KR102032584B1 - Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법 - Google Patents

Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법 Download PDF

Info

Publication number
KR102032584B1
KR102032584B1 KR1020147015629A KR20147015629A KR102032584B1 KR 102032584 B1 KR102032584 B1 KR 102032584B1 KR 1020147015629 A KR1020147015629 A KR 1020147015629A KR 20147015629 A KR20147015629 A KR 20147015629A KR 102032584 B1 KR102032584 B1 KR 102032584B1
Authority
KR
South Korea
Prior art keywords
cha
seed
mixture
zeolite
type framework
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020147015629A
Other languages
English (en)
Korean (ko)
Other versions
KR20140093982A (ko
Inventor
스테판 마우러
한펭 진
제프 양
율리크 뮬러
Original Assignee
바스프 에스이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바스프 에스이 filed Critical 바스프 에스이
Publication of KR20140093982A publication Critical patent/KR20140093982A/ko
Application granted granted Critical
Publication of KR102032584B1 publication Critical patent/KR102032584B1/ko
Assigned to 바스프 카탈리스트 엘엘씨 reassignment 바스프 카탈리스트 엘엘씨 권리의 전부이전등록 Assignors: 바스프 에스이
Assigned to 바스프 모바일 에미션스 카탈리스츠 엘엘씨 reassignment 바스프 모바일 에미션스 카탈리스츠 엘엘씨 권리의 전부이전등록 Assignors: 바스프 카탈리스트 엘엘씨
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/10—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least phosphorus atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Oxide Ceramics (AREA)
KR1020147015629A 2011-11-11 2012-11-09 Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법 Active KR102032584B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188857 2011-11-11
EP11188857.4 2011-11-11
PCT/IB2012/056292 WO2013068976A1 (en) 2011-11-11 2012-11-09 Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure

Publications (2)

Publication Number Publication Date
KR20140093982A KR20140093982A (ko) 2014-07-29
KR102032584B1 true KR102032584B1 (ko) 2019-10-15

Family

ID=48288615

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147015629A Active KR102032584B1 (ko) 2011-11-11 2012-11-09 Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법

Country Status (12)

Country Link
EP (1) EP2776369B1 (https=)
JP (1) JP6324895B2 (https=)
KR (1) KR102032584B1 (https=)
CN (1) CN104039704B (https=)
BR (1) BR112014011308B1 (https=)
CA (1) CA2855572C (https=)
IN (1) IN2014CN03353A (https=)
MX (1) MX375064B (https=)
PL (1) PL2776369T3 (https=)
RU (1) RU2612697C2 (https=)
WO (1) WO2013068976A1 (https=)
ZA (1) ZA201404210B (https=)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101960567B1 (ko) * 2012-12-10 2019-03-20 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 알루미노실리케이트 분자체의 씨딩된 합성
US20170368542A1 (en) * 2014-12-17 2017-12-28 Sabic Global Technologies B.V. Silicoaluminophosphate catalyst for chloromethane conversion
ES2574500B1 (es) * 2014-12-17 2017-03-31 Consejo Superior De Investigaciones Científicas (Csic) Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas
CN108698841B (zh) * 2015-12-22 2023-01-17 巴斯夫公司 制备铁(iii)交换的沸石组合物的方法
CN121800199A (zh) * 2016-06-08 2026-04-07 巴斯夫公司 来自无有机模板的合成的cha骨架结构的铜助催化沸石材料及其在nox的选择性催化还原中的用途
CN109311006B (zh) 2016-06-08 2022-09-27 巴斯夫公司 铜助催化的钠菱沸石及其在NOx的选择性催化还原中的用途
CN106145137B (zh) * 2016-06-27 2018-06-05 杨晓波 一种直接水热合成中硅铝比菱沸石的方法
CN106145138B (zh) * 2016-06-27 2018-05-08 杨晓波 一种合成具有菱沸石结构的沸石分子筛的方法
JP7125937B2 (ja) * 2016-12-02 2022-08-25 エコラブ ユーエスエイ インク ポリアルミニウム塩ならびに高純度コロイド状アルミナ－シリカ複合粒子およびゼオライトの調製におけるそれらの使用
WO2018210809A1 (en) 2017-05-15 2018-11-22 Basf Se A process for preparing a zeolitic material having framework type aei
US11148954B2 (en) 2017-05-15 2021-10-19 Basf Corporation Process for preparing a zeolitic material comprising a metal M and having framework type AEI
RU2020102868A (ru) * 2017-07-11 2021-08-11 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор и способ его применения
BR112020004607B1 (pt) 2017-09-07 2023-04-11 Basf Corporation Composição catalisadora scr, artigo catalisador, método para reduzir o nível de no x em um gás de exaustão e sistema de tratamento de emissão para tratamento de uma corrente de gás de exaustão
CN108217681B (zh) * 2018-01-19 2021-07-06 山东齐鲁华信高科有限公司 一种高铁含量的Fe-ZSM-5分子筛的制备方法
CN108083292B (zh) * 2018-01-31 2020-12-29 吉林大学 一种磷掺杂cha分子筛、制备方法及其应用
KR102755650B1 (ko) 2018-05-25 2025-01-20 바스프 모바일 에미션스 카탈리스츠 엘엘씨 희토류 원소를 함유하는 알루미늄-풍부 제올라이트 물질
CN112424123B (zh) 2018-07-27 2024-01-23 巴斯夫欧洲公司 制备具有骨架类型fer的沸石材料的方法
US12264076B2 (en) 2019-05-15 2025-04-01 Basf Mobile Emissions Catalysts Llc Process for the production of the CHA-AFT zeolite intergrowth COE-10 and use thereof in heterogeneous catalysis
CN111348660B (zh) * 2020-03-16 2022-08-09 江西师范大学 一种中硅cha型分子筛及其制备方法和应用
CN111762794B (zh) * 2020-07-13 2022-08-05 包头稀土研究院 分子筛及其制备方法
CN111762795B (zh) * 2020-07-13 2022-10-14 包头稀土研究院 含有稀土元素的分子筛及其生产方法
EP4015454A1 (en) * 2020-12-21 2022-06-22 Tosoh Corporation Cha-type zeolite and manufacturing method thereof
CN112919493B (zh) * 2021-02-05 2022-10-14 正大能源材料(大连)有限公司 一种低成本制备ssz-13分子筛的方法及应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU833498A1 (ru) * 1979-06-25 1981-05-30 Институт Общей И Неорганической Химииан Армянской Ccp Способ получени шабазита
SU1640112A1 (ru) * 1987-12-28 1991-04-07 Предприятие П/Я Р-6518 Синтетический натриево-цезиевый цеолит типа шабазит
CN1311757A (zh) * 1998-07-29 2001-09-05 埃克森化学专利公司 制备分子筛的方法
ES2279105T3 (es) * 2002-03-15 2007-08-16 Exxonmobil Chemical Patents, Inc. Chabacita rica en silice, su sintesis y su utilizacion en la conversion de compuestos oxigenados en olefinas.
JP4777260B2 (ja) * 2003-12-23 2011-09-21 エクソンモービル・ケミカル・パテンツ・インク カバサイトタイプ分子篩、その合成、及びオキシジネートをオレフィンへ変換することにおけるそれらの使用
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
WO2010146156A1 (en) * 2009-06-18 2010-12-23 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
CN102665902A (zh) * 2009-11-24 2012-09-12 巴斯夫欧洲公司 制备具有cha结构的沸石的方法
CN102134081A (zh) * 2010-01-25 2011-07-27 天津海赛纳米材料有限公司 无模板剂存在下一种sapo-34分子筛的合成方法
CN102285666B (zh) * 2010-06-18 2015-02-04 江西师范大学 一种菱沸石及菱沸石膜的制备方法
KR101948254B1 (ko) * 2011-04-18 2019-02-14 피큐 코포레이션 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법
CN102442679B (zh) * 2011-09-29 2013-08-14 南开大学 一种菱沸石的合成方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J. Phys. Chem. C 2011, 115, 744-750 (2010.12.27.) 1부.*

Also Published As

Publication number Publication date
JP6324895B2 (ja) 2018-05-16
ZA201404210B (en) 2015-08-26
CN104039704B (zh) 2017-10-24
BR112014011308B1 (pt) 2021-04-13
PL2776369T3 (pl) 2022-06-20
RU2014123614A (ru) 2015-12-20
WO2013068976A1 (en) 2013-05-16
MX2014005537A (es) 2014-09-16
EP2776369A1 (en) 2014-09-17
EP2776369B1 (en) 2022-02-23
RU2612697C2 (ru) 2017-03-13
MX375064B (es) 2025-03-06
CN104039704A (zh) 2014-09-10
IN2014CN03353A (https=) 2015-07-03
CA2855572A1 (en) 2013-05-16
CA2855572C (en) 2020-04-28
JP2015511919A (ja) 2015-04-23
BR112014011308A2 (pt) 2017-05-09
KR20140093982A (ko) 2014-07-29
EP2776369A4 (en) 2015-08-05

Similar Documents

Publication Publication Date Title
KR102032584B1 (ko) Cha-형 구조의 제올라이트 물질을 생성시키기 위한 무-유기 템플레이트 합성 방법
US9527751B2 (en) Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
KR102108057B1 (ko) Cha-형 제올라이트 물질, 및 사이클로알킬암모늄 화합물을 사용하여 이들을 제조하는 방법
KR102659804B1 (ko) Cha-형 제올라이트 물질 및 사이클로알킬- 및 에틸트라이메틸암모늄 화합물의 조합을 사용하는 이의 제조 방법
KR102410485B1 (ko) Cha 형 제올라이트 물질, 및 사이클로알킬- 및 테트라알킬암모늄 화합물들의 조합물을 사용하여 이를 제조하는 방법
CN103771440B (zh) 直接合成具有CHA结构的含Cu沸石的方法
US9636667B2 (en) CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds
JP5879339B2 (ja) Ｌｅｖ型構造ゼオライト系材料の製造用の有機テンプレート不使用合成方法
US9028795B2 (en) Process for the organotemplate-free synthetic production of a zeolitic material using recycled mother liquor
CN102803143A (zh) 生产沸石材料的无有机模板合成方法
CN104876237A (zh) 生产沸石材料的无有机模板合成方法
JP2013529587A (ja) Ｌｅｖ型構造ゼオライト系材料とその製造方法
CN103068732A (zh) 制备lev型结构的沸石材料的无有机模板合成法

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20140610

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20171109

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20190129

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20190708

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20191008

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20191008

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20220920

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee