KR101352471B1 - 개선된 플루오르화 반응기 - Google Patents

개선된 플루오르화 반응기 Download PDF

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Publication number
KR101352471B1
KR101352471B1 KR1020087018638A KR20087018638A KR101352471B1 KR 101352471 B1 KR101352471 B1 KR 101352471B1 KR 1020087018638 A KR1020087018638 A KR 1020087018638A KR 20087018638 A KR20087018638 A KR 20087018638A KR 101352471 B1 KR101352471 B1 KR 101352471B1
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reactor
adsorption composition
fluoride
halohydrocarbon
hydrocarbon
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KR1020087018638A
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Korean (ko)
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KR20080083036A (ko
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매튜 에이치. 룰리
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허니웰 인터내셔널 인코포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00946—Features relating to the reactants or products
    • B01J2208/00955—Sampling of the particulate material, the reactants or the products
    • B01J2208/00973—Products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00038—Processes in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00193—Sensing a parameter
    • B01J2219/00195—Sensing a parameter of the reaction system
    • B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/00213—Fixed parameter value
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00227—Control algorithm taking actions modifying the operating conditions
    • B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
    • B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
KR1020087018638A 2006-01-04 2007-01-03 개선된 플루오르화 반응기 Expired - Fee Related KR101352471B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/326,379 2006-01-04
US11/326,379 US7247759B1 (en) 2006-01-04 2006-01-04 Fluorination reactor
PCT/US2007/000171 WO2007089386A2 (en) 2006-01-04 2007-01-03 Improved fluoriation reactor

Publications (2)

Publication Number Publication Date
KR20080083036A KR20080083036A (ko) 2008-09-12
KR101352471B1 true KR101352471B1 (ko) 2014-01-17

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KR1020087018638A Expired - Fee Related KR101352471B1 (ko) 2006-01-04 2007-01-03 개선된 플루오르화 반응기

Country Status (7)

Country Link
US (2) US7247759B1 (cg-RX-API-DMAC10.html)
EP (1) EP1968921A2 (cg-RX-API-DMAC10.html)
JP (2) JP2009522366A (cg-RX-API-DMAC10.html)
KR (1) KR101352471B1 (cg-RX-API-DMAC10.html)
CN (1) CN101365669B (cg-RX-API-DMAC10.html)
RU (1) RU2446139C2 (cg-RX-API-DMAC10.html)
WO (1) WO2007089386A2 (cg-RX-API-DMAC10.html)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150093316A1 (en) * 2013-09-30 2015-04-02 Honeywell International, Inc. Purification of pf5
CN111386254B (zh) * 2017-12-12 2023-08-22 株式会社力森诺科 含氟有机化合物的制造方法和制造装置
CN108940129A (zh) * 2018-08-29 2018-12-07 山东重山光电材料股份有限公司 一种多级利用氟化剂生产氟化碳材料的系统及生产方法
WO2021031431A1 (en) * 2019-08-22 2021-02-25 Fujian Yongjing Technology Co., Ltd Process for preparing fluorobenzene by direct fluorination
CN113289557B (zh) * 2021-06-16 2023-05-09 武汉松石科技股份有限公司 一种有机物氟化气液反应系统

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4859747A (en) * 1985-11-08 1989-08-22 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
JPH02117626A (ja) * 1988-10-26 1990-05-02 Osaka Gas Co Ltd フッ素化反応装置

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4377715A (en) 1979-12-26 1983-03-22 Allied Corporation Production of perfluoropropane
DE3009760A1 (de) * 1980-03-14 1981-09-24 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von hochreinen teilfluorierten aethanen
JPS59204146A (ja) * 1983-04-30 1984-11-19 Central Glass Co Ltd 含フツ素有機化合物の精製法
FR2556340B1 (fr) * 1983-12-13 1986-05-16 Atochem Procede catalytique de preparation d'hexafluoroacetone
JPS60137928A (ja) * 1983-12-26 1985-07-22 Daikin Ind Ltd 新規含フツ素ポリエ−テルおよびその製法
IT1184149B (it) * 1985-03-11 1987-10-22 Montefluos Spa Processo per la preparazione di fluorossi-alo-composti
US4680406A (en) * 1985-10-15 1987-07-14 The Dow Chemical Company Process for fluorinating halogenated organo-compounds
US5093432A (en) * 1988-09-28 1992-03-03 Exfluor Research Corporation Liquid phase fluorination
AU4416289A (en) * 1988-09-28 1990-04-18 Exfluor Research Corporation Liquid phase fluorination
US4990701A (en) * 1990-03-20 1991-02-05 E. I. Dupont De Nemours And Company Halogen exchange fluorination
JP3115423B2 (ja) * 1992-08-07 2000-12-04 株式会社トクヤマ フッ素化合物の製造方法
DE4311062A1 (de) * 1993-04-03 1994-10-06 Solvay Fluor & Derivate Herstellung von Perfluoralkanen
DE4419534C1 (de) * 1994-06-03 1995-10-19 Hoechst Ag Verfahren zur Regenerierung eines chrom- und magnesiumhaltigen Fluorierungskatalysators
US5675046A (en) 1996-04-10 1997-10-07 Showa Denko K.K. Process for producing perfluorocarbon
JP3792051B2 (ja) * 1997-09-17 2006-06-28 日本ゼオン株式会社 パーハロゲン化シクロペンテンの製造方法
EP1051376B1 (en) * 1998-01-16 2004-11-17 AlliedSignal Inc. Method of producing fluorinated organic compounds
US20020156321A1 (en) * 2001-02-13 2002-10-24 Syvret Robert George Continuous preparation of high purity Bis(fluoroxy)difluoromethane (BDM) at elevated pressure
JP5025052B2 (ja) * 2001-08-06 2012-09-12 昭和電工株式会社 ヘキサフルオロエタンの製造方法およびその用途
DE10159940B4 (de) 2001-12-06 2007-02-08 Air Liquide Deutschland Gmbh Vorrichtung und Verfahren zur Fluorierung von Formteilen aus Kunststoff mit einem fluorhaltigen Gasgemisch
WO2004035518A1 (ja) * 2002-10-18 2004-04-29 Asahi Glass Company, Limited フッ素化された化合物の製造方法、およびフッ素化装置
US7557227B2 (en) * 2003-02-17 2009-07-07 Asahi Glass Company, Limited Process for producing hexafluoropropylene oxide

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4859747A (en) * 1985-11-08 1989-08-22 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
JPH02117626A (ja) * 1988-10-26 1990-05-02 Osaka Gas Co Ltd フッ素化反応装置

Also Published As

Publication number Publication date
WO2007089386A2 (en) 2007-08-09
KR20080083036A (ko) 2008-09-12
EP1968921A2 (en) 2008-09-17
JP2009522366A (ja) 2009-06-11
US20070154368A1 (en) 2007-07-05
RU2008131767A (ru) 2010-02-10
US7731911B2 (en) 2010-06-08
CN101365669B (zh) 2013-11-20
RU2446139C2 (ru) 2012-03-27
WO2007089386A3 (en) 2007-09-20
CN101365669A (zh) 2009-02-11
JP2014055152A (ja) 2014-03-27
US20070155996A1 (en) 2007-07-05
US7247759B1 (en) 2007-07-24

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