KR102073426B1 - 에틸렌 삼량체화 구역으로부터 얻어진 생성물의 혼합물로부터 1-헥센을 분리하는 방법 - Google Patents

에틸렌 삼량체화 구역으로부터 얻어진 생성물의 혼합물로부터 1-헥센을 분리하는 방법 Download PDF

Info

Publication number
KR102073426B1
KR102073426B1 KR1020130078445A KR20130078445A KR102073426B1 KR 102073426 B1 KR102073426 B1 KR 102073426B1 KR 1020130078445 A KR1020130078445 A KR 1020130078445A KR 20130078445 A KR20130078445 A KR 20130078445A KR 102073426 B1 KR102073426 B1 KR 102073426B1
Authority
KR
South Korea
Prior art keywords
distillation column
hexene
ethylene
reaction section
fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020130078445A
Other languages
English (en)
Korean (ko)
Other versions
KR20140005115A (ko
Inventor
다니엘-쟝 비넬
쟝-알랭 쇼도르쥬
제롬 피주리에
삐에르-이브 마르탱
로랑 부르나이
Original Assignee
악상스
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 악상스 filed Critical 악상스
Publication of KR20140005115A publication Critical patent/KR20140005115A/ko
Application granted granted Critical
Publication of KR102073426B1 publication Critical patent/KR102073426B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020130078445A 2012-07-04 2013-07-04 에틸렌 삼량체화 구역으로부터 얻어진 생성물의 혼합물로부터 1-헥센을 분리하는 방법 Active KR102073426B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR12/01.886 2012-07-04
FR1201886A FR2992962B1 (fr) 2012-07-04 2012-07-04 Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene

Publications (2)

Publication Number Publication Date
KR20140005115A KR20140005115A (ko) 2014-01-14
KR102073426B1 true KR102073426B1 (ko) 2020-02-04

Family

ID=46754512

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020130078445A Active KR102073426B1 (ko) 2012-07-04 2013-07-04 에틸렌 삼량체화 구역으로부터 얻어진 생성물의 혼합물로부터 1-헥센을 분리하는 방법

Country Status (9)

Country Link
US (1) US8816147B2 (enExample)
EP (1) EP2703373B1 (enExample)
JP (1) JP6122713B2 (enExample)
KR (1) KR102073426B1 (enExample)
CA (1) CA2819921C (enExample)
ES (1) ES2655920T3 (enExample)
FR (1) FR2992962B1 (enExample)
RU (1) RU2619113C2 (enExample)
TW (1) TWI594980B (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX369759B (es) * 2015-01-19 2019-11-20 Evonik Operations Gmbh Preparación combinada de buteno y octeno a partir de eteno.
NO3045438T3 (enExample) * 2015-01-19 2018-04-28
JP6711029B2 (ja) * 2015-03-25 2020-06-17 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
FR3045652B1 (fr) * 2015-12-22 2018-01-12 Axens Procede de fractionnement pour un procede d'oligomerisation d'olefines legeres
WO2017115255A1 (en) * 2015-12-29 2017-07-06 Sabic Global Technologies B.V. Fractional distillation systems and methods for linear alpha olefin production
WO2017115306A1 (en) * 2015-12-30 2017-07-06 Sabic Global Technologies B.V. Method of separating hexene
ES2939636T3 (es) * 2015-12-30 2023-04-25 Sabic Global Technologies Bv Método para separar hexeno
CN108473392A (zh) * 2015-12-30 2018-08-31 沙特基础工业全球技术有限公司 分离己烯的方法
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
EP3554664B1 (en) * 2016-12-19 2025-07-09 SABIC Global Technologies B.V. Method of separating linear alpha olefins
ES2937032T3 (es) * 2016-12-19 2023-03-23 Sabic Global Technologies Bv Método de separación de alfa olefinas lineales
WO2020114745A1 (en) 2018-12-04 2020-06-11 Exxonmobil Chemical Patents Inc. Methods for separating linear alpha olefins from combined product streams
KR102383417B1 (ko) * 2018-12-10 2022-04-07 주식회사 엘지화학 에틸렌 올리고머화 반응 생성물의 분리방법
EP3927678A4 (en) * 2019-02-22 2022-10-26 Public Joint Stock Company "Sibur Holding" PROCESS FOR SEPARATION OF OLEFIN OLIGOMERIZATION PRODUCTS (VARIANTS)
FR3099476B1 (fr) * 2019-07-31 2021-07-30 Ifp Energies Now Procede d’oligomerisation mettant en œuvre un recycle du ciel gazeux
KR102602865B1 (ko) 2019-08-21 2023-11-16 주식회사 엘지화학 올리고머 제조 방법 및 올리고머 제조 장치
FR3102685B1 (fr) 2019-11-06 2021-10-29 Ifp Energies Now Procédé d’oligomérisation d’oléfines dans un réacteur d’oligomérisation
FR3103485B1 (fr) 2019-11-26 2023-03-24 Ifp Energies Now Procédé de séparation d’un effluent issu d’une étape d’oligomérisation
FR3108264B1 (fr) 2020-03-19 2022-04-08 Ifp Energies Now Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines
JP7366486B2 (ja) 2020-09-07 2023-10-23 エルジー・ケム・リミテッド オリゴマーの製造方法
FR3121439B1 (fr) 2021-03-30 2023-03-24 Ifp Energies Now Procede d'oligomerisation comprenant une etape de recyclage d'un solvant prealablement refroidi
FR3123354B1 (fr) 2021-05-28 2023-05-26 Ifp Energies Now Procede d'oligomerisation dans un reacteur a zones de diametres variables comprenant une etape de recyclage d'un solvant prealablement refroidi
CN113511949A (zh) * 2021-08-06 2021-10-19 迈瑞尔实验设备（上海）有限公司 一种乙烯选择性齐聚联产1-己烯及1-辛烯的生产工艺
CN114917608B (zh) * 2022-06-30 2025-05-13 中国天辰工程有限公司 一种低能耗的丙烯寡聚体分离系统及分离方法
CN117209350A (zh) * 2023-09-13 2023-12-12 中化泉州能源科技有限责任公司 一种乙烯选择性齐聚产物的分离方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002256007A (ja) 2000-12-26 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2004502527A (ja) 2000-07-11 2004-01-29 ビーピー　ケミカルズ　リミテッド クロム、モリブデンもしくはタングステンの供給源および少なくとも１種の（ヘテロ）ヒドロカルビル基に結合した少なくとも１個の燐、砒素もしくはアンチモン原子を含有するリガンドを用いるオレフィン三量化
JP2005314268A (ja) 2004-04-28 2005-11-10 Sumitomo Chemical Co Ltd １−ヘキセンの製造方法
JP2009102363A (ja) 2006-12-28 2009-05-14 Mitsubishi Chemicals Corp α−オレフィン低重合体の製造方法
WO2011112184A1 (en) 2010-03-09 2011-09-15 Exxonmobil Chemical Patents Inc. System and method for selective trimerization

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3540827B2 (ja) * 1993-11-30 2004-07-07 三菱化学株式会社 １−ヘキセンの製造方法
US20020182124A1 (en) * 1997-10-14 2002-12-05 William M. Woodard Olefin production process
RU2200725C1 (ru) * 2001-08-24 2003-03-20 Попов Валерий Георгиевич Способ получения тримеров и тетрамеров пропилена
US7476775B2 (en) * 2004-03-03 2009-01-13 Chevron Phillips Chemical Company Lp Method and system for separating an oligomerization reactor effluent
US7858833B2 (en) * 2006-02-03 2010-12-28 Exxonmobil Chemical Patents Inc. Process for generating linear alpha olefin comonomers
US20100036185A1 (en) * 2006-12-28 2010-02-11 Mitsubishi Chemical Corporation Production method of ethylene low polymer
EP2196444A1 (en) * 2008-12-11 2010-06-16 Total Petrochemicals Research Feluy Process to make alpha olefins from ethanol
EP2295474A1 (en) * 2009-09-11 2011-03-16 Total Petrochemicals Research Feluy Process for recycling product streams separated from a hydrocarbon-containing feed stream.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004502527A (ja) 2000-07-11 2004-01-29 ビーピー　ケミカルズ　リミテッド クロム、モリブデンもしくはタングステンの供給源および少なくとも１種の（ヘテロ）ヒドロカルビル基に結合した少なくとも１個の燐、砒素もしくはアンチモン原子を含有するリガンドを用いるオレフィン三量化
JP2002256007A (ja) 2000-12-26 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2005314268A (ja) 2004-04-28 2005-11-10 Sumitomo Chemical Co Ltd １−ヘキセンの製造方法
JP2009102363A (ja) 2006-12-28 2009-05-14 Mitsubishi Chemicals Corp α−オレフィン低重合体の製造方法
WO2011112184A1 (en) 2010-03-09 2011-09-15 Exxonmobil Chemical Patents Inc. System and method for selective trimerization

Also Published As

Publication number Publication date
RU2013130665A (ru) 2015-01-10
TW201402543A (zh) 2014-01-16
KR20140005115A (ko) 2014-01-14
US8816147B2 (en) 2014-08-26
JP6122713B2 (ja) 2017-04-26
TWI594980B (zh) 2017-08-11
ES2655920T3 (es) 2018-02-22
FR2992962B1 (fr) 2015-06-26
FR2992962A1 (fr) 2014-01-10
CA2819921C (fr) 2020-08-25
RU2619113C2 (ru) 2017-05-12
US20140012059A1 (en) 2014-01-09
JP2014012665A (ja) 2014-01-23
CA2819921A1 (fr) 2014-01-04
EP2703373B1 (fr) 2017-10-25
EP2703373A1 (fr) 2014-03-05

Similar Documents

Publication Publication Date Title
KR102073426B1 (ko) 에틸렌 삼량체화 구역으로부터 얻어진 생성물의 혼합물로부터 1-헥센을 분리하는 방법
KR102591168B1 (ko) 세정 장치를 이용한 올레핀의 올리고머화 방법
RU2635551C9 (ru) Способ олигомеризации этилена
KR102074753B1 (ko) 적어도 하나의 공단량체 생성물을 형성하기 위한 탄화수소 올리고머화 방법
JP6081590B2 (ja) エチレンのオリゴマー化のための方法
KR101124028B1 (ko) 열 제거성이 개선된 선형 알파-올레핀의 제조 방법
US7652185B2 (en) Catalyst recovery process
CN102046567A (zh) 二异丁烯的方法
WO2018208375A1 (en) Linear alpha olefin process including solvent purification using dividing wall distillation column
EA039573B1 (ru) Способ извлечения альдегида, полученного путем гидроформилирования, с использованием двух колонн с увеличивающимся давлением
JP2022519998A (ja) オリゴマーの製造方法およびオリゴマーの製造装置
EP4581003A1 (en) Methods for producing 1-hexene
US20250122134A1 (en) Separation method for a mixture comprising a solvent and c4 or higher linear alpha olefins, and method and device for preparing ethylene oligomer utilizing the separation method
KR102838708B1 (ko) 올레핀의 올리고머화 반응 생성물의 분리 방법, 및 이를 활용한 에틸렌 올리고머 제조 방법 및 장치
KR20250129077A (ko) 스테이지-가열 증류 컬컴에 의해 선형 알파 올레핀을 정제하는 방법

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 20130704

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20180627

Comment text: Request for Examination of Application

Patent event code: PA02011R01I

Patent event date: 20130704

Comment text: Patent Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20190726

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20191115

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20200129

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20200129

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20230119

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20240125

Start annual number: 5

End annual number: 5