KR102042563B1 - 이소시네이트의 연속 개질 방법 - Google Patents

이소시네이트의 연속 개질 방법 Download PDF

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Publication number
KR102042563B1
KR102042563B1 KR1020147014535A KR20147014535A KR102042563B1 KR 102042563 B1 KR102042563 B1 KR 102042563B1 KR 1020147014535 A KR1020147014535 A KR 1020147014535A KR 20147014535 A KR20147014535 A KR 20147014535A KR 102042563 B1 KR102042563 B1 KR 102042563B1
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South Korea
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diisocyanate
reaction
catalyst
isocyanate
mol
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Korean (ko)
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KR20140099248A (ko
Inventor
프란크 리히터
마르틴 안스토크
필립 바케
안드레아스 고쉬
라인하르트 할파프
안드레아스 헥킹
지구르트 부흐홀츠
우르줄라 트라흐트
아드리안 코스민 도브레
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바이엘 인텔렉쳐 프로퍼티 게엠베하
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
    • C08G18/022—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D273/00—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00
    • C07D273/02—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00 having two nitrogen atoms and only one oxygen atom
    • C07D273/04—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
    • C08G18/025—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing carbodiimide groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147014535A 2011-11-30 2012-11-29 이소시네이트의 연속 개질 방법 Expired - Fee Related KR102042563B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11191377 2011-11-30
EP11191377.8 2011-11-30
PCT/EP2012/073998 WO2013079614A2 (de) 2011-11-30 2012-11-29 Verfahren zur kontinuierlichen isocyanatmodifizierung

Publications (2)

Publication Number Publication Date
KR20140099248A KR20140099248A (ko) 2014-08-11
KR102042563B1 true KR102042563B1 (ko) 2019-11-11

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KR1020147014535A Expired - Fee Related KR102042563B1 (ko) 2011-11-30 2012-11-29 이소시네이트의 연속 개질 방법

Country Status (8)

Country Link
US (1) US9790194B2 (enExample)
EP (1) EP2785761B1 (enExample)
JP (1) JP6249954B2 (enExample)
KR (1) KR102042563B1 (enExample)
CN (2) CN109970950A (enExample)
ES (1) ES2649097T3 (enExample)
HU (1) HUE034989T2 (enExample)
WO (1) WO2013079614A2 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6184773B2 (ja) * 2013-06-28 2017-08-23 旭化成株式会社 ポリイソシアネート組成物
EP3115385B1 (en) * 2014-03-04 2022-05-25 Mitsui Chemicals, Inc. Polyisocyanurate composition and method for producing same
JP6434825B2 (ja) * 2014-03-04 2018-12-05 三井化学株式会社 ポリイソシアヌレート組成物の製造方法
JP6419197B2 (ja) * 2014-09-04 2018-11-07 旭化成株式会社 ポリイソシアネート組成物、塗料組成物、塗膜及びその製造方法、並びに湿気安定化方法
CN107406566A (zh) 2015-05-08 2017-11-28 三井化学株式会社 多异氰酸酯组合物、聚氨酯树脂及涂料
CN107922563B (zh) * 2015-08-17 2020-12-08 科思创德国股份有限公司 使用环状铵盐作为催化剂改性异氰酸酯的方法
EP3301084B1 (de) * 2016-09-30 2018-12-12 OXEA GmbH Kontinuierliches herstellungsverfahren für 2-methylenalkanale
EP4122968A1 (en) 2016-10-14 2023-01-25 Asahi Kasei Kabushiki Kaisha Polyisocyanate composition, blocked polyisocyanate composition, hydrophilic polyisocyanate composition, coating material composition, and coating film
EP3444288A1 (de) 2017-08-15 2019-02-20 Covestro Deutschland AG Verfahren zur herstellung iminooxadiazindiongruppen enthaltender polyisocyanate unter verwendung von katalysatorenmischungen
CN111465632B (zh) * 2017-12-21 2022-07-19 科思创德国股份有限公司 制备含异氰脲酸酯基团的异氰酸酯混合物的方法
EP3827043A1 (en) * 2018-07-26 2021-06-02 Covestro Intellectual Property GmbH & Co. KG Process for preparing polyisocyanates containing urethane groups
JP7206089B2 (ja) * 2018-10-04 2023-01-17 旭化成株式会社 ポリイソシアネート組成物、塗料組成物及び塗膜
CA3135660A1 (en) 2019-04-01 2020-10-08 Basf Se Continuous production of polyurethane prepolymers
CN116063658B (zh) * 2021-11-02 2025-07-04 万华化学集团股份有限公司 一种异氰酸酯组合物的制备方法
CN118251435A (zh) * 2021-11-16 2024-06-25 巴斯夫欧洲公司 含有亚氨基噁二嗪二酮基团的多异氰酸酯的制备及其用途

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004060131A1 (de) 2004-12-13 2006-06-14 Basf Ag Verfahren zur Herstellung von Polyisocyanaten
JP2008523128A (ja) 2004-12-13 2008-07-03 ビーエーエスエフ ソシエタス・ヨーロピア 無色の、貯蔵安定性のビウレット基含有のポリイソシアナートの製造方法
JP2010511662A (ja) 2006-12-04 2010-04-15 ビーエーエスエフ ソシエタス・ヨーロピア ポリイソシアネートを製造するための方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0014676A3 (de) 1979-02-01 1980-11-12 Ciba-Geigy Ag Substituierte N-Phenyl-N'-benzoylharnstoffe, Verfahren zu ihrer Herstellung, diese Verbindungen enthaltende Mittel und ihre Verwendung zur Bekämpfung von Schädlingen
FR2448008A1 (fr) 1979-02-05 1980-08-29 Saint Gobain Elements de construction en platre pour l'amenagement de structures de batiments
DE2916201A1 (de) 1979-04-21 1980-10-30 Huels Chemische Werke Ag Verfahren zur trimerisierung von diisocyanaten
EP0235388B1 (en) 1985-12-28 1989-11-08 MITSUI TOATSU CHEMICALS, Inc. Preparation process of heat-resistant polymers
WO1988009329A1 (fr) 1987-05-20 1988-12-01 Mitsui Toatsu Chemicals, Inc. Procede de preparation de substances possedant une structure cyclique d'isocyanurate
JPH0623229B2 (ja) 1987-06-19 1994-03-30 三井東圧化学株式会社 熱硬化性樹脂の製造法
DE3814167A1 (de) 1988-04-27 1989-11-09 Bayer Ag Verfahren zur herstellung von isocyanuratgruppen aufweisenden polyisocyanaten und ihre verwendung
DE3902078A1 (de) 1989-01-25 1990-07-26 Bayer Ag Verfahren zur herstellung von modifizierten, isocyanuratgruppen aufweisenden polyisocyanaten und ihre verwendung
JP3195787B2 (ja) 1990-03-12 2001-08-06 旭電化工業株式会社 イソシアネート三量化またはウレタン化触媒
DE4217019A1 (de) * 1992-05-22 1993-11-25 Bayer Ag Verfahren zur Herstellung von aromatischen Diisocyanaten
DE19611849A1 (de) 1996-03-26 1997-10-02 Bayer Ag Neue Isocyanattrimerisate und Isocyanattrimerisatmischungen, deren Herstellung und Verwendung
DE19631859A1 (de) * 1996-08-07 1998-02-12 Bayer Ag Verfahren zur Polymerisation von Isocyanaten
DE19734048A1 (de) 1997-08-06 1999-02-11 Bayer Ag Verfahren zur Herstellung von Polyisocyanaten, damit hergestellte Polyisocyanate und deren Verwendung
ZA9810038B (en) * 1997-11-04 2000-05-03 Rhodia Chimie Sa A catalyst and a method for the trimerization of isocyanates.
DE19804033A1 (de) * 1998-02-02 1999-08-05 Basf Ag Kontinuierliches Verfahren zur Herstellung von Polyamiden aus Aminonitrilen
PT962454E (pt) * 1998-06-02 2002-12-31 Bayer Ag Processo para a preparacao de poli-isocianatos contendo grupos imino-oxadiazinodiona produtos do processo assim preparados e sua utilizacao
DE10232573A1 (de) 2002-07-18 2004-02-05 Bayer Ag Verfahren zur kontinuierlichen Herstellung von Isocyanuratgruppen enthaltenden Polyisocyanaten mit aromatisch gebundenen Isocyanatgruppen
DE10254878A1 (de) 2002-11-25 2004-06-03 Bayer Ag Herstellung uretdiongruppenhaltiger Polyisocyanate
DE10354544A1 (de) 2003-11-21 2005-06-23 Bayer Materialscience Ag Herstellung uretdiongruppenhaltiger Polyisocyanate
US7250184B2 (en) 2004-08-23 2007-07-31 Micro-Tender Industries Composition and method for tenderizing meat
DE102004048871A1 (de) 2004-10-07 2006-04-13 Bayer Materialscience Ag Verfahren zur Herstellung von Iminooxadiazindiongruppen aufweisenden Polyisocyanaten
US7795359B2 (en) 2005-03-04 2010-09-14 Novartis Ag Continuous process for production of polymeric materials
DE102005013401A1 (de) * 2005-03-23 2006-09-28 Degussa Ag Niedrigviskose uretdiongruppenhaltige Polyadditionsverbindungen, Verfahren zur Herstellung und Verwendung
DE102006004077A1 (de) * 2006-01-28 2007-08-02 Degussa Gmbh Verfahren zur Herstellung von hoch reaktiven uretdiongruppenhaltigen Polyurethanverbindungen
DE102006061536A1 (de) 2006-12-27 2008-07-03 Bayer Materialscience Ag Verfahren zur Konditionierung von Isocyanaten
DE102007018015A1 (de) 2007-04-17 2008-10-23 Bayer Materialscience Ag Herstellung uretdiongruppenhaltiger Polyisocyanate
DE102007058487A1 (de) 2007-12-04 2009-06-10 Bayer Materialscience Ag Herstellung von Uretdion-Polyisocyanaten
EP2100885A1 (de) 2008-03-14 2009-09-16 Bayer MaterialScience AG Herstellung von Polyisocyanaten vom Trimertyp
FR2929612B1 (fr) 2008-04-03 2011-02-04 Rhodia Operations Procede d'oligomerisation des isocyanates en continu

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004060131A1 (de) 2004-12-13 2006-06-14 Basf Ag Verfahren zur Herstellung von Polyisocyanaten
JP2008523128A (ja) 2004-12-13 2008-07-03 ビーエーエスエフ ソシエタス・ヨーロピア 無色の、貯蔵安定性のビウレット基含有のポリイソシアナートの製造方法
JP2010511662A (ja) 2006-12-04 2010-04-15 ビーエーエスエフ ソシエタス・ヨーロピア ポリイソシアネートを製造するための方法

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Publication number Publication date
ES2649097T3 (es) 2018-01-10
HUE034989T2 (en) 2018-05-02
CN103958559A (zh) 2014-07-30
JP2015500900A (ja) 2015-01-08
EP2785761B1 (de) 2017-09-13
WO2013079614A2 (de) 2013-06-06
WO2013079614A3 (de) 2014-01-30
JP6249954B2 (ja) 2017-12-20
CN109970950A (zh) 2019-07-05
KR20140099248A (ko) 2014-08-11
EP2785761A2 (de) 2014-10-08
US20140343280A1 (en) 2014-11-20
US9790194B2 (en) 2017-10-17

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