KR102507703B1 - 하이드로포르밀화 공정 - Google Patents

하이드로포르밀화 공정 Download PDF

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KR102507703B1
KR102507703B1 KR1020177016356A KR20177016356A KR102507703B1 KR 102507703 B1 KR102507703 B1 KR 102507703B1 KR 1020177016356 A KR1020177016356 A KR 1020177016356A KR 20177016356 A KR20177016356 A KR 20177016356A KR 102507703 B1 KR102507703 B1 KR 102507703B1
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vaporizer
stream
catalyst
kpa
rhodium
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KR20170093152A (ko
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마이클 에이. 브래머
조지 알. 필립스
토마스 씨. 아이젠슈미드
얼빈 비. 콕스
로버트 해터리
미카엘 존 베인브리지
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다우 테크놀로지 인베스트먼츠 엘엘씨.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020177016356A 2014-12-04 2015-11-18 하이드로포르밀화 공정 Active KR102507703B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462087572P 2014-12-04 2014-12-04
US62/087,572 2014-12-04
PCT/US2015/061332 WO2016089602A1 (en) 2014-12-04 2015-11-18 Hydroformylation process

Publications (2)

Publication Number Publication Date
KR20170093152A KR20170093152A (ko) 2017-08-14
KR102507703B1 true KR102507703B1 (ko) 2023-03-09

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US (1) US10023516B2 (https=)
EP (1) EP3230248B1 (https=)
JP (2) JP7128622B2 (https=)
KR (1) KR102507703B1 (https=)
CN (1) CN107001218B (https=)
BR (1) BR112017011447B1 (https=)
CA (1) CA2969527C (https=)
MX (1) MX381950B (https=)
MY (1) MY184826A (https=)
PL (1) PL3230248T3 (https=)
RU (1) RU2699368C2 (https=)
TW (1) TWI586644B (https=)
WO (1) WO2016089602A1 (https=)

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TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
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US12221404B2 (en) 2020-06-05 2025-02-11 SCION Holdings LLC Composition comprising branched aldehydes
US11680032B2 (en) 2020-06-05 2023-06-20 SCION Holdings LLC Alcohols production
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WO2022081444A1 (en) 2020-10-13 2022-04-21 Dow Silicones Corporation Preparation of organosilicon compounds with aldehyde functionality
CN112403401B (zh) * 2020-11-06 2022-06-21 中国海洋石油集团有限公司 一种烯烃氢甲酰化制醛中醛和催化剂分离的装置和方法
CN116635362A (zh) * 2020-12-14 2023-08-22 陶氏技术投资有限责任公司 改进加氢甲酰化方法中的催化金属可计量性的方法
US12145904B2 (en) 2020-12-17 2024-11-19 SCION Holdings LLC Branched products
WO2023060155A1 (en) 2021-10-06 2023-04-13 Dow Global Technologies Llc Preparation of propylimine-functional organosilicon compounds and primary aminopropyl-functional organosilicon compounds
CN118043331A (zh) 2021-10-06 2024-05-14 陶氏环球技术有限责任公司 制备氨基官能化有机硅化合物
CN118019747A (zh) 2021-10-06 2024-05-10 陶氏环球技术有限责任公司 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备
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US20250122229A1 (en) 2021-11-22 2025-04-17 Dow Silicones Corporation Preparation of organosilicon compounds with carbinol functionality
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US20250051524A1 (en) 2022-03-21 2025-02-13 Dow Silicones Corporation Preparation of organosilicon compounds with carboxy functionality
CN118974116A (zh) 2022-04-13 2024-11-15 陶氏环球技术有限责任公司 有机硅-乙烯基酯官能化合物及其制备方法和在个人护理组合物中的用途
JP2025514660A (ja) 2022-04-13 2025-05-09 ダウ グローバル テクノロジーズ エルエルシー ビニルエステル官能性を有する有機ケイ素化合物の調製
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US20250257169A1 (en) 2022-04-13 2025-08-14 Dow Silicones Corporation Composition, urethane prepolymer, and related methods and uses
CN114773172B (zh) * 2022-06-20 2022-10-18 中海油天津化工研究设计院有限公司 一种烯烃氢甲酰化制醛工艺优化方法
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
CN120225491A (zh) 2022-12-06 2025-06-27 陶氏技术投资有限责任公司 控制再循环催化剂料流中的重质物的方法
GB202303617D0 (en) 2023-03-13 2023-04-26 Johnson Matthey Davy Technologies Ltd Method and apparatus for producing aldehyde
CN121532373A (zh) 2023-08-03 2026-02-13 陶氏技术投资有限责任公司 用于改善基于铑/亚磷酸酯的均相加氢甲酰化催化剂活性的方法
KR20260045840A (ko) 2023-08-03 2026-04-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포르밀화 공정
CN121605144A (zh) 2023-08-14 2026-03-03 陶氏环球技术有限责任公司 乙烯基官能化聚有机硅氧烷的钴催化的加氢甲酰化
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WO2025170887A1 (en) * 2024-02-06 2025-08-14 Eastman Chemical Company Gas distribution in gas-stripping hydroformylation reactor for oxo aldehydes
WO2025170897A1 (en) * 2024-02-06 2025-08-14 Eastman Chemical Company Optimized gas-stripping hydroformylation process for oxo aldehydes
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EP3230248B1 (en) 2019-12-25
TWI586644B (zh) 2017-06-11
CA2969527C (en) 2023-08-22
MX381950B (es) 2025-03-13
BR112017011447B1 (pt) 2020-12-15
EP3230248A1 (en) 2017-10-18
CA2969527A1 (en) 2016-06-09
RU2017121307A (ru) 2018-12-19
BR112017011447A2 (pt) 2018-02-27
US20170355656A1 (en) 2017-12-14
JP2021008477A (ja) 2021-01-28
RU2017121307A3 (https=) 2019-02-01
JP7128622B2 (ja) 2022-08-31
JP2017537918A (ja) 2017-12-21
CN107001218A (zh) 2017-08-01
WO2016089602A1 (en) 2016-06-09
MX2017006792A (es) 2017-09-08
TW201620863A (zh) 2016-06-16
RU2699368C2 (ru) 2019-09-05
PL3230248T3 (pl) 2020-05-18
CN107001218B (zh) 2021-02-26
MY184826A (en) 2021-04-24
US10023516B2 (en) 2018-07-17
KR20170093152A (ko) 2017-08-14

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