8 (pt) | 2016-05-31 |
BR0309195B1 (pt) | 2014-02-11 |
ES2341441T3 (es) | 2010-06-21 |
JP2005539099A (ja) | 2005-12-22 |
DE60331637D1 (de) | 2010-04-22 |
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