KR102666434B1 - 미가공 탄소 나노튜브의 정제 방법 - Google Patents
미가공 탄소 나노튜브의 정제 방법 Download PDFInfo
- Publication number
- KR102666434B1 KR102666434B1 KR1020197031989A KR20197031989A KR102666434B1 KR 102666434 B1 KR102666434 B1 KR 102666434B1 KR 1020197031989 A KR1020197031989 A KR 1020197031989A KR 20197031989 A KR20197031989 A KR 20197031989A KR 102666434 B1 KR102666434 B1 KR 102666434B1
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- KR
- South Korea
- Prior art keywords
- carbon nanotubes
- raw
- cnts
- purified
- raw carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/17—Purification
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/22—Electronic properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/26—Mechanical properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/30—Purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/32—Specific surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762479688P | 2017-03-31 | 2017-03-31 | |
| FR1752749A FR3064623B1 (fr) | 2017-03-31 | 2017-03-31 | Processus de purification de nanotubes de carbone bruts |
| US62/479,688 | 2017-03-31 | ||
| FR17/52749 | 2017-03-31 | ||
| PCT/IB2018/052192 WO2018178929A2 (fr) | 2017-03-31 | 2018-03-29 | Procédé de purification de nanotubes de carbone bruts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20190135032A KR20190135032A (ko) | 2019-12-05 |
| KR102666434B1 true KR102666434B1 (ko) | 2024-05-17 |
Family
ID=59031154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197031989A Active KR102666434B1 (ko) | 2017-03-31 | 2018-03-29 | 미가공 탄소 나노튜브의 정제 방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US11661344B2 (https=) |
| EP (1) | EP3601161A2 (https=) |
| JP (2) | JP7171608B2 (https=) |
| KR (1) | KR102666434B1 (https=) |
| CN (1) | CN110662715B (https=) |
| CA (1) | CA3057746C (https=) |
| FR (1) | FR3064623B1 (https=) |
| WO (1) | WO2018178929A2 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3078201B1 (fr) | 2018-02-19 | 2023-01-13 | Arkema France | Formulation de matiere active pour accumulateur li-s et procede de preparation |
| FR3091041A1 (fr) | 2018-12-20 | 2020-06-26 | Arkema France | Composition conductrice electronique pour batterie au lithium tout solide |
| CN109502572A (zh) * | 2018-12-29 | 2019-03-22 | 苏州第元素纳米技术有限公司 | 碳纳米管提纯方法 |
| FR3094710A1 (fr) | 2019-04-05 | 2020-10-09 | Arkema France | Procédé de préparation d’une composition pâteuse comprenant des nanotubes de carbone |
| CN111249765B (zh) * | 2020-02-25 | 2021-04-06 | 中国科学院化学研究所 | 一种去除碳材料中金属离子的加压流体提取系统和方法 |
| CN113443617B (zh) * | 2021-08-19 | 2022-11-04 | 陕西六元碳晶股份有限公司 | 一种连续式碳纳米管的纯化装置及工艺 |
| CN114014300A (zh) * | 2021-11-24 | 2022-02-08 | 深圳市飞墨科技有限公司 | 碳纳米管及其纯化方法 |
| CN115215327B (zh) * | 2022-02-23 | 2023-10-03 | 无锡东恒新能源科技有限公司 | 一种用于碳纳米管提纯的装置及方法 |
| CN114590796A (zh) * | 2022-02-28 | 2022-06-07 | 诺瑞(深圳)新技术有限公司 | 碳纳米管的纯化方法和碳纳米管浆料的制备方法 |
| US20230391623A1 (en) | 2022-06-06 | 2023-12-07 | Indian Oil Corporation Limited | Regeant solution for purification of carbon nanomaterials and a method thereof |
| CN116022775B (zh) * | 2022-12-29 | 2024-02-09 | 蜂巢能源科技(上饶)有限公司 | 一种碳纳米管提纯方法及应用 |
| CN116553531B (zh) * | 2023-03-28 | 2025-12-02 | 东莞瑞泰新材料科技有限公司 | 一种纯化碳纳米管的方法 |
| CN116462188B (zh) * | 2023-05-11 | 2024-07-23 | 清华大学 | 提高碳纳米管纯度的方法及碳纳米管和用途 |
| JP7623560B2 (ja) * | 2023-05-19 | 2025-01-29 | 中谷産業株式会社 | カーボンナノチューブ凝集体及びその製造方法 |
| CN121487894A (zh) * | 2023-07-07 | 2026-02-06 | 住友化学株式会社 | 多壁碳纳米管集合体、多壁碳纳米管分散液、导电材料、电极、二次电池、平面状集合体、过滤器、电磁屏蔽体及极紫外用保护膜 |
| KR102796263B1 (ko) * | 2023-12-05 | 2025-04-16 | 주식회사 나노솔루션 | 탄소나노튜브의 정제방법 |
| WO2025135042A1 (ja) * | 2023-12-22 | 2025-06-26 | 住友化学株式会社 | 炭素および水素の製造方法、及び、炭素繊維 |
| CN119240675A (zh) * | 2024-08-27 | 2025-01-03 | 甬江实验室 | 碳纳米管的纯化方法 |
| WO2026079346A1 (ja) * | 2024-10-08 | 2026-04-16 | 日本ゼオン株式会社 | 繊維状構造体の製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006225245A (ja) * | 2005-02-21 | 2006-08-31 | Mitsubishi Heavy Ind Ltd | ナノカーボン材料 |
| WO2008126534A1 (ja) | 2007-03-13 | 2008-10-23 | Toyo Tanso Co., Ltd. | カーボンナノチューブを含んだ炭素材料の精製方法及びこの精製方法により得られた炭素材料、並びにこの炭素材料を用いた樹脂成形体、繊維、ヒートシンク、摺動材、電界電子放出源材料、電極の導電助剤、触媒担持材及び導電性フィルム |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7090819B2 (en) * | 2001-02-12 | 2006-08-15 | William Marsh Rice University | Gas-phase process for purifying single-wall carbon nanotubes and compositions thereof |
| US7858185B2 (en) * | 2003-09-08 | 2010-12-28 | Nantero, Inc. | High purity nanotube fabrics and films |
| FR2881735B1 (fr) | 2005-02-07 | 2008-04-18 | Arkema Sa | Procede de synthese de nanotubes de carbone |
| JP2006225244A (ja) | 2005-02-21 | 2006-08-31 | Mitsubishi Heavy Ind Ltd | ナノカーボン材料 |
| CN101631744A (zh) * | 2007-03-13 | 2010-01-20 | 东洋炭素株式会社 | 含有碳纳米管的碳材料的精制方法及由该精制方法得到的碳材料、以及使用该碳材料的树脂成型体、纤维、散热器、滑动材料、电场电子释放源材料、电极的导电助剂、担载有催化剂的材料及导电性膜 |
| FR2914634B1 (fr) | 2007-04-06 | 2011-08-05 | Arkema France | Procede de fabrication de nanotubes de carbone a partir de matieres premieres renouvelables |
| CN101873993A (zh) | 2007-07-11 | 2010-10-27 | 御国色素株式会社 | 碳纳米管的造粒产物及其制造方法 |
| DE102007044031A1 (de) * | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung |
| FR2927062B1 (fr) | 2008-02-04 | 2011-07-01 | Arkema France | Procede de remplissage securise de nanotubes de carbone, systeme de remplissage et installation industrielle mettant en oeuvre le procede. |
| DE102009038464A1 (de) * | 2009-08-21 | 2011-02-24 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchen-Agglomerat |
| JP5599204B2 (ja) * | 2010-03-12 | 2014-10-01 | 東洋炭素株式会社 | カーボンナノチューブ集合体及びその製造方法 |
| FR2966815B1 (fr) * | 2010-10-28 | 2013-05-31 | Centre Nat Rech Scient | Methode de purification de nanotubes de carbone |
| US10294133B2 (en) * | 2011-03-18 | 2019-05-21 | Css Nanotech, Inc. | Methods of synthesizing three-dimensional heteroatom-doped carbon nanotube macro materials and compositions thereof |
| KR101408950B1 (ko) * | 2012-10-18 | 2014-06-17 | 주식회사 효성 | 압축 cnt의 제조방법 및 그에 의한 압축 cnt |
| DE102013213273A1 (de) * | 2013-02-22 | 2014-08-28 | Bayer Materialscience Aktiengesellschaft | Kohlenstoffnanoröhren-haltige Dispersion und ihre Verwendung in der Herstellung von Elektroden |
| KR20140004985U (ko) | 2013-03-07 | 2014-09-17 | 이성균 | 수륙양용자전거 |
| DE102013214229A1 (de) * | 2013-07-19 | 2015-01-22 | Bayer Materialscience Ag | Verfahren zur Herstellung eines effizienten Katalysators für die Produktion mehrwandiger Kohlenstoffnanoröhrchen, mehrwandiges Kohlenstoffnanoröhrchen und Kohlenstoffnanoröhrchenpulver |
| CN105271164B (zh) * | 2014-07-17 | 2019-08-20 | 山东大展纳米材料有限公司 | 一种连续化制备碳纳米管的装置及方法 |
| CN104900871A (zh) | 2015-04-14 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | 一种LiFePO4正极材料的制备方法、锂离子电池及其制备方法 |
| KR20170011779A (ko) * | 2015-07-24 | 2017-02-02 | 주식회사 엘지화학 | 열안정성이 개선된 카본나노튜브 |
| KR102002048B1 (ko) * | 2015-09-03 | 2019-07-19 | 주식회사 엘지화학 | 카본나노튜브의 정제방법 |
| KR20170032566A (ko) * | 2015-09-15 | 2017-03-23 | 주식회사 엘지화학 | 결정성이 개선된 카본나노튜브 |
| WO2020064868A1 (en) | 2018-09-25 | 2020-04-02 | Agc Glass Europe | Vehicle control device and manufacturing method thereof |
-
2017
- 2017-03-31 FR FR1752749A patent/FR3064623B1/fr active Active
-
2018
- 2018-03-29 WO PCT/IB2018/052192 patent/WO2018178929A2/fr not_active Ceased
- 2018-03-29 JP JP2019553296A patent/JP7171608B2/ja active Active
- 2018-03-29 CA CA3057746A patent/CA3057746C/fr active Active
- 2018-03-29 CN CN201880034976.7A patent/CN110662715B/zh active Active
- 2018-03-29 EP EP18721140.4A patent/EP3601161A2/fr active Pending
- 2018-03-29 KR KR1020197031989A patent/KR102666434B1/ko active Active
- 2018-03-29 US US16/498,537 patent/US11661344B2/en active Active
-
2022
- 2022-11-02 JP JP2022176379A patent/JP7429760B2/ja active Active
-
2023
- 2023-04-10 US US18/298,075 patent/US20230339758A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006225245A (ja) * | 2005-02-21 | 2006-08-31 | Mitsubishi Heavy Ind Ltd | ナノカーボン材料 |
| WO2008126534A1 (ja) | 2007-03-13 | 2008-10-23 | Toyo Tanso Co., Ltd. | カーボンナノチューブを含んだ炭素材料の精製方法及びこの精製方法により得られた炭素材料、並びにこの炭素材料を用いた樹脂成形体、繊維、ヒートシンク、摺動材、電界電子放出源材料、電極の導電助剤、触媒担持材及び導電性フィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| CA3057746C (fr) | 2025-05-20 |
| CN110662715B (zh) | 2023-10-27 |
| US11661344B2 (en) | 2023-05-30 |
| EP3601161A2 (fr) | 2020-02-05 |
| US20230339758A1 (en) | 2023-10-26 |
| JP7429760B2 (ja) | 2024-02-08 |
| US20210107791A1 (en) | 2021-04-15 |
| KR20190135032A (ko) | 2019-12-05 |
| JP2023009119A (ja) | 2023-01-19 |
| FR3064623B1 (fr) | 2025-06-20 |
| WO2018178929A2 (fr) | 2018-10-04 |
| JP2020515497A (ja) | 2020-05-28 |
| CN110662715A (zh) | 2020-01-07 |
| JP7171608B2 (ja) | 2022-11-15 |
| FR3064623A1 (fr) | 2018-10-05 |
| CA3057746A1 (fr) | 2018-10-04 |
| WO2018178929A3 (fr) | 2018-12-20 |
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