KR101703378B1 - 액체 수지 주입 이용분야를 위한 변형 수지계 및 이와 관련된 공정 방법 - Google Patents
액체 수지 주입 이용분야를 위한 변형 수지계 및 이와 관련된 공정 방법 Download PDFInfo
- Publication number
- KR101703378B1 KR101703378B1 KR1020127018919A KR20127018919A KR101703378B1 KR 101703378 B1 KR101703378 B1 KR 101703378B1 KR 1020127018919 A KR1020127018919 A KR 1020127018919A KR 20127018919 A KR20127018919 A KR 20127018919A KR 101703378 B1 KR101703378 B1 KR 101703378B1
- Authority
- KR
- South Korea
- Prior art keywords
- resin
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- thermoplastic material
- core
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
- B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
- B29C70/025—Combinations of fibrous reinforcement and non-fibrous material with particular filler
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
- B29C70/443—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding and impregnating by vacuum or injection
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/04—Polyadducts obtained by the diene synthesis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
- B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Inorganic Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0922599.6 | 2009-12-23 | ||
| GB0922599A GB0922599D0 (en) | 2009-12-23 | 2009-12-23 | Modified resin systems for liquid resin infusion applications, prepreg autoclave applications and hybrids thereof |
| PCT/GB2010/002324 WO2011077094A1 (en) | 2009-12-23 | 2010-12-22 | Modified resin systems for liquid resin infusion applications & process methods related thereto |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120108002A KR20120108002A (ko) | 2012-10-04 |
| KR101703378B1 true KR101703378B1 (ko) | 2017-02-06 |
Family
ID=41716940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127018919A Expired - Fee Related KR101703378B1 (ko) | 2009-12-23 | 2010-12-22 | 액체 수지 주입 이용분야를 위한 변형 수지계 및 이와 관련된 공정 방법 |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20110151232A1 (enExample) |
| EP (1) | EP2516139B1 (enExample) |
| JP (1) | JP5808057B2 (enExample) |
| KR (1) | KR101703378B1 (enExample) |
| CN (1) | CN103025508B (enExample) |
| AU (1) | AU2010334587B2 (enExample) |
| BR (1) | BR112012014186B1 (enExample) |
| CA (1) | CA2785279C (enExample) |
| ES (1) | ES2576133T3 (enExample) |
| GB (1) | GB0922599D0 (enExample) |
| MY (1) | MY160836A (enExample) |
| TW (1) | TWI517966B (enExample) |
| WO (1) | WO2011077094A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2817201C (en) * | 2010-11-09 | 2017-11-07 | Cytec Technology Corp. | Compatible carrier for secondary toughening |
| US9879722B2 (en) * | 2013-03-11 | 2018-01-30 | Bell Helicopter Textron Inc. | Low shear modulus transition shim for elastomeric bearing bonding in torsional applications |
| EP3233438B1 (en) * | 2014-12-18 | 2021-02-17 | Cytec Industries Inc. | Modified resin systems suitable for liquid resin infusion |
| AU2016304854A1 (en) * | 2015-08-10 | 2018-02-22 | Cytec Industries Inc. | Prepreg material capable of providing lightning strike protection and burn-through resistance |
| CN108367512B (zh) * | 2015-12-16 | 2021-05-28 | 塞特工业公司 | 用于制造纤维增强复合材料的树脂灌注方法 |
| ES2953445T3 (es) * | 2016-01-20 | 2023-11-13 | Zephyros Inc | Materiales epoxi termoplásticos con fase de núcleo-envoltura |
| JP6354884B1 (ja) * | 2017-03-13 | 2018-07-11 | 横浜ゴム株式会社 | シアネートエステル樹脂組成物およびプリプレグ |
| CN107263887A (zh) * | 2017-07-04 | 2017-10-20 | 西安飞机工业(集团)有限责任公司 | 一种真空辅助定位装置及定位方法 |
| GB201717639D0 (en) * | 2017-10-26 | 2017-12-13 | Cytec Ind Inc | Resin compositions and resin infusion process |
| CN109986813A (zh) * | 2017-12-29 | 2019-07-09 | 北京金风科创风电设备有限公司 | 风力发电机组叶片内、外补强模具及其制备方法 |
| US12091479B2 (en) | 2018-07-06 | 2024-09-17 | Toray Industries, Inc. | Epoxy resin composition for fiber-reinforced composite material, fiber-reinforced composite material, and production method thereof |
| WO2021157442A1 (ja) | 2020-02-03 | 2021-08-12 | 東レ株式会社 | 成形材料および繊維強化複合材料 |
| US20230091746A1 (en) * | 2020-02-21 | 2023-03-23 | Huntsman Advanced Materials Americas Llc | Toughened thermoset resin compositions |
| WO2022040125A1 (en) * | 2020-08-17 | 2022-02-24 | Huntsman Advanced Materials Americas Llc | Thermoset resin compositions |
| US11930565B1 (en) * | 2021-02-05 | 2024-03-12 | Mainstream Engineering Corporation | Carbon nanotube heater composite tooling apparatus and method of use |
| US20240117130A1 (en) | 2021-02-18 | 2024-04-11 | Toray Industries, Inc. | Epoxy resin composition for fiber-reinforced composite material, fiber-reinforced composite material, and method for producing fiber-reinforced composite material |
| JPWO2023176935A1 (enExample) | 2022-03-17 | 2023-09-21 | ||
| WO2023176934A1 (ja) | 2022-03-17 | 2023-09-21 | 東レ株式会社 | エポキシ樹脂組成物、繊維強化複合材料およびその製造方法 |
| CN117362928A (zh) * | 2023-10-20 | 2024-01-09 | 华东理工大学华昌聚合物有限公司 | 一种单组份液体成型环氧树脂组合物及其制备方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3035310A (en) * | 1956-01-23 | 1962-05-22 | Republic Aviat Corp | Method of making reinforced synthetic resin forming tool |
| US4656208A (en) * | 1985-02-19 | 1987-04-07 | Hercules Incorporated | Thermosetting epoxy resin compositions and thermosets therefrom |
| WO1987000188A1 (en) * | 1985-06-26 | 1987-01-15 | The Dow Chemical Company | Rubber-modified epoxy compounds |
| DE69027295T2 (de) * | 1990-01-19 | 1997-01-23 | Minnesota Mining & Mfg | Wärmehärtbare Zusammensetzung |
| US5266610A (en) * | 1991-03-11 | 1993-11-30 | Ici Composites Inc. | Toughened cocontinuous resin system |
| ES2183802T3 (es) * | 1991-07-30 | 2003-04-01 | Cytec Tech Corp | Materiales preimpregnados de matrices de resina termofraguada, reforzados con fibra y endurecidos, y los compuestos de los mismos. |
| GB9616455D0 (en) * | 1996-08-05 | 1996-09-25 | Short Brothers Plc | Apparatus and method for forming a fibre reinforced resin composite component |
| FR2753978B1 (fr) * | 1996-09-30 | 1999-05-14 | Inst Francais Du Petrole | Composition thermodurcissable, ses utilisations et preforme souple depliable comprenant cette composition |
| CN1103350C (zh) * | 1999-06-11 | 2003-03-19 | 中国科学院化学研究所 | 一种环氧树脂复合物及其制备方法 |
| US6537470B1 (en) * | 2000-09-01 | 2003-03-25 | Honeywell International Inc. | Rapid densification of porous bodies (preforms) with high viscosity resins or pitches using a resin transfer molding process |
| GB2401081B (en) * | 2000-10-03 | 2005-06-01 | Structural Polymer Systems Ltd | Moulding material |
| JP3874108B2 (ja) * | 2002-08-13 | 2007-01-31 | 信越化学工業株式会社 | エポキシ樹脂組成物 |
| EP1899148A4 (en) * | 2005-07-05 | 2011-06-08 | Quickstep Technologies Pty Ltd | FLUID DENSITY AND PRINTING METHOD FOR PRODUCING COMPOSITE COMPONENTS |
| KR101303246B1 (ko) * | 2005-08-24 | 2013-09-06 | 헨켈 아일랜드 리미티드 | 개선된 내충격성을 갖는 에폭시 조성물 |
| JP4983228B2 (ja) * | 2005-11-29 | 2012-07-25 | 味の素株式会社 | 多層プリント配線板の絶縁層用樹脂組成物 |
| GB0619401D0 (en) * | 2006-10-02 | 2006-11-08 | Hexcel Composites Ltd | Composite materials with improved performance |
| ES2365573T3 (es) * | 2007-04-17 | 2011-10-07 | Hexcel Corporation | Materiales compuestos preimpregnados con rendimiento mejorado. |
| BRPI0809295B1 (pt) * | 2007-04-17 | 2018-10-16 | Hexcel Corp | material compósito pré-impregnado para curar em uma temperatura de cura entre 140 ºc e 200 ºc, parte do compósito que compreende um material compósito pré-impregnado e métodos para produzir os mesmos |
| GB0717507D0 (en) | 2007-09-07 | 2007-10-17 | Cytec Tech Corp | Composite materials and their use |
| GB2460050A (en) * | 2008-05-14 | 2009-11-18 | Hexcel Composites Ltd | Epoxy composite |
| GB2464085A (en) * | 2008-06-07 | 2010-04-07 | Hexcel Composites Ltd | Improved Conductivity of Resin Materials and Composite Materials |
| US8518208B2 (en) * | 2009-08-31 | 2013-08-27 | Cytec Technology Corp. | High performance adhesive compositions |
-
2009
- 2009-12-23 GB GB0922599A patent/GB0922599D0/en not_active Ceased
-
2010
- 2010-12-09 US US12/963,823 patent/US20110151232A1/en not_active Abandoned
- 2010-12-22 CN CN201080059036.7A patent/CN103025508B/zh active Active
- 2010-12-22 EP EP10799119.2A patent/EP2516139B1/en active Active
- 2010-12-22 AU AU2010334587A patent/AU2010334587B2/en not_active Ceased
- 2010-12-22 WO PCT/GB2010/002324 patent/WO2011077094A1/en not_active Ceased
- 2010-12-22 TW TW099145371A patent/TWI517966B/zh not_active IP Right Cessation
- 2010-12-22 KR KR1020127018919A patent/KR101703378B1/ko not_active Expired - Fee Related
- 2010-12-22 CA CA2785279A patent/CA2785279C/en active Active
- 2010-12-22 JP JP2012545433A patent/JP5808057B2/ja active Active
- 2010-12-22 BR BR112012014186-4A patent/BR112012014186B1/pt not_active IP Right Cessation
- 2010-12-22 MY MYPI2012002370A patent/MY160836A/en unknown
- 2010-12-22 ES ES10799119.2T patent/ES2576133T3/es active Active
-
2017
- 2017-07-18 US US15/653,098 patent/US10836118B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MY160836A (en) | 2017-03-31 |
| CN103025508A (zh) | 2013-04-03 |
| TW201136752A (en) | 2011-11-01 |
| AU2010334587B2 (en) | 2014-10-09 |
| CA2785279A1 (en) | 2011-06-30 |
| EP2516139A1 (en) | 2012-10-31 |
| US10836118B2 (en) | 2020-11-17 |
| JP5808057B2 (ja) | 2015-11-10 |
| CN103025508B (zh) | 2015-11-25 |
| JP2013515806A (ja) | 2013-05-09 |
| BR112012014186A2 (pt) | 2016-05-31 |
| BR112012014186B1 (pt) | 2019-10-08 |
| WO2011077094A1 (en) | 2011-06-30 |
| TWI517966B (zh) | 2016-01-21 |
| WO2011077094A9 (en) | 2012-12-13 |
| ES2576133T3 (es) | 2016-07-05 |
| US20170326819A1 (en) | 2017-11-16 |
| GB0922599D0 (en) | 2010-02-10 |
| CA2785279C (en) | 2017-09-05 |
| KR20120108002A (ko) | 2012-10-04 |
| US20110151232A1 (en) | 2011-06-23 |
| EP2516139B1 (en) | 2016-03-16 |
| AU2010334587A1 (en) | 2012-06-07 |
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