KR101751574B1 - 리튬 이차 전지용 음극 활물질, 이의 제조 방법, 이를 포함하는 리튬 이차 전지용 음극, 및 리튬 이차 전지 - Google Patents
리튬 이차 전지용 음극 활물질, 이의 제조 방법, 이를 포함하는 리튬 이차 전지용 음극, 및 리튬 이차 전지 Download PDFInfo
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- KR101751574B1 KR101751574B1 KR1020140131018A KR20140131018A KR101751574B1 KR 101751574 B1 KR101751574 B1 KR 101751574B1 KR 1020140131018 A KR1020140131018 A KR 1020140131018A KR 20140131018 A KR20140131018 A KR 20140131018A KR 101751574 B1 KR101751574 B1 KR 101751574B1
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- Prior art keywords
- acid
- active material
- core
- lithium
- negative electrode
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 65
- 239000007773 negative electrode material Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims description 19
- 239000010936 titanium Substances 0.000 claims abstract description 27
- FDLZQPXZHIFURF-UHFFFAOYSA-N [O-2].[Ti+4].[Li+] Chemical compound [O-2].[Ti+4].[Li+] FDLZQPXZHIFURF-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 9
- 150000007524 organic acids Chemical class 0.000 claims description 36
- 150000008065 acid anhydrides Chemical class 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 125000000524 functional group Chemical group 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 17
- 239000011247 coating layer Substances 0.000 claims description 16
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
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- C01D15/02—Oxides; Hydroxides
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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- C01G23/003—Titanates
- C01G23/005—Alkali titanates
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/56—After-treatment
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- H01M10/05—Accumulators with non-aqueous electrolyte
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- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- C01P2006/00—Physical properties of inorganic compounds
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- C—CHEMISTRY; METALLURGY
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
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- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
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| PCT/KR2015/010003 WO2016052910A1 (ko) | 2014-09-30 | 2015-09-23 | 리튬이차전지용 음극 활물질, 이의 제조 방법, 이를 포함하는 리튬이차전지용 음극, 및 리튬이차전지 |
| CN201580004074.5A CN105917497B (zh) | 2014-09-30 | 2015-09-23 | 锂二次电池用负极活性材料、其制造方法、包含其的锂二次电池用负极和锂二次电池 |
| PL15847257T PL3054506T3 (pl) | 2014-09-30 | 2015-09-23 | Materiał czynny anody dla litowej baterii akumulatorowej, sposób jego wytwarzania oraz litowa bateria akumulatorowa zawierająca ten materiał |
| JP2016535090A JP6563923B2 (ja) | 2014-09-30 | 2015-09-23 | リチウム二次電池用負極活物質、その製造方法、それを含むリチウム二次電池用負極、及びリチウム二次電池 |
| EP15847257.1A EP3054506B1 (en) | 2014-09-30 | 2015-09-23 | Anode active material for lithium secondary battery, manufacturing method therefor, lithium secondary battery comprising the same |
| US15/032,396 US10205169B2 (en) | 2014-09-30 | 2015-09-23 | Anode active material for lithium secondary battery, manufacturing method there-for, anode for lithium secondary battery comprising same, and lithium secondary battery |
| TW104131797A TWI565129B (zh) | 2014-09-30 | 2015-09-25 | 可充電鋰電池之負活性材料、製備彼之方法及包含彼之可充電鋰電池 |
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| WO2018003929A1 (ja) * | 2016-06-30 | 2018-01-04 | 宇部興産株式会社 | 蓄電デバイスの電極用チタン酸リチウム粉末および活物質材料、並びにそれを用いた電極シートおよび蓄電デバイス |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| JP6722388B2 (ja) * | 2017-06-22 | 2020-07-15 | トヨタ自動車株式会社 | 非水電解液二次電池 |
| JP6905671B2 (ja) * | 2018-03-20 | 2021-07-21 | トヨタ自動車株式会社 | 非水電解質リチウム二次電池用正極の製造方法 |
| WO2019198146A1 (ja) * | 2018-04-10 | 2019-10-17 | 株式会社 東芝 | 電極群、非水電解質電池及び電池パック |
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| JP2011146154A (ja) * | 2010-01-12 | 2011-07-28 | Toyota Motor Corp | 負極ペーストの製造方法、負極板の製造方法、及び、リチウム二次電池の製造方法 |
| KR101243906B1 (ko) | 2010-06-21 | 2013-03-14 | 삼성에스디아이 주식회사 | 리튬 전지 및 상기 리튬 전지의 제조 방법 |
| KR101244417B1 (ko) * | 2010-12-23 | 2013-03-18 | 한국기초과학지원연구원 | 탄소를 함유하는 리튬 2차 전지용 리튬티타늄산화물 전극재료 및 이의 제조방법 |
| JP5652313B2 (ja) * | 2011-04-28 | 2015-01-14 | 日本ゼオン株式会社 | リチウム二次電池用負極スラリー組成物、リチウム二次電池用負極の製造方法、リチウム二次電池用負極及びリチウム二次電池 |
| JP5919942B2 (ja) * | 2011-06-02 | 2016-05-18 | 日産自動車株式会社 | 正極活物質および電極の製造方法、ならびに電極 |
| JP5694208B2 (ja) * | 2012-01-19 | 2015-04-01 | 株式会社東芝 | 非水電解質電池用負極活物質及びその製造方法、非水電解質電池および電池パック |
| KR101375611B1 (ko) * | 2012-03-20 | 2014-03-18 | 한국세라믹기술원 | 리튬티타늄산화물 음극 활물질의 제조방법 |
| CN104380504B (zh) | 2012-07-10 | 2016-11-16 | 株式会社Lg化学 | 二次电池用负极及包含其的二次电池 |
| JP2014075238A (ja) * | 2012-10-03 | 2014-04-24 | Kaneka Corp | 非水電解質二次電池用負極活物質及びその製造方法並びに非水電解質二次電池 |
| US9059451B2 (en) | 2012-10-18 | 2015-06-16 | GM Global Technology Operations LLC | Coatings for lithium titanate to suppress gas generation in lithium-ion batteries and methods for making and use thereof |
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2014
- 2014-09-30 KR KR1020140131018A patent/KR101751574B1/ko active Active
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2015
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- 2015-09-23 CN CN201580004074.5A patent/CN105917497B/zh active Active
- 2015-09-23 US US15/032,396 patent/US10205169B2/en active Active
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| EP3054506B1 (en) | 2018-09-12 |
| EP3054506A4 (en) | 2016-12-14 |
| CN105917497B (zh) | 2018-12-11 |
| CN105917497A (zh) | 2016-08-31 |
| EP3054506A1 (en) | 2016-08-10 |
| KR20160038339A (ko) | 2016-04-07 |
| JP6563923B2 (ja) | 2019-08-21 |
| TW201628238A (zh) | 2016-08-01 |
| JP2017530499A (ja) | 2017-10-12 |
| US10205169B2 (en) | 2019-02-12 |
| PL3054506T3 (pl) | 2019-02-28 |
| WO2016052910A1 (ko) | 2016-04-07 |
| US20160276672A1 (en) | 2016-09-22 |
| TWI565129B (zh) | 2017-01-01 |
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