KR101874425B1 - 발수/발유 피막 및 그 제조방법 - Google Patents
발수/발유 피막 및 그 제조방법 Download PDFInfo
- Publication number
- KR101874425B1 KR101874425B1 KR1020167025075A KR20167025075A KR101874425B1 KR 101874425 B1 KR101874425 B1 KR 101874425B1 KR 1020167025075 A KR1020167025075 A KR 1020167025075A KR 20167025075 A KR20167025075 A KR 20167025075A KR 101874425 B1 KR101874425 B1 KR 101874425B1
- Authority
- KR
- South Korea
- Prior art keywords
- repellent
- group
- water
- oil
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000005871 repellent Substances 0.000 claims abstract description 130
- 239000007787 solid Substances 0.000 claims abstract description 31
- 238000000576 coating method Methods 0.000 claims description 42
- 239000007788 liquid Substances 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 40
- 239000002243 precursor Substances 0.000 claims description 33
- 125000003545 alkoxy group Chemical group 0.000 claims description 25
- -1 organosilane compound Chemical class 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims description 15
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 125000000962 organic group Chemical group 0.000 claims description 4
- 239000003586 protic polar solvent Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 38
- 239000003921 oil Substances 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000010935 stainless steel Substances 0.000 description 19
- 229910001220 stainless steel Inorganic materials 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- 239000011521 glass Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 12
- KOKDSALTQSQPDH-UHFFFAOYSA-N 1,3-bis(3-phenoxyphenoxy)benzene Chemical compound C=1C=CC(OC=2C=C(OC=3C=C(OC=4C=CC=CC=4)C=CC=3)C=CC=2)=CC=1OC1=CC=CC=C1 KOKDSALTQSQPDH-UHFFFAOYSA-N 0.000 description 7
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 7
- 230000002940 repellent Effects 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229920001721 polyimide Polymers 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 125000005372 silanol group Chemical group 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 229910000679 solder Inorganic materials 0.000 description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 3
- ARFTWYDDLXMDHX-UHFFFAOYSA-N C[N](C)(COC)O Chemical compound C[N](C)(COC)O ARFTWYDDLXMDHX-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- BAAAEEDPKUHLID-UHFFFAOYSA-N decyl(triethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)OCC BAAAEEDPKUHLID-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 2
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000012643 polycondensation polymerization Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- HJIMAFKWSKZMBK-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HJIMAFKWSKZMBK-UHFFFAOYSA-N 0.000 description 1
- 244000020998 Acacia farnesiana Species 0.000 description 1
- 235000010643 Leucaena leucocephala Nutrition 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007611 bar coating method Methods 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Paints Or Removers (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014032316A JP6346456B2 (ja) | 2013-02-22 | 2014-02-21 | 撥水/撥油皮膜及びその製造方法 |
| JPJP-P-2014-032316 | 2014-02-21 | ||
| PCT/JP2015/054626 WO2015125866A1 (ja) | 2014-02-21 | 2015-02-19 | 撥水/撥油皮膜及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20160122211A KR20160122211A (ko) | 2016-10-21 |
| KR101874425B1 true KR101874425B1 (ko) | 2018-07-04 |
Family
ID=53879266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167025075A Active KR101874425B1 (ko) | 2014-02-21 | 2015-02-19 | 발수/발유 피막 및 그 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10138380B2 (enExample) |
| EP (1) | EP3109290A4 (enExample) |
| JP (1) | JP6346456B2 (enExample) |
| KR (1) | KR101874425B1 (enExample) |
| CN (1) | CN106029818B (enExample) |
| WO (1) | WO2015125866A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6715531B2 (ja) | 2014-10-31 | 2020-07-01 | 住友化学株式会社 | 透明皮膜 |
| US10370546B2 (en) | 2014-10-31 | 2019-08-06 | Sumitomo Chemical Company, Limited | Water/oil-repellent coating composition |
| WO2016068138A1 (ja) * | 2014-10-31 | 2016-05-06 | 住友化学株式会社 | 透明皮膜 |
| KR102478714B1 (ko) | 2014-11-12 | 2022-12-16 | 스미또모 가가꾸 가부시키가이샤 | 발수 발유 코팅 조성물 및 투명 피막 |
| CN107075306B (zh) | 2014-11-12 | 2020-03-17 | 住友化学株式会社 | 透明被膜 |
| JP6710049B2 (ja) * | 2016-01-12 | 2020-06-17 | 住友化学株式会社 | 含フッ素皮膜及び撥水撥油コーティング組成物 |
| TWI712682B (zh) * | 2016-04-28 | 2020-12-11 | 日商住友化學股份有限公司 | 被膜 |
| WO2017188329A1 (ja) * | 2016-04-28 | 2017-11-02 | 住友化学株式会社 | 組成物 |
| US11981828B2 (en) | 2018-06-04 | 2024-05-14 | Toagosei Co. Ltd. | Water repellent and oil repellent film composition and use thereof |
| CN110857334A (zh) * | 2018-08-23 | 2020-03-03 | 香港城市大学深圳研究院 | 具有拒油性的耐溶剂的聚二甲基硅氧烷聚合物及其生产方法 |
| EP4190883A4 (en) | 2020-07-30 | 2024-09-04 | Kao Corporation | Lubricant |
| CN111961332A (zh) * | 2020-08-30 | 2020-11-20 | 宁波耀众模塑科技有限公司 | 一种拒油效果好的聚氨酯发泡产品配方 |
| FR3159608A1 (fr) * | 2024-02-28 | 2025-08-29 | Seb S.A. | Finish sol-gel sans silice avec TMMS ou TMES |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010248468A (ja) | 2009-03-25 | 2010-11-04 | Panasonic Electric Works Co Ltd | 撥水撥油樹脂組成物および塗装品 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2397895A (en) * | 1945-02-14 | 1946-04-02 | Corning Glass Works | Organo-siloxanes and methods of preparing them |
| US3450672A (en) * | 1967-01-12 | 1969-06-17 | Gen Electric | Organosilsesquioxanes and a method for making them |
| US3634321A (en) * | 1969-07-28 | 1972-01-11 | Owens Illinois Inc | Methods of making solid organopolysiloxanes |
| US4322476A (en) * | 1979-12-12 | 1982-03-30 | General Electric Company | Impact resistant laminate |
| US4895286A (en) * | 1988-09-29 | 1990-01-23 | Derosa James V | Camera support |
| FR2674862B1 (fr) * | 1991-04-05 | 1994-09-09 | Corning France | Composition et procede de traitement d'articles pour leur conferer des proprietes durables d'anti-adherence et de repulsion d'eau. |
| JPH0632991A (ja) | 1992-07-10 | 1994-02-08 | Kanebo Ltd | 改質粉体及び改質粉体を配合した化粧料 |
| JP3599358B2 (ja) | 1993-08-06 | 2004-12-08 | ジーイー東芝シリコーン株式会社 | コーティング用組成物 |
| JP3193818B2 (ja) * | 1993-12-08 | 2001-07-30 | シャープ株式会社 | 防水処理されたセラミックヒータ |
| JPH09157636A (ja) * | 1995-12-11 | 1997-06-17 | Hiroaki Hayashi | 表面処理剤およびその製造方法 |
| DE69827856T2 (de) | 1997-03-21 | 2005-11-03 | Canon K.K. | Verfahren zur Herstellung eines bedruckten Substrats |
| JPH1192714A (ja) * | 1997-09-25 | 1999-04-06 | Toshiba Silicone Co Ltd | コーティング剤組成物 |
| JP3013337B2 (ja) * | 1998-02-02 | 2000-02-28 | 松下電器産業株式会社 | パターン形成方法 |
| JP3300940B2 (ja) * | 1998-06-30 | 2002-07-08 | 昭和電工株式会社 | 光触媒皮膜用下地膜の形成方法 |
| JP2000080354A (ja) * | 1998-09-03 | 2000-03-21 | Ge Toshiba Silicones Co Ltd | 防錆・耐汚染性保護コーティング剤組成物 |
| JP2000182513A (ja) * | 1998-12-16 | 2000-06-30 | Canon Inc | 電子放出素子、電子源、画像形成装置及びそれらの製造方法 |
| JP2000195415A (ja) * | 1998-12-25 | 2000-07-14 | Canon Inc | 電子放出素子、電子源、画像形成装置及びそれらの製造方法 |
| US6743516B2 (en) * | 2000-09-29 | 2004-06-01 | Guardian Industries Corporation | Highly durable hydrophobic coatings and methods |
| TWI282349B (en) | 2003-01-24 | 2007-06-11 | Shinetsu Chemical Co | Silicone composition and paper treatment agent including the same |
| JP4530255B2 (ja) * | 2003-10-16 | 2010-08-25 | 信越化学工業株式会社 | 水分散型撥水撥油剤及びそれを用いた撥水撥油紙及びシート |
| MY151065A (en) * | 2003-02-25 | 2014-03-31 | Kaneka Corp | Curing composition and method for preparing same, light-shielding paste, light-shielding resin and method for producing same, package for light-emitting diode, and semiconductor device |
| AU2003901735A0 (en) * | 2003-04-11 | 2003-05-01 | Unisearch Limited | Durable superhydrophobic coating |
| WO2004113456A2 (en) * | 2003-06-23 | 2004-12-29 | University Of Zurich | Superhydrophobic coating |
| US7351477B2 (en) | 2004-04-07 | 2008-04-01 | Shin-Etsu Chemical Co., Ltd. | Antifouling coating compositions and coated articles |
| US20080090004A1 (en) * | 2004-10-05 | 2008-04-17 | Hua Zhang | Hydrophobic and Lyophobic Coating |
| US20070141305A1 (en) * | 2005-12-21 | 2007-06-21 | Toshihiro Kasai | Superhydrophobic coating |
| JP5553304B2 (ja) | 2009-02-27 | 2014-07-16 | 独立行政法人産業技術総合研究所 | 固体表面の改質方法及び表面改質された基材 |
| JP5368951B2 (ja) * | 2009-11-25 | 2013-12-18 | パナソニック株式会社 | 撥水撥油性樹脂組成物及び塗装品 |
| JP2012017394A (ja) * | 2010-07-07 | 2012-01-26 | Central Glass Co Ltd | 防曇性物品 |
| JP2012214588A (ja) * | 2011-03-31 | 2012-11-08 | Panasonic Corp | 撥水撥油性樹脂組成物及び塗装品 |
| WO2012137977A1 (ja) * | 2011-04-08 | 2012-10-11 | 東レ・ダウコーニング株式会社 | 被膜形成用組成物 |
| WO2012137976A1 (ja) * | 2011-04-08 | 2012-10-11 | 東レ・ダウコーニング株式会社 | 被膜形成用組成物 |
| JP5481653B2 (ja) * | 2013-02-07 | 2014-04-23 | 国立大学法人弘前大学 | ナノコンポジット、ナノ分散液、その製造方法及び該分散液からなる各種剤 |
| JP2013173939A (ja) * | 2013-04-11 | 2013-09-05 | Kazufumi Ogawa | 表面に微細な凸凹を有する撥水撥油防汚膜が形成された物品および製品とそれらの製造方法 |
-
2014
- 2014-02-21 JP JP2014032316A patent/JP6346456B2/ja active Active
-
2015
- 2015-02-19 KR KR1020167025075A patent/KR101874425B1/ko active Active
- 2015-02-19 CN CN201580009221.8A patent/CN106029818B/zh active Active
- 2015-02-19 EP EP15751325.0A patent/EP3109290A4/en not_active Ceased
- 2015-02-19 US US15/119,437 patent/US10138380B2/en active Active
- 2015-02-19 WO PCT/JP2015/054626 patent/WO2015125866A1/ja not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010248468A (ja) | 2009-03-25 | 2010-11-04 | Panasonic Electric Works Co Ltd | 撥水撥油樹脂組成物および塗装品 |
Also Published As
| Publication number | Publication date |
|---|---|
| US10138380B2 (en) | 2018-11-27 |
| CN106029818B (zh) | 2018-05-22 |
| EP3109290A1 (en) | 2016-12-28 |
| JP2014185334A (ja) | 2014-10-02 |
| JP6346456B2 (ja) | 2018-06-20 |
| US20170015842A1 (en) | 2017-01-19 |
| KR20160122211A (ko) | 2016-10-21 |
| CN106029818A (zh) | 2016-10-12 |
| WO2015125866A1 (ja) | 2015-08-27 |
| EP3109290A4 (en) | 2017-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101874425B1 (ko) | 발수/발유 피막 및 그 제조방법 | |
| US8925626B2 (en) | Composition for forming film | |
| JP6557248B2 (ja) | 疎水性物品 | |
| CN110268025B (zh) | 用于形成膜的液体组合物和其制造方法 | |
| WO1999063022A1 (en) | Process for producing article coated with water-repellent film, article coated with water-repellent film, and liquid composition for water-repellent film coating | |
| Urata et al. | A thermally stable, durable and temperature-dependent oleophobic surface of a polymethylsilsesquioxane film | |
| WO2013061747A1 (ja) | 被膜付き基板の製造方法 | |
| WO2012081524A1 (ja) | 含フッ素化合物、コーティング用組成物、撥水層付き基材およびその製造方法 | |
| JP2017186495A (ja) | 難着霜性、難結露性、難着氷性を有する低温環境用部材 | |
| JP7047927B2 (ja) | 平坦化膜形成用塗布液、平坦化膜形成用塗布液の製造方法、平坦化膜付き金属箔、及び平坦化膜付き金属箔の製造方法 | |
| TWI716384B (zh) | 用於光電應用中之聚矽氧烷調配物及塗層 | |
| US20150141571A1 (en) | Water-repellent and oil-repellent coating, and formation method thereof | |
| WO2017159867A1 (ja) | 被膜 | |
| Menaa et al. | Preparation and properties of polyphenylsiloxane-based hybrid glass films obtained from a non-aqueous coating sol via a single-step dip-coating | |
| JP2013111500A (ja) | 表面処理方法 | |
| JP2011006653A (ja) | 硬化被膜付き基材 | |
| JP7177889B2 (ja) | 膜形成用液組成物 | |
| Liu et al. | An ultra-slippery transparent coating with waterproofing and heat dissipation functions for electronic devices | |
| JPWO2020137990A1 (ja) | 蒸着材料、下地層付き基材の製造方法、撥水撥油層付き基材の製造方法 | |
| JP6103704B2 (ja) | 撥水/撥油皮膜 | |
| JP4484492B2 (ja) | 溶射被膜用コーティング剤 | |
| JP2023105900A (ja) | フッ素化膜を備えたフッ素化構造体、該構造体の製造方法、及び該構造体の製造に用いる前駆溶液 | |
| JP2006241304A (ja) | 膜形成用組成物、絶縁膜およびその製造方法 | |
| JP2013144629A (ja) | シリカ膜の形成方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| PA0105 | International application |
Patent event date: 20160909 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20160909 Comment text: Request for Examination of Application |
|
| PG1501 | Laying open of application | ||
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20171213 Patent event code: PE09021S01D |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 20180607 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20180628 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20180629 End annual number: 3 Start annual number: 1 |
|
| PG1601 | Publication of registration | ||
| PR1001 | Payment of annual fee |
Payment date: 20210413 Start annual number: 4 End annual number: 4 |
|
| PR1001 | Payment of annual fee |
Payment date: 20230413 Start annual number: 6 End annual number: 6 |
|
| PR1001 | Payment of annual fee |
Payment date: 20240415 Start annual number: 7 End annual number: 7 |
|
| PR1001 | Payment of annual fee |
Payment date: 20250414 Start annual number: 8 End annual number: 8 |