KR102107032B1 - 글래스 조성물, 이를 포함하는 외부전극용 페이스트 및 적층 세라믹 전자부품 - Google Patents
글래스 조성물, 이를 포함하는 외부전극용 페이스트 및 적층 세라믹 전자부품 Download PDFInfo
- Publication number
- KR102107032B1 KR102107032B1 KR1020140055474A KR20140055474A KR102107032B1 KR 102107032 B1 KR102107032 B1 KR 102107032B1 KR 1020140055474 A KR1020140055474 A KR 1020140055474A KR 20140055474 A KR20140055474 A KR 20140055474A KR 102107032 B1 KR102107032 B1 KR 102107032B1
- Authority
- KR
- South Korea
- Prior art keywords
- mol
- glass
- group
- oxide
- external electrode
- Prior art date
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- 239000011521 glass Substances 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000000919 ceramic Substances 0.000 title claims description 55
- 239000011572 manganese Substances 0.000 claims abstract description 49
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 29
- 229910052788 barium Inorganic materials 0.000 claims abstract description 28
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 28
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 28
- 229910052796 boron Inorganic materials 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 22
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000010703 silicon Substances 0.000 claims abstract description 22
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 22
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 21
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 21
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011591 potassium Substances 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 21
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002003 electrode paste Substances 0.000 claims description 19
- 239000010949 copper Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 34
- 239000011787 zinc oxide Substances 0.000 abstract description 17
- 238000010304 firing Methods 0.000 description 18
- 238000007747 plating Methods 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 239000011701 zinc Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 229910052720 vanadium Inorganic materials 0.000 description 7
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 6
- 239000003985 ceramic capacitor Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 229910018068 Li 2 O Inorganic materials 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002113 barium titanate Inorganic materials 0.000 description 2
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000004031 devitrification Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/228—Terminals
- H01G4/232—Terminals electrically connecting two or more layers of a stacked or rolled capacitor
- H01G4/2325—Terminals electrically connecting two or more layers of a stacked or rolled capacitor characterised by the material of the terminals
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Glass Compositions (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Ceramic Capacitors (AREA)
- Conductive Materials (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140055474A KR102107032B1 (ko) | 2014-05-09 | 2014-05-09 | 글래스 조성물, 이를 포함하는 외부전극용 페이스트 및 적층 세라믹 전자부품 |
| JP2014146683A JP6104853B2 (ja) | 2014-05-09 | 2014-07-17 | ガラス組成物、それを含有する外部電極用ペースト、及び積層セラミック電子部品 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140055474A KR102107032B1 (ko) | 2014-05-09 | 2014-05-09 | 글래스 조성물, 이를 포함하는 외부전극용 페이스트 및 적층 세라믹 전자부품 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150128309A KR20150128309A (ko) | 2015-11-18 |
| KR102107032B1 true KR102107032B1 (ko) | 2020-05-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020140055474A KR102107032B1 (ko) | 2014-05-09 | 2014-05-09 | 글래스 조성물, 이를 포함하는 외부전극용 페이스트 및 적층 세라믹 전자부품 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6104853B2 (ja) |
| KR (1) | KR102107032B1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102538902B1 (ko) | 2016-02-24 | 2023-06-01 | 삼성전기주식회사 | 전자부품 및 그의 제조방법 |
| KR102018309B1 (ko) * | 2017-10-31 | 2019-09-04 | 삼성전기주식회사 | 커패시터 부품 및 이의 제조 방법 |
| JP6702296B2 (ja) * | 2017-12-08 | 2020-06-03 | 株式会社村田製作所 | 電子部品 |
| JP6954130B2 (ja) * | 2018-01-11 | 2021-10-27 | Ａｇｃ株式会社 | ガラス、ガラス粉末、導電ペーストおよび太陽電池 |
| JP7117256B2 (ja) * | 2019-02-22 | 2022-08-12 | 日本山村硝子株式会社 | ガラス組成物 |
| JP7424340B2 (ja) | 2021-04-02 | 2024-01-30 | 株式会社村田製作所 | 導電性ペースト、積層セラミックコンデンサの製造方法、積層セラミックコンデンサ |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002100526A (ja) * | 2000-09-25 | 2002-04-05 | Shoei Chem Ind Co | 積層セラミック部品端子電極用導体ペースト |
| JP2003246644A (ja) * | 2001-12-21 | 2003-09-02 | Shoei Chem Ind Co | ガラスおよびこれを用いた導体ペースト |
| JP2013232609A (ja) * | 2012-05-02 | 2013-11-14 | Noritake Co Ltd | 太陽電池用導電性ペースト組成物 |
| WO2014050703A1 (ja) * | 2012-09-26 | 2014-04-03 | 株式会社村田製作所 | 導電性ペースト及び太陽電池 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100664979B1 (ko) * | 2003-11-20 | 2007-01-09 | 삼성전기주식회사 | 글라스 프릿트와 그 제조방법, 이를 이용하는 외부전극용페이스트 조성물 및 적층세라믹 커패시터 |
| JP2008130720A (ja) | 2006-11-20 | 2008-06-05 | Tdk Corp | 電極形成用組成物及びこれを用いた電子部品 |
-
2014
- 2014-05-09 KR KR1020140055474A patent/KR102107032B1/ko active IP Right Grant
- 2014-07-17 JP JP2014146683A patent/JP6104853B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002100526A (ja) * | 2000-09-25 | 2002-04-05 | Shoei Chem Ind Co | 積層セラミック部品端子電極用導体ペースト |
| JP2003246644A (ja) * | 2001-12-21 | 2003-09-02 | Shoei Chem Ind Co | ガラスおよびこれを用いた導体ペースト |
| JP2013232609A (ja) * | 2012-05-02 | 2013-11-14 | Noritake Co Ltd | 太陽電池用導電性ペースト組成物 |
| WO2014050703A1 (ja) * | 2012-09-26 | 2014-04-03 | 株式会社村田製作所 | 導電性ペースト及び太陽電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150128309A (ko) | 2015-11-18 |
| JP6104853B2 (ja) | 2017-03-29 |
| JP2015216091A (ja) | 2015-12-03 |
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