KR101541749B1 - 구형 마그네슘 할라이드 어덕트, 촉매 성분 및 그것으로부터 제조된 올레핀 중합용 촉매 - Google Patents

구형 마그네슘 할라이드 어덕트, 촉매 성분 및 그것으로부터 제조된 올레핀 중합용 촉매 Download PDF

Info

Publication number
KR101541749B1
KR101541749B1 KR1020127003788A KR20127003788A KR101541749B1 KR 101541749 B1 KR101541749 B1 KR 101541749B1 KR 1020127003788 A KR1020127003788 A KR 1020127003788A KR 20127003788 A KR20127003788 A KR 20127003788A KR 101541749 B1 KR101541749 B1 KR 101541749B1
Authority
KR
South Korea
Prior art keywords
magnesium halide
alkyl
catalyst
aryl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020127003788A
Other languages
English (en)
Korean (ko)
Other versions
KR20120039016A (ko
Inventor
시안지 시아
위에시앙 리우
지귀 장
신셍 왕
핑 가오
수젠 치아오
마오핑 잉
웨이리 리
티앙이 장
렌치 펭
잉 첸
지휘 장
Original Assignee
차이나 페트로리움 앤드 케미컬 코포레이션
베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 차이나 페트로리움 앤드 케미컬 코포레이션, 베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션 filed Critical 차이나 페트로리움 앤드 케미컬 코포레이션
Publication of KR20120039016A publication Critical patent/KR20120039016A/ko
Application granted granted Critical
Publication of KR101541749B1 publication Critical patent/KR101541749B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02Magnesium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/025Metal oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020127003788A 2009-07-15 2009-07-15 구형 마그네슘 할라이드 어덕트, 촉매 성분 및 그것으로부터 제조된 올레핀 중합용 촉매 Active KR101541749B1 (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2009/000796 WO2011006278A1 (en) 2009-07-15 2009-07-15 Spherical magnesium halide adduct, catalyst component and catalyst for olefin polymerization prepared therefrom

Publications (2)

Publication Number Publication Date
KR20120039016A KR20120039016A (ko) 2012-04-24
KR101541749B1 true KR101541749B1 (ko) 2015-08-04

Family

ID=43448857

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127003788A Active KR101541749B1 (ko) 2009-07-15 2009-07-15 구형 마그네슘 할라이드 어덕트, 촉매 성분 및 그것으로부터 제조된 올레핀 중합용 촉매

Country Status (9)

Country Link
US (2) US9499569B2 (enExample)
EP (1) EP2454290B1 (enExample)
JP (1) JP5898073B2 (enExample)
KR (1) KR101541749B1 (enExample)
BR (1) BR112012000866B1 (enExample)
ES (1) ES2478017T3 (enExample)
IN (1) IN2012DN00631A (enExample)
SG (1) SG177665A1 (enExample)
WO (1) WO2011006278A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN2012DN00631A (enExample) 2009-07-15 2015-08-21 China Petroleum & Chemical
CN102040690A (zh) * 2009-10-20 2011-05-04 中国石油化工股份有限公司 一种低灰分聚丙烯的制备方法
CN102796211B (zh) * 2011-05-27 2014-03-12 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂以及烯烃聚合方法
ITMI20120877A1 (it) * 2011-05-27 2012-11-28 Beijing Res Inst Of Chemi Cal Industry Addotto di alogenuro di magnesio, componente catalitico/catalizzatore comprendente addotto di alogenuro di magnesio e sua preparazione.
KR101373775B1 (ko) 2012-11-23 2014-03-13 롯데케미칼 주식회사 폴리올레핀 합성용 촉매의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
CN105622423B (zh) * 2014-10-28 2019-06-28 中国石油化工股份有限公司 一种卤化镁加合物及其制备方法和应用
CN105622793B (zh) * 2014-10-28 2019-05-31 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分和催化剂体系及其应用和烯烃聚合方法
CN105622794B (zh) * 2014-10-28 2018-07-20 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分和催化剂体系及其应用和烯烃聚合方法
US9637575B2 (en) * 2014-12-31 2017-05-02 W. R. Grace & Co. -Conn. Catalyst system, olefin polymerization catalyst components comprising at least an internal electron donor compound, and methods of making and using the same
CN107108802B (zh) * 2014-12-31 2021-03-09 博里利斯股份公司 制备丙烯共聚物的方法
CN109096424A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
FR3104584B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
US20250066513A1 (en) * 2023-08-23 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003068828A1 (en) * 2002-02-07 2003-08-21 China Petroleum & Chemical Corporation Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof
CN1743347A (zh) * 2004-09-02 2006-03-08 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
CN101050245A (zh) * 2006-04-06 2007-10-10 中国石油化工股份有限公司 一种卤化镁加合物及其制备方法和应用

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069169A (en) * 1975-11-24 1978-01-17 Mitsui Petrochemical Industries Ltd. Process for preparation of catalyst component supported on high performance carrier
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
DE2839136A1 (de) * 1978-09-08 1980-03-20 Bayer Ag Katalysator auf einem festen traeger zur polymerisation von alpha -olefinen
DE3062482D1 (en) * 1979-01-10 1983-05-05 Ici Plc Olefine polymerisation catalyst and the production and use thereof
JPS5730708A (en) * 1980-07-30 1982-02-19 Mitsui Toatsu Chem Inc Stereoregular polymerizing method of alpha-olefin
JPS5774307A (en) * 1980-10-29 1982-05-10 Mitsui Petrochem Ind Ltd Polymerizing of alpha-olefin
IT1136627B (it) 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
EP0113960A1 (en) * 1982-12-15 1984-07-25 Imperial Chemical Industries Plc Production and use of magnesium halide composition
US4563512A (en) 1984-02-28 1986-01-07 Shell Oil Company Olefin polymerization process utilizing a combination of selectivity control agents
FI80055C (fi) * 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1227260B (it) 1988-09-30 1991-03-28 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja) 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
FI90248C (fi) 1991-11-29 1994-01-10 Borealis As Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
FI95715C (fi) * 1992-03-24 1996-03-11 Neste Oy Suihkukiteyttämällä valmistetun polymerointikatalyyttikantajan valmistus
CA2132531A1 (en) * 1992-03-31 1993-10-14 Joe Collier Polyporpylene resins and process for the production thereof
TW400342B (en) 1994-09-06 2000-08-01 Chisso Corp A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer
US7049377B1 (en) 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
IT1274250B (it) 1995-02-21 1997-07-15 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
US6323152B1 (en) 1998-03-30 2001-11-27 Basell Technology Company Bv Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom
CN102093397B (zh) 1997-03-29 2016-04-20 巴塞尔聚烯烃意大利有限公司 氯化镁-醇加合物、其制备方法以及从中获得的催化剂组分
WO2001036496A1 (en) * 1999-11-15 2001-05-25 Basell Technology Company B.V. Solid catalyst component for olefin polymerization, catalyst for olefin polymerization and process for producing olefin polymer
CN1151183C (zh) 2000-06-15 2004-05-26 中国石油化工股份有限公司 用于烯烃聚合或共聚合的球形催化剂组分及其催化剂
CN100441561C (zh) 2002-02-07 2008-12-10 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的多酯化合物
CN1463990A (zh) 2002-06-10 2003-12-31 营口市向阳催化剂有限责任公司 一种烯烃聚合球型催化剂组分及载体的制备方法
CN1169840C (zh) * 2002-08-15 2004-10-06 浙江大学 球形催化剂载体MgCl2-醇-有机络合剂复合物的制备方法
JP2006523730A (ja) * 2003-02-24 2006-10-19 ゾンクォーシーヨーファークォングーフェンヨーシェングォンス プロピレン重合用触媒の複合担体、これを含む触媒成分及び触媒
RU2330863C2 (ru) * 2003-03-27 2008-08-10 Базелль Полиолефин Италия С.Р.Л. Аддукты дихлорид магния-спирт и компоненты катализатора, полученные из них
CN1213080C (zh) 2003-04-21 2005-08-03 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
CN1267508C (zh) 2003-08-08 2006-08-02 中国石油化工股份有限公司 一种卤化镁/醇加合物及其制备方法和应用
CN1229400C (zh) * 2003-09-18 2005-11-30 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
WO2005063832A1 (en) * 2003-12-23 2005-07-14 Basell Poliolefine Italia S.R.L. Magnesium dichloride-ethanol adducts and atalyst components obtained therefrom
CN1286863C (zh) * 2004-03-25 2006-11-29 浙江大学 球形MgCl2-醇-有机络合剂载体负载的烯烃聚合催化剂及制备方法
US7351778B2 (en) 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
CN100348624C (zh) 2005-01-13 2007-11-14 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
US7153803B2 (en) * 2004-06-28 2006-12-26 Engelhard Corporation High activity and good hydrogen response Ziegler-Natta polyethylene catalyst
MY151043A (en) 2006-04-06 2014-03-31 China Petroleum & Chemical Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom
CN101486722B (zh) * 2008-01-17 2011-05-04 中国石油化工股份有限公司 一种卤化镁加合物及其制备方法和应用
CN101486776B (zh) 2008-01-17 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
IN2012DN00631A (enExample) 2009-07-15 2015-08-21 China Petroleum & Chemical
CN102040690A (zh) * 2009-10-20 2011-05-04 中国石油化工股份有限公司 一种低灰分聚丙烯的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003068828A1 (en) * 2002-02-07 2003-08-21 China Petroleum & Chemical Corporation Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof
CN1743347A (zh) * 2004-09-02 2006-03-08 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
CN101050245A (zh) * 2006-04-06 2007-10-10 中国石油化工股份有限公司 一种卤化镁加合物及其制备方法和应用

Also Published As

Publication number Publication date
US20170101486A1 (en) 2017-04-13
ES2478017T3 (es) 2014-07-18
WO2011006278A8 (en) 2012-01-26
EP2454290B1 (en) 2014-04-16
KR20120039016A (ko) 2012-04-24
JP5898073B2 (ja) 2016-04-06
US9499569B2 (en) 2016-11-22
US20120184694A1 (en) 2012-07-19
JP2012532896A (ja) 2012-12-20
US10239969B2 (en) 2019-03-26
WO2011006278A1 (en) 2011-01-20
SG177665A1 (en) 2012-02-28
IN2012DN00631A (enExample) 2015-08-21
BR112012000866B1 (pt) 2021-07-20
EP2454290A4 (en) 2013-01-02
BR112012000866A2 (pt) 2020-10-27
EP2454290A1 (en) 2012-05-23

Similar Documents

Publication Publication Date Title
KR101541749B1 (ko) 구형 마그네슘 할라이드 어덕트, 촉매 성분 및 그것으로부터 제조된 올레핀 중합용 촉매
KR101419757B1 (ko) 올레핀 중합용 촉매 성분 및 그의 제조 방법
KR101548595B1 (ko) 올레핀 중합용 촉매 성분 및 그것을 포함하는 촉매
KR101114073B1 (ko) 프로필렌 중합용 고체촉매의 제조 방법
JP5769728B2 (ja) プロピレン重合用固体触媒の製造方法及びそれによって製造された触媒
CN1726080A (zh) 氯化镁基加合物及由其制备的催化剂组分
CN1670043A (zh) 烯烃聚合用催化剂及其制备和聚合方法
KR20160073986A (ko) 올레핀 중합 촉매용 구형 담체, 촉매 구성 성분, 촉매 및 이의 제조 방법
US7388060B2 (en) Catalyst component for olefin (co)polymerization, preparation thereof, a catalyst comprising the same and use thereof
KR20110080616A (ko) 프로필렌 중합용 고체촉매의 제조 방법
EP2036928B1 (en) Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom
CN108570120B (zh) 含有邻苯二胺类化合物的固体催化剂组分和催化剂及其应用
CN116041577B (zh) 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法
CN108117617B (zh) 一种用于烯烃聚合的固体催化剂组分和催化剂
JP2014009359A (ja) プロピレン重合用固体触媒およびこれを用いたポリプロピレン製造方法
JP5671625B2 (ja) プロピレン重合用固体触媒およびその製造方法
CN107417819B (zh) 一种用于烯烃聚合的固体催化剂组分、催化剂及其应用
CN108570119B (zh) 一种含有萘二胺类化合物的固体催化剂组分、催化剂及其应用
KR20120002790A (ko) 프로필렌 중합용 고체촉매의 제조방법
CN121045420A (zh) 用于制备催化剂的组合物和催化剂和催化剂体系
KR20240076546A (ko) 공중합성이 개선된 프로필렌계 공중합체의 제조방법
KR100870818B1 (ko) 올레핀 중합 또는 공중합 방법
KR101374480B1 (ko) 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법
KR101447346B1 (ko) 프로필렌 중합용 고체촉매의 제조방법과 이에 의하여 제조된 촉매 및 상기 촉매를 이용한 폴리프로필렌 제조방법
KR20120060404A (ko) 프로필렌 중합용 고체촉매의 제조방법

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20120213

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20130716

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20150114

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20150623

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20150729

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20150729

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
FPAY Annual fee payment

Payment date: 20180620

Year of fee payment: 4

PR1001 Payment of annual fee

Payment date: 20180620

Start annual number: 4

End annual number: 4

FPAY Annual fee payment

Payment date: 20190625

Year of fee payment: 5

PR1001 Payment of annual fee

Payment date: 20190625

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20200623

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20210609

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20220531

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 20230619

Start annual number: 9

End annual number: 9

PR1001 Payment of annual fee

Payment date: 20240603

Start annual number: 10

End annual number: 10