KR20030007683A - 안정화제 혼합물 - Google Patents
안정화제 혼합물 Download PDFInfo
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- KR20030007683A KR20030007683A KR1020027015838A KR20027015838A KR20030007683A KR 20030007683 A KR20030007683 A KR 20030007683A KR 1020027015838 A KR1020027015838 A KR 1020027015838A KR 20027015838 A KR20027015838 A KR 20027015838A KR 20030007683 A KR20030007683 A KR 20030007683A
- Authority
- KR
- South Korea
- Prior art keywords
- rtm
- tinuvin
- formula
- compound
- hydrogen
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 239000003381 stabilizer Substances 0.000 title claims abstract description 40
- 150000001875 compounds Chemical class 0.000 claims abstract description 336
- 239000001257 hydrogen Substances 0.000 claims abstract description 227
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 227
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 201
- -1 amine compounds Chemical class 0.000 claims abstract description 111
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 claims abstract description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 52
- 125000000217 alkyl group Chemical group 0.000 claims description 39
- 150000002431 hydrogen Chemical class 0.000 claims description 26
- 125000002947 alkylene group Chemical group 0.000 claims description 25
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 22
- 239000011368 organic material Substances 0.000 claims description 18
- 239000004743 Polypropylene Substances 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
- 125000002252 acyl group Chemical group 0.000 claims description 10
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 10
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 6
- 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims description 6
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- 230000015556 catabolic process Effects 0.000 claims description 5
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 claims description 5
- 238000006731 degradation reaction Methods 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims description 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims description 2
- XPHBRTNHVJSEQD-UHFFFAOYSA-N anidoxime Chemical compound C=1C=CC=CC=1C(CCN(CC)CC)=NOC(=O)NC1=CC=C(OC)C=C1 XPHBRTNHVJSEQD-UHFFFAOYSA-N 0.000 claims description 2
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 claims description 2
- 229920001059 synthetic polymer Polymers 0.000 claims description 2
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 349
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 68
- 239000004611 light stabiliser Substances 0.000 description 53
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 48
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 47
- FLPKSBDJMLUTEX-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)(CCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FLPKSBDJMLUTEX-UHFFFAOYSA-N 0.000 description 47
- CMXLJKWFEJEFJE-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound C1=CC(OC)=CC=C1C=C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(=O)OC1CC(C)(C)N(C)C(C)(C)C1 CMXLJKWFEJEFJE-UHFFFAOYSA-N 0.000 description 41
- OLBWDGJTEXRJLY-UHFFFAOYSA-N tetradecyl 3-(2,2,4,4-tetramethyl-21-oxo-7-oxa-3,20-diazadispiro[5.1.11^{8}.2^{6}]henicosan-20-yl)propanoate Chemical compound O1C2(CCCCCCCCCCC2)N(CCC(=O)OCCCCCCCCCCCCCC)C(=O)C21CC(C)(C)NC(C)(C)C2 OLBWDGJTEXRJLY-UHFFFAOYSA-N 0.000 description 36
- GUCMKIKYKIHUTM-UHFFFAOYSA-N 3,3,5,5-tetramethyl-1-[2-(3,3,5,5-tetramethyl-2-oxopiperazin-1-yl)ethyl]piperazin-2-one Chemical compound O=C1C(C)(C)NC(C)(C)CN1CCN1C(=O)C(C)(C)NC(C)(C)C1 GUCMKIKYKIHUTM-UHFFFAOYSA-N 0.000 description 34
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 34
- 229920001577 copolymer Polymers 0.000 description 34
- 150000003254 radicals Chemical class 0.000 description 28
- GMBXBKNMMIWUED-UHFFFAOYSA-N n-(2,2,6,6-tetramethylpiperidin-4-yl)-3-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]propanamide Chemical compound C1C(C)(C)NC(C)(C)CC1NCCC(=O)NC1CC(C)(C)NC(C)(C)C1 GMBXBKNMMIWUED-UHFFFAOYSA-N 0.000 description 27
- IVVLFHBYPHTMJU-UHFFFAOYSA-N 2,2,4,4-tetramethyl-7-oxa-3,20-diazadispiro[5.1.11^{8}.2^{6}]henicosan-21-one Chemical compound C1C(C)(C)NC(C)(C)CC21C(=O)NC1(CCCCCCCCCCC1)O2 IVVLFHBYPHTMJU-UHFFFAOYSA-N 0.000 description 24
- 229910052757 nitrogen Inorganic materials 0.000 description 22
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- 229920000642 polymer Polymers 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000004952 Polyamide Substances 0.000 description 12
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- 150000002148 esters Chemical class 0.000 description 12
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 9
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- 229920002857 polybutadiene Polymers 0.000 description 9
- 239000005062 Polybutadiene Substances 0.000 description 8
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 8
- 239000004702 low-density polyethylene Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 239000004417 polycarbonate Substances 0.000 description 8
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 7
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 229920006324 polyoxymethylene Polymers 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 4
- ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
- CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
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- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 3
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- 239000003446 ligand Substances 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
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- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
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- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/26—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
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- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
- C08K5/353—Five-membered rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
Description
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.075%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계사용된 광안정화제의 양은 각각 0.05%임* |
없음 | 185 | - |
TINUVIN 770(RTM) + TINUVIN 765(RTM) | 1780 | 3095 |
TINUVIN 770(RTM) + TINUVIN 144(RTM) | 1990 | 2815 |
TINUVIN 770(RTM) + TINUVIN 123(RTM) | 1780 | 2650 |
TINUVIN 770(RTM) + HOSTAVIN N 20(RTM) | 2760 | 3205 |
TINUVIN 770(RTM) + ADK STAB LA 57(RTM) | 2245 | 3045 |
TINUVIN 770(RTM) + GOODRITE UV 3034(RTM) | 2440 | 3570 |
TINUVIN 770(RTM) + GOODRITE UV 3150(RTM) | 2715 | 3230 |
TINUVIN 770(RTM) + 화합물(B-6-a-1) | 1930 | 3095 |
TINUVIN 770(RTM) + 화합물(B-6-a-2) | 2000 | 3400 |
TINUVIN 770(RTM) + 화합물(B-10-a-1) | 3510 | 3940 |
TINUVIN 770(RTM) + 화합물(B-1-a-1) | 1715 | 3520 |
TINUVIN 770(RTM) + SANDUVOR 3050(RTM) | 1630 | 3040 |
TINUVIN 770(RTM) + SANDUVOR PR-31(RTM) | 1885 | 2730 |
HOSTAVIN N 20(RTM) + ADK STAB LA 57(RTM) | 2485 | 2765 |
HOSTAVIN N 20(RTM) + 화합물(B-6-a-1) | 2625 | 3010 |
HOSTAVIN N 20(RTM) + UVINUL 4049 H(RTM) | 2655 | 3245 |
HOSTAVIN N 20(RTM) + 화합물(B-1-a-1) | 2510 | 3055 |
HOSTAVIN N 20(RTM) + SANDUVOR PR-31(RTM) | 2120 | 3140 |
ADK STAB LA 57(RTM) + TINUVIN 765(RTM) | 2290 | 2705 |
ADK STAB LA 57(RTM)+GOODRITE UV 3150(RTM) | 2305 | 2930 |
ADK STAB LA 57(RTM) + 화합물(B-6-a-2) | 2255 | 2745 |
ADK STAB LA 57(RTM) + UVINUL 4049 H(RTM) | 2400 | 2735 |
ADK STAB LA 57(RTM) + SANDUVOR PR-31(RTM) | 1670 | 2655 |
GOODRITE UV 3150(RTM) + 화합물(B-6-a-1) | 2390 | 3040 |
GOODRITE UV 3150(RTM) + 화합물(B-6-a-2) | 2155 | 2670 |
GOODRITE UV 3150(RTM)+SANDUVOR PR-31(RTM) | 2075 | 2840 |
화합물(B-6-a-1) + TINUVIN 765(RTM) | 2230 | 3010 |
화합물(B-6-a-1) + 화합물(B-6-a-2) | 2235 | 2980 |
화합물(B-6-a-1) + UVINUL 4049 H(RTM) | 2465 | 3235 |
화합물(B-6-a-1) + 화합물(B-1-a-1) | 2225 | 2775 |
화합물(B-10-a-1) + UVINUL 4049 H(RTM) | 3430 | 4055 |
화합물(B-10-a-1) + SANDUVOR PR-31(RTM) | 2710 | 3255 |
화합물(B-1-a-1) + TINUVIN 765(RTM) | 2365 | 3060 |
화합물(B-1-a-1) + UVINUL 4049 H(RTM) | 2475 | 3205 |
화합물(B-1-a-1) + SANDUVOR PR-31(RTM) | 1845 | 2550 |
화합물(B-1-a-1) + 화합물(B-6-a-2) | 2240 | 2650 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 광안정화제의 양은 각각 0.05%이고, TINUVIN 622(RTM)의 양은 0.10임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 광안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 광안정화제의 양은 각각 0.09%이고, TINUVIN 622(RTM)의 양은 0.02임* |
없음 | 300 | - | - | - |
TINUVIN 770(RTM) +TINUVIN 144(RTM) | 4635 | 7530 | 7585 | 6235 |
TINUVIN 770(RTM) +TINUVIN 123(RTM) | 4935 | 7940 | 7170 | 7130 |
TINUVIN 770(RTM) +HOSTAVIN N 24(RTM) | 5105 | 7455 | 7030 | 6890 |
TINUVIN 770(RTM) +ADK STAB LA 52(RTM) | 6710 | 6945 | 7865 | 8010 |
TINUVIN 770(RTM) +ADK STAB LA 57(RTM) | 5450 | 7225 | 7225 | 7280 |
TINUVIN 770(RTM) +ADK STAB LA 67(RTM) | 5915 | 6700 | 7190 | 7025 |
TINUVIN 770(RTM) +GOODRITE UV 3034(RTM) | 6925 | >8340 | >8340 | 7360 |
TINUVIN 770(RTM) +GOODRITE UV 3150(RTM) | 6325 | 7965 | 7625 | 7025 |
TINUVIN 770(RTM) +화합물(B-1-a-1) | 6040 | 7400 | 7540 | 7025 |
TINUVIN 770(RTM) +SANDUVOR 3050(RTM) | 5070 | 7005 | 6990 | 5735 |
TINUVIN 770(RTM) +SANDUVOR PR-31(RTM) | 5745 | 7470 | 6765 | 6705 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)혼합물(A-2)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, 혼합물(A-2)의 양은 0.05%임* |
없음 | 300 | - |
TINUVIN 770(RTM) +TINUVIN 144(RTM) | 4635 | 6025 |
TINUVIN 770(RTM) +TINUVIN 123(RTM) | 4935 | 6080 |
TINUVIN 770(RTM) +HOSTAVIN N 24(RTM) | 5105 | 6005 |
TINUVIN 770(RTM) +ADK STAB LA 57(RTM) | 5450 | 6800 |
TINUVIN 770(RTM) +GOODRITE UV 3034(RTM) | 6925 | 7735 |
TINUVIN 770(RTM) +화합물(B-6-a-2) | 6530 | 7335 |
TINUVIN 770(RTM) +화합물(B-1-a-1) | 6040 | 6905 |
TINUVIN 770(RTM) +SANDUVOR 3050(RTM) | 5070 | >6495 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 315 | - |
TINUVIN 770(RTM) +TINUVIN 765(RTM) | 4815 | >7260 |
TINUVIN 770(RTM) +TINUVIN 144(RTM) | 5695 | 7145 |
TINUVIN 770(RTM) +TINUVIN 123(RTM) | 4670 | 7080 |
TINUVIN 770(RTM) +HOSTAVIN N 24(RTM) | 5390 | 6710 |
TINUVIN 770(RTM) +ADK STAB LA 52(RTM) | 6655 | >7260 |
TINUVIN 770(RTM) +ADK STAB LA 62(RTM) | 5040 | 6760 |
TINUVIN 770(RTM) +ADK STAB LA 67(RTM) | 5010 | 6205 |
TINUVIN 770(RTM) +화합물(B-10-a-1) | 5825 | >7260 |
TINUVIN 770(RTM) +화합물(B-1-a-1) | 6125 | 7215 |
TINUVIN 770(RTM) +SANDUVOR 3050(RTM) | 5690 | >7260 |
TINUVIN 770(RTM) +SANDUVOR PR-31(RTM) | 5100 | 6475 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 315 | - |
TINUVIN 765(RTM) +TINUVIN 144(RTM) | 4930 | 7180 |
TINUVIN 765(RTM) +TINUVIN 123(RTM) | 4640 | >7260 |
TINUVIN 765(RTM) +HOSTAVIN N 20(RTM) | 6580 | >7260 |
TINUVIN 765(RTM) +HOSTAVIN N 24(RTM) | 5325 | 7040 |
TINUVIN 765(RTM) +ADK STAB LA 52(RTM) | 5605 | >7260 |
TINUVIN 765(RTM) +ADK STAB LA 57(RTM) | 5360 | 6905 |
TINUVIN 765(RTM) +ADK STAB LA 62(RTM) | 4620 | >7260 |
TINUVIN 765(RTM) +ADK STAB LA 67(RTM) | 4840 | 6625 |
TINUVIN 765(RTM) +GOODRITE UV 3034(RTM) | 6550 | >7260 |
TINUVIN 765(RTM) +GOODRITE UV 3150(RTM) | 5715 | >7260 |
TINUVIN 765(RTM) +화합물(B-6-a-1) | 5105 | >7260 |
TINUVIN 765(RTM) +화합물(B-1-a-1) | 6145 | >7260 |
TINUVIN 765(RTM) +SANDUVOR 3050(RTM) | 5425 | >7260 |
TINUVIN 765(RTM) +SANDUVOR PR-31(RTM) | 4920 | 6675 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 330 | - |
TINUVIN 144(RTM) +TINUVIN 123(RTM) | 3185 | 5765 |
TINUVIN 144(RTM) +HOSTAVIN N 20(RTM) | 4295 | 6150 |
TINUVIN 144(RTM) +HOSTAVIN N 24(RTM) | 3725 | 5720 |
TINUVIN 144(RTM) +ADK STAB LA 52(RTM) | 4195 | 5635 |
TINUVIN 144(RTM) +ADK STAB LA 57(RTM) | 4870 | 6350 |
TINUVIN 144(RTM) +ADK STAB LA 62(RTM) | 2815 | 5695 |
TINUVIN 144(RTM) +ADK STAB LA 67(RTM) | 3910 | 4940 |
TINUVIN 144(RTM) +GOODRITE UV 3034(RTM) | 4185 | 6115 |
TINUVIN 144(RTM) +GOODRITE UV 3150(RTM) | 4290 | 5725 |
TINUVIN 144(RTM) +화합물(B-6-a-1) | 5515 | 6565 |
TINUVIN 144(RTM) +화합물(B-6-a-2) | 5100 | 6810 |
TINUVIN 144(RTM) +화합물(B-10-a-1) | 5380 | 6585 |
TINUVIN 144(RTM) +화합물(B-1-a-1) | 5470 | 6305 |
TINUVIN 144(RTM) +SANDUVOR 3050(RTM) | 4030 | 5200 |
TINUVIN 144(RTM) +SANDUVOR PR-31(RTM) | 3105 | 5890 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 330 | - |
TINUVIN 123(RTM) +HOSTAVIN N 20(RTM) | 4455 | 5715 |
TINUVIN 123(RTM) +HOSTAVIN N 24(RTM) | 3490 | 5265 |
TINUVIN 123(RTM) +ADK STAB LA 52(RTM) | 4620 | 5610 |
TINUVIN 123(RTM) +ADK STAB LA 57(RTM) | 4275 | 5670 |
TINUVIN 123(RTM) +ADK STAB LA 62(RTM) | 3380 | 5185 |
TINUVIN 123(RTM) +ADK STAB LA 67(RTM) | 3470 | 5355 |
TINUVIN 123(RTM) +GOODRITE UV 3034(RTM) | 4520 | >6280 |
TINUVIN 123(RTM) +GOODRITE UV 3150(RTM) | 4260 | 5635 |
TINUVIN 123(RTM) +화합물(B-6-a-1) | 4760 | 6145 |
TINUVIN 123(RTM) +화합물(B-6-a-2) | 5115 | 6365 |
TINUVIN 123(RTM) +화합물(B-10-a-1) | 5785 | 6700 |
TINUVIN 123(RTM) +화합물(B-1-a-1) | 4345 | 6115 |
TINUVIN 123(RTM) +SANDUVOR 3050(RTM) | 3650 | 5040 |
TINUVIN 123(RTM) +SANDUVOR PR-31(RTM) | 3655 | 5390 |
TINUVIN 123(RTM) +화합물(B-7-1) | 4305 | 5205 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 325 | - |
HOSTAVIN N 20(RTM) +HOSTAVIN N 24(RTM) | 3695 | 4565 |
HOSTAVIN N 20(RTM) +ADK STAB LA 52(RTM) | 4375 | 5525 |
HOSTAVIN N 20(RTM) +ADK STAB LA 57(RTM) | 4485 | 5535 |
HOSTAVIN N 20(RTM) +ADK STAB LA 62(RTM) | 3810 | 5315 |
HOSTAVIN N 20(RTM) +ADK STAB LA 67(RTM) | 3655 | 5045 |
HOSTAVIN N 20(RTM) +GOODRITE UV 3034(RTM) | 5005 | 5610 |
HOSTAVIN N 20(RTM) +GOODRITE UV 3150(RTM) | 3950 | 5050 |
HOSTAVIN N 20(RTM) +화합물(B-6-a-1) | 5025 | >5890 |
HOSTAVIN N 20(RTM) +화합물(B-6-a-2) | 5465 | >5890 |
HOSTAVIN N 20(RTM) +화합물(B-10-a-1) | 5405 | >5890 |
HOSTAVIN N 20(RTM) +화합물(B-1-a-1) | 5410 | >5890 |
HOSTAVIN N 20(RTM) +SANDUVOR 3050(RTM) | 3985 | 5090 |
HOSTAVIN N 20(RTM) +SANDUVOR PR-31(RTM) | 4085 | 5255 |
HOSTAVIN N 20(RTM) +화합물(B-7-1) | 4200 | 5220 |
광 안정화제 계 | T0.1(시간)사용된 광안정화제의 양은 각각 0.1%임* | T0.1(시간)TINUVIN 622(RTM)와 조합된 광안정화제 계광안정화제 계중 안정화제의 양은 각각 0.075%이고, TINUVIN 622(RTM)의 양은 0.05%임* |
없음 | 325 | - |
ADK STAB LA 57(RTM) +HOSTAVIN N 24(RTM) | 4035 | 5020 |
ADK STAB LA 57(RTM) +ADK STAB LA 52(RTM) | 3855 | 4985 |
ADK STAB LA 57(RTM) +GOODRITE UV 3150(RTM) | 4320 | 4890 |
ADK STAB LA 57(RTM) +SANDUVOR PR-31(RTM) | 3970 | 4430 |
ADK STAB LA 57(RTM) +화합물(B-7-1) | 3765 | 4475 |
Claims (17)
- 성분(A) 및 (B)을 함유하는 안정화제 혼합물로서, 성분(A)은 하기 일반식(A-1)의 화합물, 하기 일반식(A-2-a) 및 (A-2-b)중 적어도 한 화합물, 하기 일반식(A-3)의 화합물 또는 하기 일반식(A-4)의 화합물이며; 그리고 성분(B)은 하기 일반식(I) 또는 (II)의 기를 함유하는 2개의 서로 다른 저분자량 입체장애 아민 화합물에 의해 형성되는 안정화제 혼합물:상기 식중에서,A1는 수소 또는 C1-C4알킬이고,A2는 직접 결합 또는 C1-C10알킬렌이고,n1, n2, n2* 및 n4는 2∼50의 수이고,A3및 A4는 서로 독립적으로 수소 또는 C1-C8알킬이거나, 또는 A3및 A4는 함께 C2-C14알킬렌기를 형성하고,n3은 서로 독립적으로 1∼50의 수이고,A5는 수소 또는 C1-C4알킬이고,A6및 A7은 서로 독립적으로 C1-C4알킬이거나 또는 하기 일반식(a-I)의 기이고:(a-I)A8은 수소, C1-C8알킬, O., -OH, -CH2CN, C1-C18알콕시, C5-C12시클로알콕시, C3-C6알케닐, 1, 2 또는 3의 C1-C4알킬에 의해 페닐에 치환되거나 치환되지 않은 C7-C9페닐알킬, 또는 C1-C8아실이고,단, 라디칼 A7의 적어도 50%는 일반식(a-I)의 기이고, 그리고 성분(A) 및 (B)는 서로 다르다.
- 제1항에 있어서, 성분(B)의 서로 다른 2개의 화합물이 하기 일반식(B-1) 내지 (B-11)의 화합물로 이루어진 군으로부터 선택되는 것을 특징으로 하는 안정화제 혼합물:(B-1)상기 식에서,E1은 수소, C1-C8알킬, O., -OH, -CH2CN, C1-C18알콕시, C5-C12시클로알콕시, C3-C6알케닐, 1, 2 또는 3의 C1-C4알킬에 의해 페닐에 치환되거나 치환되지 않은 C7-C9페닐알킬, 또는 C1-C8아실이고,m1은 1, 2 또는 4이고,m1이 1인 경우, E2는 C1-C25알킬이고,m1이 2인 경우, E2는 C1-C14알킬렌 또는 하기 일반식(b-I)의 기이고:(b-I)상기 식에서,E3은 C1-C10알킬 또는 C2-C10알케닐이고,E4는 C1-C10알킬렌이고,E5및 E6은 서로 독립적으로 C1-C4알킬, 시클로헥실 또는 메틸시클로헥실이고,m1이 4인 경우,E2는 C4-C10알칸테트라일이고;(B-2)상기 식에서,라디칼 E7들중 2개는 -COO-(C1-C20알킬)이고, 그리고라디칼 E7들중 2개는 하기 일반식(b-II)의 기이고;(b-II)상기 식에서, E8은 E1의 정의중 하나이고;(B-3)상기 식에서,E9및 E10는 함께 C2-C14알킬렌을 형성하고,E11은 수소 또는 -Z1-COO-Z2이고,Z1은 C2-C14알킬렌이고,Z2는 C1-C24알킬이고,E12는 E1의 정의중 하나이고;(B-4)상기 식에서,라디칼 E13은 서로 독립적으로 E1의 정의중 하나이고,라디칼 E14는 서로 독립적으로 수소 또는 C1-C12알킬이고, 그리고E15는 C1-C10알킬렌 또는 C3-C10알킬리덴이고;(B-5)상기 식에서,라디칼 E16은 서로 독립적으로 E1의 정의중 하나이고;(B-6)상기 식에서,E17은 C1-C24알킬이고, 그리고E18은 E1의 정의중 하나이고;(B-7)상기 식에서,E19, E20및 E21은 서로 독립적으로 하기 일반식(b-III)의 기이고:(b-III)E22는 E1의 정의중 하나이고;(B-8)상기 식에서,라디칼 E23은 서로 독립적으로 E1의 정의중 하나이고,E24는 수소, C1-C12알킬 또는 C1-C12알콕시이고;(B-9)상기 식에서,m2는 1, 2 또는 3이고,E25는 E1의 정의중 하나이고,m2가 1인 경우, E26은기이고,m2가 2인 경우, E26은 C2-C22알킬렌이고,m2가 3인 경우, E26은 하기 일반식(b-IV)의 기이고:(b-IV)상기 식에서,라디칼 E27은 서로 독립적으로 C2-C12알킬렌이고, 그리고라디칼 E28은 서로 독립적으로 C1-C12알킬 또는 C5-C12시클로알킬이고;(B-10)상기 식에서,라디칼 E29는 서로 독립적으로 E1의 정의중 하나이고, 그리고E30은 C2-C22알킬렌, C5-C7시클로알킬렌, C1-C4알킬렌디(C5-C7시클로알킬렌), 페닐렌 또는 페닐렌디(C1-C4알킬렌)이고; 또는(B-11)상기 식에서,E31은 C1-C10알킬, C5-C12시클로알킬, C1-C4알킬-치환 C5-C12시클로알킬, 페닐 또는 C1-C10알킬-치환 페닐이고,E32은 C3-C10알킬렌이고,E33는 E1의 정의중 하나이고, 그리고m3는 2∼6의 수이다.
- 제1항에 있어서, 하기와 같이 정의되는 안정화제 혼합물:A1은 수소 또는 메틸이고,A2는 직접 결합 또는 C2-C6알킬렌이고,n1, n2, n2* 및 n4는 각각 2∼25이고,A3및 A4는 서로 독립적으로 수소 또는 C1-C4알킬이고, 또는 A3및 A4는 함께 C9-C13알킬렌기를 형성하고,n3은 서로 독립적으로 1∼25이고,A5및 A6은 서로 독립적으로 C1-C4알킬이고, 그리고A7은 C1-C4알킬 또는 일반식(a-I)의 기이고,단, 라디칼A7의 적어도 50%는 일반식(a-I)의 기이다.
- 제2항에 있어서, 하기와 같이 정의되는 안정화제 혼합물:m1은 1, 2 또는 4이고,m1이 1이면, E2는 C12-C20알킬이고,m1이 2이면, E2는 C2-C10알킬렌 또는 일반식(b-1)의 기이고,E3은 C1-C4알킬이고,E4는 C1-C6알킬렌이고,E5및 E6은 서로 독립적으로 C1-C4알킬이고,m1이 4이면, E2는 C4-C8알칸테트라일이고,라디칼E7중 2개는 -COO-(C10-C15알킬)이고,라디칼E7중 2개는 일반식(b-II)의 기이고,E9및 E10은 함께 C9-C13알킬렌을 형성하고,E11은 수소 또는 -Z1-COO-Z2이고,Z1은 C2-C6알킬렌이고,Z2는 C10-C16알킬이고,E14는 수소이고,E15는 C2-C6알킬렌 또는 C3-C5알킬리덴이고,E17은 C10-C14알킬이고;E24는 C1-C4알콕시이고;m2는 1, 2 또는 3이고,m2가 1이면, E26은이고,m2가 2이면, E26은 C2-C6알킬렌이고,m2가 3이면, E26은 일반식(b-IV)의 기이고,라디칼E27은 서로 독립적으로 C2-C6알킬렌이고,라디칼E28은 서로 독립적으로 C1-C4알킬 또는 C5-C8시클로알킬이고,E30은 C2-C8알킬렌이고,E31은 C1-C4알킬이고,E32은 C3-C6알킬렌이고, 그리고m3는 2∼6이다.
- 제1항에 있어서, 성분(A)이 하기 일반식(A-1-a), (A-2-a), (A-2-b), (A-3-a) 또는 (A-4-a)이고; 그리고 성분(B)이 하기 일반식(B-1-a), (B-1-b), (B-1-c), (B-1-d), (B-2-a), (B-3-a), (B-3-b), (B-4-a), (B-4-b), (B-5), (B-6-a), (B-7), (B-8-a), (B-9-a), (B-9-b), (B-9-c), (B-10-a) 및 (B-11-a)로 이루어진 군으로부터 선택된 2개의 서로 다른 화합물에 의해 형성되는 것을 특징으로 하는 안정화제 혼합물:(A-1-a)(A-2-a)(A-2-b)(A-4-a)상기 식에서,n1, n2, n2* 및 n4는 2∼20의 수이고,n3은 서로 독립적으로 1∼20의 수이고,라디칼 A7중 적어도 50%는 하기 일반식(a-I)의 기이고:(a-I)상기 식에서,A8은 수소, C1-C8알킬, O., -OH, -CH2CN, C1-C18알콕시, C5-C12시클로알콕시, C3-C6알케닐, 1, 2 또는 3의 C1-C4알킬에 의해 페닐에 치환되거나 치환되지 않은 C7-C9페닐알킬, 또는 C1-C8아실이고, 그리고 나머지 라디칼 A7은 에틸이고; 그리고(B-2-a)(B-3-a)(B-3-b)(B-4-a)(B-4-b)(B-5)(B-6-a)(B-7)(B-8-a)(B-9-a)(B-9-b)(B-9-c)(B-10-a)(B-11-a)상기 식에서,E1은 수소, C1-C8알킬, O., -OH, -CH2CN, C1-C18알콕시, C5-C12시클로알콕시, C3-C6알케닐, 1, 2 또는 3의 C1-C4알킬에 의해 페닐에 치환되거나 치환되지 않은 C7-C9페닐알킬, 또는 C1-C8아실이고,라디칼 E7중 2개는 -COO-C13H27이고,라디칼 E7중 나머지 2개는이고,E8, E12, E13, E16, E18, E22, E23, E25, E29및 E33는 E1의 정의중 하나이고,E19, E20및 E21은 서로 독립적으로 하기 일반식(b-III)의 기이고:(b-III);m3는 2∼6의 수이다.
- 제1항에 있어서, A8이 수소, C1-C4알킬, C1-C10알콕시, 시클로헥실옥시, 알릴, 벤질 또는 아세틸인 것을 특징으로 하는 안정화제 혼합물.
- 제2항에 있어서, E1, E8, E12, E13, E16, E18, E22, E23, E25, E29및 E33가 수소, C1-C4알킬, C1-C10알콕시, 시클로헥실옥시, 알릴, 벤질 또는 아세틸인 것을 특징으로 하는 안정화제 혼합물.
- 제5항에 있어서, A8, E1, E8, E12, E13, E16, E18, E22, E23, E25, E29및 E33이 수소 또는 메틸이고, 그리고 E1은 추가적으로 C1-C8알콕시인 것을 특징으로 하는 안정화제 혼합물.
- 제5항에 있어서, 성분(B)을 형성하는 서로 다른 두 화합물중 하나는 E1이 수소인 일반식(B-1-b)의 화합물인 것을 특징으로 하는 안정화제 혼합물.
- 제5항에 있어서,성분(A)는, n1이 2∼20인 일반식(A-1-a)의 화합물 또는 n2및 n2 *가 2∼20인 일반식(A-2-a) 또는 (A-2-b)의 화합물이고; 그리고성분(B)을 형성하는 서로 다른 두 화합물중 하나는 E1이 수소인 일반식(B-1-b)의 화합물인 것을 특징으로 하는 안정화제 혼합물.
- 제5항에 있어서,성분(A)는, n1이 2∼20인 일반식(A-1-a)의 화합물 또는 n2및 n2 *가 2∼20인 일반식(A-2-a) 또는 (A-2-b)의 화합물이고,성분(B)을 형성하는 서로 다른 두 화합물중 하나는 E1이 수소인 일반식(B-1-b)의 화합물이고,성분(B)을 형성하는 서로 다른 두 화합물중 또 다른 하나는 E1이 수소인 일반식(B-1-a), E1이 메틸인 일반식(B-1-b), E1이 수소 또는 메틸인 일반식(B-1-d), E12가 수소인 일반식(B-3-a), E12가 수소인 일반식(B-3-b), E13이 수소인 일반식(B-4-b), E16이 수소인 일반식(B-5), E18이 수소 또는 메틸인 일반식(B-6-a), E23이 메틸인 일반식(B-8-a), E25가 수소 또는 메틸인 일반식(B-9-c), E29가 수소인 일반식(B-10-a), 또는 E33이 수소인 일반식(B-11-a)의 화합물인 것을 특징으로 하는 안정화제 혼합물.
- 제5항에 있어서,성분(A)은 n1이 2∼20인 일반식(A-1-a)의 화합물이고,성분(B)은 E1이 수소인 일반식(B-1-b)의 화합물이고, 그리고성분(C)은 E1이 옥틸옥시인 일반식(B-1-b)의 화합물이거나; 또는성분(A)은 n1이 2∼20인 일반식(A-1-a)의 화합물이고,성분(B)은 E1이 수소인 일반식(B-1-b)의 화합물이고, 그리고성분(C)은 E12이 수소인 일반식(B-3-a)의 화합물이거나; 또는성분(A)은 n1이 2∼20인 일반식(A-1-a)의 화합물이고,성분(B)은 E1이 수소인 일반식(B-1-b)의 화합물이고, 그리고성분(C)은 E1이 수소인 일반식(B-1-d)의 화합물이거나; 또는성분(A)은 n1이 2∼20인 일반식(A-1-a)의 화합물이고,성분(B)은 E1이 수소인 일반식(B-1-b)의 화합물이고, 그리고성분(C)은 E1이 수소인 일반식(B-1-a)의 화합물이거나; 또는성분(A)은 n1이 2∼20인 일반식(A-1-a)의 화합물이고,성분(B)은 E1이 메틸인 일반식(B-1-b)의 화합물이고, 그리고성분(C)은 E1이 메틸인 일반식(B-1-d)의 화합물인 것을 특징으로 하는 안정화제 혼합물.
- 광, 열 또는 산화에 의해 열화되기 쉬운 유기 물질과 제1항에 따른 안정화제 혼합물을 포함하는 조성물.
- 제13항에 있어서, 유기 물질이 합성 중합체인 것을 특징으로 하는 조성물.
- 제13항에 있어서, 유기 물질이 폴리올레핀인 것을 특징으로 하는 조성물.
- 제13항에 있어서, 유기 물질이 폴리에틸렌, 폴리프로필렌, 폴리에틸렌 공중합체 또는 폴리프로필렌 공중합체인 것을 특징으로 하는 조성물.
- 유기 물질에 제1항에 따른 안정화제 혼합물을 혼입하는 것을 포함하는, 광, 열 또는 산화에 의해 열화되기 쉬운 유기 물질을 안정화시키는 방법.
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2001
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- 2001-05-22 WO PCT/EP2001/005865 patent/WO2001092398A2/en active Application Filing
- 2001-05-22 AU AU6601001A patent/AU6601001A/xx active Pending
- 2001-05-22 CA CA002408093A patent/CA2408093A1/en not_active Abandoned
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- 2001-05-22 CN CNB018103138A patent/CN1235958C/zh not_active Expired - Lifetime
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- 2001-05-29 IT IT2001MI001135 patent/IT1324894B/it active
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