KR101969615B1 - 이종 반응 시스템에서 환상 아세탈의 제조 방법 - Google Patents

이종 반응 시스템에서 환상 아세탈의 제조 방법 Download PDF

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KR101969615B1
KR101969615B1 KR1020147017191A KR20147017191A KR101969615B1 KR 101969615 B1 KR101969615 B1 KR 101969615B1 KR 1020147017191 A KR1020147017191 A KR 1020147017191A KR 20147017191 A KR20147017191 A KR 20147017191A KR 101969615 B1 KR101969615 B1 KR 101969615B1
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formaldehyde
compound
source
cyclic acetal
liquid
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KR20140106599A (ko
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미카엘 하웁스
다미안 페오르드
조니
클라우스 쿠르츠
위르겐 링나우
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셀라니즈 세일즈 저머니 게엠베하
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C07D323/04—Six-membered rings
    • C07D323/06—Trioxane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/04—Formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C07D323/04—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/30—Chemical modification by after-treatment
    • C08G2/36—Chemical modification by after-treatment by depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/28—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/62—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the nature of monomer used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C08J2359/02—Copolyoxymethylenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020147017191A 2011-11-24 2012-11-23 이종 반응 시스템에서 환상 아세탈의 제조 방법 Active KR101969615B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP11190586.5 2011-11-24
EP11190586 2011-11-24
EP11190574.1 2011-11-24
EP11190567.5 2011-11-24
EP11190567 2011-11-24
EP11190574 2011-11-24
PCT/EP2012/073543 WO2013076290A1 (en) 2011-11-24 2012-11-23 Process for producing a cyclic acetal in a heterogeneous reaction system

Publications (2)

Publication Number Publication Date
KR20140106599A KR20140106599A (ko) 2014-09-03
KR101969615B1 true KR101969615B1 (ko) 2019-04-16

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KR1020147017191A Active KR101969615B1 (ko) 2011-11-24 2012-11-23 이종 반응 시스템에서 환상 아세탈의 제조 방법
KR1020147017187A Withdrawn KR20140107309A (ko) 2011-11-24 2012-11-23 중합 공정 동안 폼알데하이드 공급원의 재생 방법
KR1020147017142A Withdrawn KR20140102243A (ko) 2011-11-24 2012-11-23 환상 아세탈의 제조 방법
KR1020147017132A Ceased KR20140102241A (ko) 2011-11-24 2012-11-23 수성 폼알데하이드 공급원으로부터 트라이옥산의 제조 방법

Family Applications After (3)

Application Number Title Priority Date Filing Date
KR1020147017187A Withdrawn KR20140107309A (ko) 2011-11-24 2012-11-23 중합 공정 동안 폼알데하이드 공급원의 재생 방법
KR1020147017142A Withdrawn KR20140102243A (ko) 2011-11-24 2012-11-23 환상 아세탈의 제조 방법
KR1020147017132A Ceased KR20140102241A (ko) 2011-11-24 2012-11-23 수성 폼알데하이드 공급원으로부터 트라이옥산의 제조 방법

Country Status (6)

Country Link
US (8) US9574061B2 (https=)
EP (5) EP2782906B1 (https=)
JP (5) JP6192652B2 (https=)
KR (4) KR101969615B1 (https=)
CN (7) CN108164500B (https=)
WO (7) WO2013076291A1 (https=)

Cited By (1)

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KR20200136984A (ko) * 2018-03-29 2020-12-08 셀라니즈 세일즈 저머니 게엠베하 비균질 반응 시스템에서의 환상 아세탈의 제조 방법

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EP2782906B1 (en) * 2011-11-24 2019-05-22 Celanese Sales Germany GmbH Process for producing a cyclic acetal
CN105218513B (zh) * 2014-05-29 2017-12-12 中国石油大学(北京) 一种合成三聚甲醛的方法
FR3024729B1 (fr) * 2014-08-07 2018-09-07 Arkema France Procede de preparation du trioxane
CN104478848B (zh) * 2015-01-09 2016-06-29 开封龙宇化工有限公司 一种三聚甲醛脱轻塔分离器加碱水洗装置及使用方法
CN105175389B (zh) * 2015-09-10 2018-09-07 中国石油大学(北京) 一种利用酸和盐催化甲醛合成三聚甲醛的方法
CN107474037A (zh) * 2017-07-03 2017-12-15 湖北三里枫香科技有限公司 一种多级固定床型三聚甲醛生产工艺方法及制备装置
FR3108909A1 (fr) * 2020-04-07 2021-10-08 Arkema Fance Recyclage de polyacétal pour la production de polyoxyméthylènedialkyléthers
WO2021213663A1 (de) * 2020-04-23 2021-10-28 Wacker Chemie Ag Verfahren zur herstellung von aldehyden aus 1,3,5-trioxanen
CN116323730A (zh) * 2020-08-14 2023-06-23 国际人造丝公司 利用生物质来生产聚甲醛共聚物
CN112724118B (zh) * 2020-12-08 2023-02-28 中国石油大学(华东) 一种石油基塑料pom的生物质醇解方法
US20220380557A1 (en) * 2021-05-20 2022-12-01 Xerox Corporation Polyoxymethylene microparticles and methods of production and use thereof
TW202413339A (zh) * 2022-06-03 2024-04-01 日商三菱瓦斯化學股份有限公司 組成物、及使用其之三噁烷的製造方法
US11643486B1 (en) 2022-06-08 2023-05-09 Arkema Inc. Non-linear vinylidene fluoride copolymers

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200136984A (ko) * 2018-03-29 2020-12-08 셀라니즈 세일즈 저머니 게엠베하 비균질 반응 시스템에서의 환상 아세탈의 제조 방법
KR102812643B1 (ko) 2018-03-29 2025-05-23 셀라니즈 세일즈 저머니 게엠베하 비균질 반응 시스템에서의 환상 아세탈의 제조 방법

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KR20140106599A (ko) 2014-09-03
US9574061B2 (en) 2017-02-21
JP2014534254A (ja) 2014-12-18
US20140316147A1 (en) 2014-10-23
JP6144272B2 (ja) 2017-06-07
CN103958493A (zh) 2014-07-30
JP6192652B2 (ja) 2017-09-06
CN108164500A (zh) 2018-06-15
CN104024240A (zh) 2014-09-03
JP2015500799A (ja) 2015-01-08
EP2782909A1 (en) 2014-10-01
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US9469624B2 (en) 2016-10-18
US20160280882A1 (en) 2016-09-29
US20140323686A1 (en) 2014-10-30
EP2782905A1 (en) 2014-10-01
US20140329988A1 (en) 2014-11-06
US20140350216A1 (en) 2014-11-27
CN103946219B (zh) 2019-10-25
EP2782907B8 (en) 2018-06-27
EP2782906A1 (en) 2014-10-01
EP2782908B1 (en) 2018-07-25
JP6192653B2 (ja) 2017-09-06
CN103946219A (zh) 2014-07-23
KR20140102241A (ko) 2014-08-21
WO2013076286A1 (en) 2013-05-30
WO2013076291A1 (en) 2013-05-30
US9365537B2 (en) 2016-06-14
US20140343302A1 (en) 2014-11-20
CN103958492A (zh) 2014-07-30
CN104105695A (zh) 2014-10-15
JP2014534252A (ja) 2014-12-18
CN106866615A (zh) 2017-06-20
CN106866615B (zh) 2022-01-11
WO2013076287A1 (en) 2013-05-30
KR20140107309A (ko) 2014-09-04
WO2013076289A1 (en) 2013-05-30
JP2014534253A (ja) 2014-12-18
JP2015500894A (ja) 2015-01-08
US9499512B2 (en) 2016-11-22
JP6192650B2 (ja) 2017-09-06
JP6192651B2 (ja) 2017-09-06
CN108164500B (zh) 2024-09-03
US9604956B2 (en) 2017-03-28
WO2013076288A1 (en) 2013-05-30
EP2782905B1 (en) 2020-01-01
US9546148B2 (en) 2017-01-17
CN103958493B (zh) 2018-02-06
EP2782907B1 (en) 2018-04-11
EP2782906B1 (en) 2019-05-22
WO2013076290A1 (en) 2013-05-30
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EP2782907A1 (en) 2014-10-01
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US20140343301A1 (en) 2014-11-20
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