KR101501823B1 - 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 - Google Patents
리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 Download PDFInfo
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- KR101501823B1 KR101501823B1 KR1020130015090A KR20130015090A KR101501823B1 KR 101501823 B1 KR101501823 B1 KR 101501823B1 KR 1020130015090 A KR1020130015090 A KR 1020130015090A KR 20130015090 A KR20130015090 A KR 20130015090A KR 101501823 B1 KR101501823 B1 KR 101501823B1
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 36
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000011365 complex material Substances 0.000 title 2
- 239000002131 composite material Substances 0.000 claims abstract description 88
- 239000000243 solution Substances 0.000 claims abstract description 47
- 239000011572 manganese Substances 0.000 claims abstract description 40
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000008139 complexing agent Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000007858 starting material Substances 0.000 claims abstract description 15
- 238000000975 co-precipitation Methods 0.000 claims abstract description 12
- 238000007599 discharging Methods 0.000 claims abstract description 10
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001981 cobalt nitrate Inorganic materials 0.000 claims abstract description 7
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000002002 slurry Substances 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 25
- 239000002243 precursor Substances 0.000 claims description 17
- 238000010304 firing Methods 0.000 claims description 15
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 14
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 14
- 238000002441 X-ray diffraction Methods 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 12
- 230000009467 reduction Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- 238000004458 analytical method Methods 0.000 claims description 8
- 230000006399 behavior Effects 0.000 claims description 8
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000006258 conductive agent Substances 0.000 claims description 7
- 239000011888 foil Substances 0.000 claims description 7
- 239000012046 mixed solvent Substances 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000011812 mixed powder Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical group [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000007774 positive electrode material Substances 0.000 claims description 2
- 238000004080 punching Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 210000004027 cell Anatomy 0.000 description 40
- 239000000463 material Substances 0.000 description 25
- 238000010438 heat treatment Methods 0.000 description 22
- 239000010405 anode material Substances 0.000 description 11
- 238000006722 reduction reaction Methods 0.000 description 11
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910014689 LiMnO Inorganic materials 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 5
- 239000010406 cathode material Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 4
- 230000033116 oxidation-reduction process Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000004626 scanning electron microscopy Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 229910015118 LiMO Inorganic materials 0.000 description 2
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000006182 cathode active material Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910000398 iron phosphate Inorganic materials 0.000 description 2
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 229910001317 nickel manganese cobalt oxide (NMC) Inorganic materials 0.000 description 2
- 239000010450 olivine Substances 0.000 description 2
- 229910052609 olivine Inorganic materials 0.000 description 2
- 239000005486 organic electrolyte Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910014071 LiMn1/3Co1/3Ni1/3O2 Inorganic materials 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- TZSOMSGYOHXXAT-UHFFFAOYSA-N dodecalithium trisilicate Chemical compound [Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+] TZSOMSGYOHXXAT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 210000003339 pole cell Anatomy 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H01M10/0422—Cells or battery with cylindrical casing
- H01M10/0427—Button cells
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- H01M10/44—Methods for charging or discharging
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- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H01M4/0435—Rolling or calendering
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- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
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- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/417—Polyolefins
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
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- H—ELECTRICITY
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
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- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130015090A KR101501823B1 (ko) | 2013-02-13 | 2013-02-13 | 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 |
| US14/766,874 US10020488B2 (en) | 2013-02-13 | 2013-08-20 | Method for producing anodic composite material for lithium secondary battery, method for producing electrode using same, and method for charging and discharging electrode |
| JP2015555900A JP6257650B2 (ja) | 2013-02-13 | 2013-08-20 | リチウム二次電池用正極複合素材製造方法及びこれを用いた電極製造方法 |
| PCT/KR2013/007462 WO2014126312A1 (ko) | 2013-02-13 | 2013-08-20 | 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130015090A KR101501823B1 (ko) | 2013-02-13 | 2013-02-13 | 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140101915A KR20140101915A (ko) | 2014-08-21 |
| KR101501823B1 true KR101501823B1 (ko) | 2015-03-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020130015090A Active KR101501823B1 (ko) | 2013-02-13 | 2013-02-13 | 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법 |
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| JP (1) | JP6257650B2 (enExample) |
| KR (1) | KR101501823B1 (enExample) |
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| WO2013058604A2 (ko) * | 2011-10-21 | 2013-04-25 | 한국생산기술 연구원 | 전기자동차용 리튬이차전지용 고에너지밀도의 양극 복합소재 합성 및 전극 제조기술 |
| CN104409716A (zh) * | 2014-10-30 | 2015-03-11 | 中国科学院过程工程研究所 | 一种具有浓度梯度的镍锂离子电池正极材料及其制备方法 |
| DE102017207683A1 (de) * | 2016-05-09 | 2017-11-09 | Nichia Corporation | Verfahren zur Herstellung eines Nickel-Kobalt-Verbundhydroxids und Verfahren zur Herstellung eines Aktivmaterials einer Positivelektrode für eine wasserfreie Elektrolytsekundärbatterie |
| CN110494394A (zh) * | 2017-03-15 | 2019-11-22 | 尤米科尔公司 | 用于制造过渡金属氢氧化物前体的硝酸盐方法 |
| KR102131738B1 (ko) * | 2017-07-13 | 2020-07-08 | 주식회사 엘지화학 | 양극 활물질의 제조방법 |
| EP3611132B1 (en) * | 2017-11-24 | 2021-09-01 | LG Chem, Ltd. | Method for preparing cathode active material |
| KR102288291B1 (ko) * | 2018-04-12 | 2021-08-10 | 주식회사 엘지화학 | 양극 활물질의 제조방법 |
| WO2019230101A1 (ja) * | 2018-05-31 | 2019-12-05 | パナソニックIpマネジメント株式会社 | 正極活物質およびそれを備えた電池 |
| KR102880140B1 (ko) * | 2020-08-14 | 2025-11-04 | 주식회사 엘지에너지솔루션 | 전극 슬러리 조성물, 이의 제조방법 및 이의 용도 |
| CA3233515A1 (en) * | 2021-10-04 | 2023-04-13 | Basf Se | Process for the manufacture of a coated cathode active material, and coated cathode active material |
| CN114933337B (zh) * | 2022-06-30 | 2023-12-26 | 宁波容百新能源科技股份有限公司 | 一种锰基碳酸盐前驱体、富锂锰基正极材料及锂离子二次电池 |
| KR102467486B1 (ko) * | 2022-06-30 | 2022-11-17 | 주식회사 탑머티리얼 | 리튬 이차 전지용 양극 활물질, 이의 제조 방법, 이를 포함하는 양극 및 리튬 이차 전지 |
| WO2025025106A1 (zh) * | 2023-07-31 | 2025-02-06 | 北京当升材料科技股份有限公司 | 富锂锰氧化物正极材料及其制备方法与应用、正极片及其应用 |
| CN119812667B (zh) * | 2025-03-11 | 2025-10-17 | 江苏中兴派能电池有限公司 | 隔膜改性材料及其制备方法、隔膜和钠电池 |
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| KR100815583B1 (ko) * | 2006-10-13 | 2008-03-20 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지 |
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| DE19849343A1 (de) | 1997-10-30 | 1999-06-02 | Samsung Display Devices Co Ltd | Lithiumcompositoxid, dessen Herstellung und sekundäre Lithiumionzelle mit Lithiumcompositoxid als aktives Material der positiven Elektrode |
| KR100280998B1 (ko) * | 1998-12-10 | 2001-03-02 | 김순택 | 리튬 이차 전지용 양극 활물질 |
| JP4556377B2 (ja) | 2001-04-20 | 2010-10-06 | 株式会社Gsユアサ | 正極活物質およびその製造方法、非水電解質二次電池用正極、並びに、非水電解質二次電池 |
| TWI335687B (en) * | 2006-02-17 | 2011-01-01 | Lg Chemical Ltd | Lithium-metal composite oxides and electrochemical device using the same |
| CN102055023A (zh) * | 2007-11-12 | 2011-05-11 | 株式会社杰士汤浅国际 | 锂二次电池的制造方法 |
| US10056644B2 (en) | 2009-07-24 | 2018-08-21 | Zenlabs Energy, Inc. | Lithium ion batteries with long cycling performance |
| WO2012067675A1 (en) * | 2010-11-17 | 2012-05-24 | Uchicago Argonne, Llc, Operator Of Argonne National Laboratory | Electrode structures and surfaces for li batteries |
| WO2012164752A1 (ja) * | 2011-05-30 | 2012-12-06 | 住友金属鉱山株式会社 | 非水系二次電池用正極活物質とその製造方法、ならびに該正極活物質を用いた非水系電解質二次電池 |
| CN102842705B (zh) * | 2011-06-22 | 2015-03-11 | 清华大学 | 钴的氧化物及其复合材料,以及钴的氧化物复合材料的制备方法 |
| WO2013058604A2 (ko) * | 2011-10-21 | 2013-04-25 | 한국생산기술 연구원 | 전기자동차용 리튬이차전지용 고에너지밀도의 양극 복합소재 합성 및 전극 제조기술 |
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| KR100815583B1 (ko) * | 2006-10-13 | 2008-03-20 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지 |
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| Journal of Materials Chemistry 2010, 20, pp3961-3967 * |
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| Publication number | Publication date |
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| JP6257650B2 (ja) | 2018-01-10 |
| JP2016509348A (ja) | 2016-03-24 |
| US10020488B2 (en) | 2018-07-10 |
| US20150380720A1 (en) | 2015-12-31 |
| WO2014126312A1 (ko) | 2014-08-21 |
| KR20140101915A (ko) | 2014-08-21 |
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