CN103025508B - 液态树脂注入用的改性树脂体系及其加工方法 - Google Patents

液态树脂注入用的改性树脂体系及其加工方法 Download PDF

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Publication number
CN103025508B
CN103025508B CN201080059036.7A CN201080059036A CN103025508B CN 103025508 B CN103025508 B CN 103025508B CN 201080059036 A CN201080059036 A CN 201080059036A CN 103025508 B CN103025508 B CN 103025508B
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resin
modified resin
thermoplastic material
particles
modified
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CN103025508A (zh
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J·E·米根
R·布莱克本
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Cytec Technology Corp
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Cytec Technology Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
    • B29C70/025—Combinations of fibrous reinforcement and non-fibrous material with particular filler
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • B29C70/443—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding and impregnating by vacuum or injection
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/04—Polyadducts obtained by the diene synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Inorganic Chemistry (AREA)
CN201080059036.7A 2009-12-23 2010-12-22 液态树脂注入用的改性树脂体系及其加工方法 Active CN103025508B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0922599.6 2009-12-23
GB0922599A GB0922599D0 (en) 2009-12-23 2009-12-23 Modified resin systems for liquid resin infusion applications, prepreg autoclave applications and hybrids thereof
PCT/GB2010/002324 WO2011077094A1 (en) 2009-12-23 2010-12-22 Modified resin systems for liquid resin infusion applications & process methods related thereto

Publications (2)

Publication Number Publication Date
CN103025508A CN103025508A (zh) 2013-04-03
CN103025508B true CN103025508B (zh) 2015-11-25

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Country Status (13)

Country Link
US (2) US20110151232A1 (enExample)
EP (1) EP2516139B1 (enExample)
JP (1) JP5808057B2 (enExample)
KR (1) KR101703378B1 (enExample)
CN (1) CN103025508B (enExample)
AU (1) AU2010334587B2 (enExample)
BR (1) BR112012014186B1 (enExample)
CA (1) CA2785279C (enExample)
ES (1) ES2576133T3 (enExample)
GB (1) GB0922599D0 (enExample)
MY (1) MY160836A (enExample)
TW (1) TWI517966B (enExample)
WO (1) WO2011077094A1 (enExample)

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US9879722B2 (en) * 2013-03-11 2018-01-30 Bell Helicopter Textron Inc. Low shear modulus transition shim for elastomeric bearing bonding in torsional applications
BR112017012644B1 (pt) * 2014-12-18 2022-04-19 Cytec Industries Inc Processo de fabricação para produzir um artigo moldado por infusão de resina líquida, composição curável, artigo moldado curado, e, uso de uma composição curável
AU2016304854A1 (en) 2015-08-10 2018-02-22 Cytec Industries Inc. Prepreg material capable of providing lightning strike protection and burn-through resistance
AU2016370863B2 (en) * 2015-12-16 2022-01-13 Cytec Industries Inc. Resin infusion process for manufacturing fiber-reinforced composites
CN108495748A (zh) 2016-01-20 2018-09-04 泽费罗斯股份有限公司 具有核壳相的热塑性环氧材料
JP6354884B1 (ja) * 2017-03-13 2018-07-11 横浜ゴム株式会社 シアネートエステル樹脂組成物およびプリプレグ
CN107263887A (zh) * 2017-07-04 2017-10-20 西安飞机工业（集团）有限责任公司 一种真空辅助定位装置及定位方法
GB201717639D0 (en) * 2017-10-26 2017-12-13 Cytec Ind Inc Resin compositions and resin infusion process
CN109986813A (zh) * 2017-12-29 2019-07-09 北京金风科创风电设备有限公司 风力发电机组叶片内、外补强模具及其制备方法
JP7247888B2 (ja) 2018-07-06 2023-03-29 東レ株式会社 繊維強化複合材料用エポキシ樹脂組成物、および繊維強化複合材料ならびにその製造方法
JP7694381B2 (ja) 2020-02-03 2025-06-18 東レ株式会社 成形材料および繊維強化複合材料
JP7719786B2 (ja) * 2020-02-21 2025-08-06 ハンツマン・アドバンスド・マテリアルズ・アメリカズ・エルエルシー 高靭化熱硬化性樹脂組成物
US20230303822A1 (en) * 2020-08-17 2023-09-28 Huntsman Advanced Materials Americas Llc Thermoset Resin Compositions
US11930565B1 (en) * 2021-02-05 2024-03-12 Mainstream Engineering Corporation Carbon nanotube heater composite tooling apparatus and method of use
WO2022176773A1 (ja) 2021-02-18 2022-08-25 東レ株式会社 繊維強化複合材料用エポキシ樹脂組成物、繊維強化複合材料、および繊維強化複合材料の製造方法
AU2023235727A1 (en) 2022-03-17 2024-09-26 Toray Industries, Inc. Epoxy resin composition for resin transfer molding, cured resin product, fiber-reinforced composite material, and method for manufacturing same
US20250188267A1 (en) 2022-03-17 2025-06-12 Toray Industries, Inc. Epoxy resin composition, fiber-reinforced composite material, and production method thereof
CN117362928A (zh) * 2023-10-20 2024-01-09 华东理工大学华昌聚合物有限公司 一种单组份液体成型环氧树脂组合物及其制备方法

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CN101242947A (zh) * 2005-07-05 2008-08-13 快步科技私人有限公司 利用流体密度和压力生产复合材料部件

Also Published As

Publication number Publication date
AU2010334587B2 (en) 2014-10-09
EP2516139A1 (en) 2012-10-31
CA2785279A1 (en) 2011-06-30
AU2010334587A1 (en) 2012-06-07
US20110151232A1 (en) 2011-06-23
CA2785279C (en) 2017-09-05
WO2011077094A9 (en) 2012-12-13
WO2011077094A1 (en) 2011-06-30
JP5808057B2 (ja) 2015-11-10
US20170326819A1 (en) 2017-11-16
JP2013515806A (ja) 2013-05-09
BR112012014186A2 (pt) 2016-05-31
GB0922599D0 (en) 2010-02-10
US10836118B2 (en) 2020-11-17
EP2516139B1 (en) 2016-03-16
TW201136752A (en) 2011-11-01
BR112012014186B1 (pt) 2019-10-08
ES2576133T3 (es) 2016-07-05
KR101703378B1 (ko) 2017-02-06
KR20120108002A (ko) 2012-10-04
MY160836A (en) 2017-03-31
CN103025508A (zh) 2013-04-03
TWI517966B (zh) 2016-01-21

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