KR20040091757A - 화장 조성물내의 레조르시놀 유도체의 안정화 - Google Patents
화장 조성물내의 레조르시놀 유도체의 안정화 Download PDFInfo
- Publication number
- KR20040091757A KR20040091757A KR10-2004-7014632A KR20047014632A KR20040091757A KR 20040091757 A KR20040091757 A KR 20040091757A KR 20047014632 A KR20047014632 A KR 20047014632A KR 20040091757 A KR20040091757 A KR 20040091757A
- Authority
- KR
- South Korea
- Prior art keywords
- resorcinol
- alkyl
- composition
- esters
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 103
- 239000002537 cosmetic Substances 0.000 title claims abstract description 31
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 title claims description 19
- 230000006641 stabilisation Effects 0.000 title description 4
- 238000011105 stabilization Methods 0.000 title description 4
- -1 4-substituted resorcinol Chemical class 0.000 claims abstract description 59
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 30
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 30
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 25
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Natural products OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 22
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 16
- 239000000516 sunscreening agent Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 12
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 238000002845 discoloration Methods 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- VGMJYYDKPUPTID-UHFFFAOYSA-N 4-ethylbenzene-1,3-diol Chemical compound CCC1=CC=C(O)C=C1O VGMJYYDKPUPTID-UHFFFAOYSA-N 0.000 claims description 6
- 239000003623 enhancer Substances 0.000 claims description 6
- LSEHCENPUMUIKC-UHFFFAOYSA-N 4-cyclohexylbenzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1C1CCCCC1 LSEHCENPUMUIKC-UHFFFAOYSA-N 0.000 claims description 5
- IXMNGROEFGBSGO-UHFFFAOYSA-N 4-cyclopentylbenzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1C1CCCC1 IXMNGROEFGBSGO-UHFFFAOYSA-N 0.000 claims description 5
- 229930188104 Alkylresorcinol Natural products 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 4
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 claims description 4
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 claims description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229960001679 octinoxate Drugs 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 claims description 3
- LALVCWMSKLEQMK-UHFFFAOYSA-N 1-phenyl-3-(4-propan-2-ylphenyl)propane-1,3-dione Chemical compound C1=CC(C(C)C)=CC=C1C(=O)CC(=O)C1=CC=CC=C1 LALVCWMSKLEQMK-UHFFFAOYSA-N 0.000 claims description 3
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 claims description 3
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 3
- 239000004101 4-Hexylresorcinol Substances 0.000 claims description 3
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 3
- WFJIVOKAWHGMBH-UHFFFAOYSA-N 4-hexylbenzene-1,3-diol Chemical compound CCCCCCC1=CC=C(O)C=C1O WFJIVOKAWHGMBH-UHFFFAOYSA-N 0.000 claims description 3
- 235000019360 4-hexylresorcinol Nutrition 0.000 claims description 3
- 229920001273 Polyhydroxy acid Polymers 0.000 claims description 3
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 3
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 3
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 3
- 150000001277 beta hydroxy acids Chemical class 0.000 claims description 3
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 claims description 3
- CBZHHQOZZQEZNJ-UHFFFAOYSA-N ethyl 4-[bis(2-hydroxypropyl)amino]benzoate Chemical compound CCOC(=O)C1=CC=C(N(CC(C)O)CC(C)O)C=C1 CBZHHQOZZQEZNJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229960003258 hexylresorcinol Drugs 0.000 claims description 3
- 229960004881 homosalate Drugs 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 claims description 3
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 claims description 2
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 claims description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 2
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 claims description 2
- ODCAWUSPKFJJPH-UHFFFAOYSA-N 4-cycloheptylbenzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1C1CCCCCC1 ODCAWUSPKFJJPH-UHFFFAOYSA-N 0.000 claims description 2
- ORRJPSVKFKJXTB-UHFFFAOYSA-N 4-cyclooctylbenzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1C1CCCCCCC1 ORRJPSVKFKJXTB-UHFFFAOYSA-N 0.000 claims description 2
- CSHZYWUPJWVTMQ-UHFFFAOYSA-N 4-n-Butylresorcinol Chemical compound CCCCC1=CC=C(O)C=C1O CSHZYWUPJWVTMQ-UHFFFAOYSA-N 0.000 claims description 2
- LNFVQIGQENWZQN-UHFFFAOYSA-N 4-propan-2-ylbenzene-1,3-diol Chemical compound CC(C)C1=CC=C(O)C=C1O LNFVQIGQENWZQN-UHFFFAOYSA-N 0.000 claims description 2
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 claims description 2
- 229960005193 avobenzone Drugs 0.000 claims description 2
- 229940111759 benzophenone-2 Drugs 0.000 claims description 2
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 claims description 2
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 claims description 2
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 claims description 2
- 229940114124 ferulic acid Drugs 0.000 claims description 2
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 claims description 2
- 235000001785 ferulic acid Nutrition 0.000 claims description 2
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 claims description 2
- 229960004705 kojic acid Drugs 0.000 claims description 2
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 claims description 2
- 229960003921 octisalate Drugs 0.000 claims description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 2
- 229960000601 octocrylene Drugs 0.000 claims description 2
- WCJLCOAEJIHPCW-UHFFFAOYSA-N octyl 2-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1O WCJLCOAEJIHPCW-UHFFFAOYSA-N 0.000 claims description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical group OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 2
- 229960001173 oxybenzone Drugs 0.000 claims description 2
- 230000002207 retinal effect Effects 0.000 claims description 2
- NCYCYZXNIZJOKI-OVSJKPMPSA-N retinal group Chemical group C\C(=C/C=O)\C=C\C=C(\C=C\C1=C(CCCC1(C)C)C)/C NCYCYZXNIZJOKI-OVSJKPMPSA-N 0.000 claims description 2
- 229960003471 retinol Drugs 0.000 claims description 2
- 235000020944 retinol Nutrition 0.000 claims description 2
- 239000011607 retinol Substances 0.000 claims description 2
- 125000000946 retinyl group Chemical group [H]C([*])([H])/C([H])=C(C([H])([H])[H])/C([H])=C([H])/C([H])=C(C([H])([H])[H])/C([H])=C([H])/C1=C(C([H])([H])[H])C([H])([H])C([H])([H])C([H])([H])C1(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 229960000368 sulisobenzone Drugs 0.000 claims description 2
- 230000000699 topical effect Effects 0.000 claims description 2
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 claims description 2
- UEVAMYPIMMOEFW-UHFFFAOYSA-N trolamine salicylate Chemical compound OCCN(CCO)CCO.OC(=O)C1=CC=CC=C1O UEVAMYPIMMOEFW-UHFFFAOYSA-N 0.000 claims description 2
- VEXDRERIMPLZLU-UHFFFAOYSA-N 3-hydroxy-2-methylbutanoic acid Chemical compound CC(O)C(C)C(O)=O VEXDRERIMPLZLU-UHFFFAOYSA-N 0.000 claims 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 claims 1
- WHJVDJMYJOEKQZ-UHFFFAOYSA-N 2-dodecylbenzene-1,3-diol Chemical compound CCCCCCCCCCCCC1=C(O)C=CC=C1O WHJVDJMYJOEKQZ-UHFFFAOYSA-N 0.000 claims 1
- QJZPSSRNQMRETN-UHFFFAOYSA-N 4-decylbenzene-1,3-diol Chemical compound CCCCCCCCCCC1=CC=C(O)C=C1O QJZPSSRNQMRETN-UHFFFAOYSA-N 0.000 claims 1
- PFPZRMUCMKVUEX-UHFFFAOYSA-N 4-heptylbenzene-1,3-diol Chemical compound CCCCCCCC1=CC=C(O)C=C1O PFPZRMUCMKVUEX-UHFFFAOYSA-N 0.000 claims 1
- RVHJRIXOUQNFIL-UHFFFAOYSA-N 4-nonylbenzene-1,3-diol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1O RVHJRIXOUQNFIL-UHFFFAOYSA-N 0.000 claims 1
- JPUHXNRAGDKQRD-UHFFFAOYSA-N 4-octylbenzene-1,3-diol Chemical compound CCCCCCCCC1=CC=C(O)C=C1O JPUHXNRAGDKQRD-UHFFFAOYSA-N 0.000 claims 1
- PJHYOCWMKYASAB-UHFFFAOYSA-N 4-pentylbenzene-1,3-diol Chemical compound CCCCCC1=CC=C(O)C=C1O PJHYOCWMKYASAB-UHFFFAOYSA-N 0.000 claims 1
- DJDHQJFHXLBJNF-UHFFFAOYSA-N 4-propylbenzene-1,3-diol Chemical compound CCCC1=CC=C(O)C=C1O DJDHQJFHXLBJNF-UHFFFAOYSA-N 0.000 claims 1
- WXSPDYAYXOBKMM-UHFFFAOYSA-N 4-undecylbenzene-1,3-diol Chemical compound CCCCCCCCCCCC1=CC=C(O)C=C1O WXSPDYAYXOBKMM-UHFFFAOYSA-N 0.000 claims 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 5
- 125000002252 acyl group Chemical group 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- 239000000194 fatty acid Substances 0.000 description 16
- 239000000126 substance Substances 0.000 description 14
- 230000000475 sunscreen effect Effects 0.000 description 13
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
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- 235000014113 dietary fatty acids Nutrition 0.000 description 10
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- 239000000969 carrier Substances 0.000 description 6
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
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- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- WRHZVMBBRYBTKZ-UHFFFAOYSA-N pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC=CN1 WRHZVMBBRYBTKZ-UHFFFAOYSA-N 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000036620 skin dryness Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36692402P | 2002-03-22 | 2002-03-22 | |
| US60/366,924 | 2002-03-22 | ||
| PCT/EP2003/002655 WO2003080002A1 (en) | 2002-03-22 | 2003-03-13 | Stabilization of resorcinol derivatives in cosmetic compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20040091757A true KR20040091757A (ko) | 2004-10-28 |
Family
ID=28454827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2004-7014632A Ceased KR20040091757A (ko) | 2002-03-22 | 2003-03-13 | 화장 조성물내의 레조르시놀 유도체의 안정화 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6863897B2 (https=) |
| JP (1) | JP2005527534A (https=) |
| KR (1) | KR20040091757A (https=) |
| CN (1) | CN1293857C (https=) |
| AU (1) | AU2003218759A1 (https=) |
| BR (1) | BRPI0307687B1 (https=) |
| MX (1) | MXPA04008842A (https=) |
| WO (1) | WO2003080002A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140040036A (ko) * | 2012-09-24 | 2014-04-02 | 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 | ４치환된 레소르시놀 및 고 탄소 사슬 에스테르를 포함하는 저 오일 조성물 |
| KR20190099206A (ko) * | 2016-12-21 | 2019-08-26 | 유니레버 엔.브이. | 레조르시놀의 색 안정성을 개선하기 위한 킬레이팅제의 용도 |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040109832A1 (en) * | 2002-12-09 | 2004-06-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Di-substituted resorcinols as skin lightening agents |
| US20050282902A1 (en) * | 2004-06-22 | 2005-12-22 | Allergan, Inc. | Abnormal cannabidiols as agents for lowering intraocular pressure |
| US20050282912A1 (en) * | 2004-06-22 | 2005-12-22 | June Chen | Abnormal cannabidiols as neuroprotective agents for the eye |
| US20060210497A1 (en) * | 2005-03-18 | 2006-09-21 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Novel resorcinol derivatives |
| US20090130035A1 (en) * | 2006-01-05 | 2009-05-21 | Symrise Gmbh & Co. Kg | Stabilized preparations comprising phenolic compounds and benzophenones |
| US7618966B2 (en) * | 2006-04-24 | 2009-11-17 | Allergan, Inc. | Abnormal Cannabidiols as agents for lowering intraocular pressure |
| US7612101B2 (en) * | 2006-04-24 | 2009-11-03 | Allergan, Inc. | Abnormal cannabidiols as agents for lowering intraocular pressure |
| US7968711B2 (en) | 2006-04-24 | 2011-06-28 | Allergan, Inc. | Abnormal cannabidiols as agents for lowering intraocular pressure |
| US7718830B2 (en) * | 2006-04-24 | 2010-05-18 | Allergan, Inc. | Abnormal cannabidiols as agents for lowering intraocular pressure |
| US7521505B2 (en) * | 2006-06-12 | 2009-04-21 | Sabic Innovative Plastics Ip B.V. | Method of stabilization of dihydric phenols |
| US20070287796A1 (en) * | 2006-06-12 | 2007-12-13 | General Electric Company | Method of stabilization of dihydric phenols |
| CN101472594B (zh) * | 2006-06-19 | 2014-06-25 | 可乐丽股份有限公司 | 含有三萜酸的皮肤外用制剂 |
| JP5132095B2 (ja) * | 2006-07-13 | 2013-01-30 | ポーラ化成工業株式会社 | エマルション剤形の皮膚外用剤 |
| DE102007038098A1 (de) | 2007-08-13 | 2009-02-19 | Merck Patent Gmbh | Tyrosinaseinhibitoren |
| DE102007038097A1 (de) | 2007-08-13 | 2009-02-19 | Merck Patent Gmbh | Tyrosinaseinhibitoren |
| US8481006B2 (en) * | 2008-04-25 | 2013-07-09 | New Sunshine, Llc | Melt formula |
| US8440237B2 (en) | 2009-04-27 | 2013-05-14 | Mary Kay Inc. | Botanical anti-acne formulations |
| US20110081430A1 (en) * | 2009-10-02 | 2011-04-07 | Simarna Kaur | COMPOSITIONS COMPRISING AN NFkB-INHIBITOR AND A TROPOELASTIN PROMOTER |
| US8084504B2 (en) | 2009-10-02 | 2011-12-27 | Johnson & Johnson Consumer Companies, Inc. | High-clarity aqueous concentrates of 4-hexylresorcinol |
| US20110081305A1 (en) * | 2009-10-02 | 2011-04-07 | Steven Cochran | Compositions comprising a skin-lightening resorcinol and a skin darkening agent |
| CA2774026C (en) * | 2009-10-02 | 2018-04-24 | Johnson & Johnson Consumer Companies, Inc. | Compositions comprising an anti-inflammatory blend |
| US8906432B2 (en) | 2009-10-02 | 2014-12-09 | Johnson & Johnson Consumer Companies, Inc. | Compositions comprising an NFκB-inhibitor and a non-retinoid collagen promoter |
| DE102009048977A1 (de) * | 2009-10-09 | 2011-04-14 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit Kombinationen aus 4-n-Butylresorcin und einem oder mehreren Sulfiten, insbesondere Hydrogensulfiten und/oder Disulfiten |
| EP3566691B1 (en) | 2011-12-19 | 2024-04-17 | Mary Kay Inc. | Cosmetic method of whitening skin and evening tone with azuki beans |
| JP6086706B2 (ja) * | 2012-11-14 | 2017-03-01 | ポーラ化成工業株式会社 | 高い紫外線吸収効果を有する皮膚外用組成物 |
| DE102012222445A1 (de) * | 2012-12-06 | 2014-06-26 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit Kombinationen aus4-n-Butylresorcin und einem oder mehreren nichtterpenoiden Parfumrohstoffen |
| EA031098B1 (ru) | 2013-03-08 | 2018-11-30 | Юнилевер Н.В. | Соединения резорцина для дерматологического применения |
| US9849077B2 (en) | 2014-03-10 | 2017-12-26 | Mary Kay Inc. | Skin lightening compositions |
| US20150272837A1 (en) | 2014-03-27 | 2015-10-01 | Johnson & Johnson Consumer Companies, Inc. | Topical Compositions Comprising A Resorcinol and Powders |
| WO2017194486A1 (en) | 2016-05-12 | 2017-11-16 | Unilever Plc | Method for stabilizing retinoic acid precursors and a skin benefit composition with stabilized retinoic acid precursors |
| JP7084924B2 (ja) | 2016-12-21 | 2022-06-15 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | 難溶性化合物を含むパーソナルケア組成物 |
| US11337908B2 (en) | 2016-12-21 | 2022-05-24 | Conopco, Inc. | Personal care compositions with cystine |
| US11260005B2 (en) | 2016-12-21 | 2022-03-01 | Conopco, Inc. | Personal care compositions with glutathione precursor comprising 4-substituted resorcinols and amino acids |
| EP3558255B1 (en) | 2016-12-21 | 2021-10-13 | Unilever IP Holdings B.V. | Topical skin lightening additive and composition with amino acids and nicotinamide compounds |
| CA3069484A1 (en) | 2017-07-12 | 2019-01-17 | Unilever Plc | Nanoemulsions with color stabilized actives |
| CN112165927B (zh) | 2018-05-23 | 2024-01-30 | 联合利华知识产权控股有限公司 | 纳米乳液及其制备方法 |
| US10537534B1 (en) | 2019-06-25 | 2020-01-21 | Johnson & Johnson Consumer Inc. | Compositions and methods for treating skin conditions using visible light and resorcinols |
| US20200405603A1 (en) | 2019-06-25 | 2020-12-31 | Johnson & Johnson Consumer Inc. | Compositions and methods for treating skin conditions using infrared light and resorcinols |
| EP4427816A3 (en) * | 2019-07-12 | 2025-01-01 | Unilever IP Holdings B.V. | Stabilization of resorcinol compounds in cosmetic compositions |
| MX2022004661A (es) * | 2019-10-25 | 2022-05-25 | Unilever Ip Holdings B V | Composicion cosmetica con estabilidad de color mejorada. |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1024335A (en) | 1963-12-17 | 1966-03-30 | David Oliver Holland | Compositions comprising resorcinol monosalicylate for the treatment of skin diseases |
| GB1581428A (en) | 1978-03-13 | 1980-12-10 | Conoco Inc | Alkylation of aromatic hydroxy compounds |
| FR2611497B1 (fr) | 1987-02-27 | 1989-06-09 | Fabre Pierre Cosmetique | Agglomerats, leur preparation et compositions pharmaceutiques et/ou cosmetiques les contenant |
| JPH0651619B2 (ja) | 1988-05-09 | 1994-07-06 | 株式会社クラレ | 美白剤 |
| US4919934A (en) | 1989-03-02 | 1990-04-24 | Richardson-Vicks Inc. | Cosmetic sticks |
| JPH02292213A (ja) | 1989-05-02 | 1990-12-03 | Kuraray Co Ltd | 制癌剤 |
| DE69012947T2 (de) | 1989-10-27 | 1995-03-30 | Richardson-Vicks Inc., Wilton, Conn. | Lichtschutzmittel mit verbesserter Aktivität. |
| GB9010526D0 (en) | 1990-05-10 | 1990-07-04 | Unilever Plc | Cosmetic composition |
| JPH054905A (ja) | 1990-10-31 | 1993-01-14 | Pola Chem Ind Inc | 化粧料 |
| JP2801960B2 (ja) | 1990-10-31 | 1998-09-21 | ポーラ化成工業株式会社 | 頭髪化粧料 |
| JP2875374B2 (ja) | 1990-10-31 | 1999-03-31 | ポーラ化成工業株式会社 | ニキビ用化粧料 |
| DE69732339T2 (de) | 1996-12-05 | 2005-06-09 | Unilever N.V. | Gelzusammensetzung für Geschirrspülmaschine |
| BR9803596A (pt) * | 1997-09-23 | 2000-04-25 | Pfizer Prod Inc | Derivados do resorcinol. |
| US5961961A (en) | 1998-06-04 | 1999-10-05 | Chesebrough-Pond's Usa Co. | Sunscreen cosmetic composition |
| JP4004182B2 (ja) * | 1999-05-24 | 2007-11-07 | ポーラ化成工業株式会社 | 乳化組成物 |
| EP1134207A1 (en) * | 2000-03-15 | 2001-09-19 | Pfizer Products Inc. | Process for preparing resorcinol derivatives |
-
2003
- 2003-03-11 US US10/385,955 patent/US6863897B2/en not_active Expired - Lifetime
- 2003-03-13 KR KR10-2004-7014632A patent/KR20040091757A/ko not_active Ceased
- 2003-03-13 JP JP2003577834A patent/JP2005527534A/ja active Pending
- 2003-03-13 CN CNB038067560A patent/CN1293857C/zh not_active Expired - Lifetime
- 2003-03-13 BR BRPI0307687-3A patent/BRPI0307687B1/pt not_active IP Right Cessation
- 2003-03-13 AU AU2003218759A patent/AU2003218759A1/en not_active Abandoned
- 2003-03-13 WO PCT/EP2003/002655 patent/WO2003080002A1/en not_active Ceased
- 2003-03-13 MX MXPA04008842A patent/MXPA04008842A/es active IP Right Grant
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140040036A (ko) * | 2012-09-24 | 2014-04-02 | 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 | ４치환된 레소르시놀 및 고 탄소 사슬 에스테르를 포함하는 저 오일 조성물 |
| KR20190099206A (ko) * | 2016-12-21 | 2019-08-26 | 유니레버 엔.브이. | 레조르시놀의 색 안정성을 개선하기 위한 킬레이팅제의 용도 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0307687A (pt) | 2005-01-11 |
| US20030180234A1 (en) | 2003-09-25 |
| WO2003080002A1 (en) | 2003-10-02 |
| AU2003218759A1 (en) | 2003-10-08 |
| CN1293857C (zh) | 2007-01-10 |
| US6863897B2 (en) | 2005-03-08 |
| JP2005527534A (ja) | 2005-09-15 |
| MXPA04008842A (es) | 2004-11-26 |
| CN1642512A (zh) | 2005-07-20 |
| BRPI0307687B1 (pt) | 2015-06-23 |
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