KR101001503B1 - 지지된 은 촉매 및 이 촉매를 사용한 에폭시화 방법 - Google Patents

지지된 은 촉매 및 이 촉매를 사용한 에폭시화 방법 Download PDF

Info

Publication number
KR101001503B1
KR101001503B1 KR1020047013119A KR20047013119A KR101001503B1 KR 101001503 B1 KR101001503 B1 KR 101001503B1 KR 1020047013119 A KR1020047013119 A KR 1020047013119A KR 20047013119 A KR20047013119 A KR 20047013119A KR 101001503 B1 KR101001503 B1 KR 101001503B1
Authority
KR
South Korea
Prior art keywords
carrier
catalyst
alumina
weight
pores
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
KR1020047013119A
Other languages
English (en)
Korean (ko)
Other versions
KR20040086431A (ko
Inventor
로케미어존로버트
예이츠랜달클레이튼
스지만스키토머스
레머스도널드제임스
저데스윌리엄허먼
Original Assignee
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Publication of KR20040086431A publication Critical patent/KR20040086431A/ko
Application granted granted Critical
Publication of KR101001503B1 publication Critical patent/KR101001503B1/ko
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020047013119A 2002-02-25 2004-08-23 지지된 은 촉매 및 이 촉매를 사용한 에폭시화 방법 Expired - Lifetime KR101001503B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US36006002P 2002-02-25 2002-02-25
US60/360,060 2002-02-25
PCT/US2003/005902 WO2003072246A2 (en) 2002-02-25 2003-02-25 Supported silver catalyst and an epoxidation process using the catalyst

Publications (2)

Publication Number Publication Date
KR20040086431A KR20040086431A (ko) 2004-10-08
KR101001503B1 true KR101001503B1 (ko) 2010-12-14

Family

ID=27766182

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020047013119A Expired - Lifetime KR101001503B1 (ko) 2002-02-25 2004-08-23 지지된 은 촉매 및 이 촉매를 사용한 에폭시화 방법

Country Status (13)

Country Link
US (3) US20030162984A1 (enExample)
EP (1) EP1511563B1 (enExample)
JP (1) JP4335692B2 (enExample)
KR (1) KR101001503B1 (enExample)
CN (2) CN100553763C (enExample)
AU (1) AU2003217756B2 (enExample)
BR (1) BR0307958B1 (enExample)
CA (1) CA2477069C (enExample)
IN (1) IN2004DE02399A (enExample)
MX (1) MXPA04008167A (enExample)
RU (1) RU2342190C2 (enExample)
WO (1) WO2003072246A2 (enExample)
ZA (1) ZA200406645B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200115635A (ko) * 2018-02-07 2020-10-07 바스프 에스이 에틸렌으로부터 에틸렌 옥사이드로의 산화성 전환에 효과적인 촉매

Families Citing this family (81)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2314156C2 (ru) * 2002-06-28 2008-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ улучшения селективности катализатора и способ эпоксидирования олефина
WO2004039497A2 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Silver-based olefin oxide catalysts
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
EP1658136A1 (en) * 2003-08-22 2006-05-24 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
EP1658135A1 (en) * 2003-08-22 2006-05-24 Union Carbide Chemicals & Plastics Technology Corporation Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
JP4824569B2 (ja) * 2003-10-16 2011-11-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイド製造用の増強された安定性、効率及び／又は活性を有する触媒
TW200600190A (en) 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
CA2571179C (en) * 2004-06-18 2014-06-10 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
CN100572370C (zh) * 2004-06-18 2009-12-23 国际壳牌研究有限公司 生产烯烃氧化物、1,2-二醇、1,2-二醇醚或链烷醇胺的方法
MX2007001684A (es) * 2004-08-12 2007-04-12 Shell Int Research Metodo para la preparacion de un catalizador formado, el catalizador, y uso del catalizador.
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
BRPI0514814A (pt) * 2004-09-01 2008-06-24 Shell Int Research processo de epoxidação de olefina, um catalisador para uso no processo, um veìculo para uso na preparação do catalisador, e processo para preparar o veìculo
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
TWI334363B (en) * 2005-06-07 2010-12-11 Saint Gobain Ceramics A catalyst carrier
KR101369619B1 (ko) * 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
WO2007000945A1 (ja) * 2005-06-27 2007-01-04 Nippon Nyukazai Co., Ltd. モノ低級アルキルモノアルカノールアミン連続製造用成形触媒及びその製造方法
US8382868B2 (en) 2005-10-28 2013-02-26 Iain Patrick Goudemond Cubic boron nitride compact
US7459589B2 (en) 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US7750170B2 (en) 2005-12-22 2010-07-06 Shell Oil Company Process for mixing an oxidant having explosive potential with a hydrocarbon
BE1017793A3 (fr) * 2005-12-22 2009-07-07 Shell Int Research Procede de preparation d'un oxyde d'olefine ou d'un produit chimique pouvant provenir d'un oxyde d'olefine.
EP1979092A2 (en) * 2006-02-03 2008-10-15 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
CN101370746B (zh) * 2006-02-10 2012-09-05 圣戈本陶瓷及塑料股份有限公司 制备多孔陶瓷材料的方法
US20070270597A1 (en) * 2006-05-18 2007-11-22 Basf Aktiengesellschaft Process for preparing maleic anhydride in a microchannel reactor
US20070280877A1 (en) * 2006-05-19 2007-12-06 Sawyer Technical Materials Llc Alpha alumina supports for ethylene oxide catalysts and method of preparing thereof
JP4267015B2 (ja) 2006-09-29 2009-05-27 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
WO2008141032A1 (en) 2007-05-09 2008-11-20 Shell Oil Company An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
EP2152411B1 (en) 2007-05-09 2019-12-04 Shell International Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
JP2010532251A (ja) * 2007-07-05 2010-10-07 グレース・ゲーエムベーハー・ウント・コムパニー・カーゲー 無機酸化物担持触媒の製造方法
US7507845B1 (en) * 2007-08-27 2009-03-24 Sd Lizenzverwertungsgesellschaft Mbh & Co Kg Process for production of an olefin oxide
WO2009029578A2 (en) * 2007-08-27 2009-03-05 Shell Oil Company A carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US7714152B2 (en) * 2007-08-30 2010-05-11 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Carrier for olefin oxide catalyst
CA2723177A1 (en) 2008-04-30 2009-11-05 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
KR101629038B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
CN102056909B (zh) 2008-05-07 2014-03-05 国际壳牌研究有限公司 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法
BRPI0915854A2 (pt) * 2008-07-14 2015-08-04 Basf Se Processo para preparar óxido de etileno
US9115104B2 (en) * 2009-01-27 2015-08-25 Scientific Design Company, Inc. Ethylene oxide catalyst with optimized cesium content
WO2010113963A1 (ja) 2009-03-31 2010-10-07 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
JP2010234264A (ja) * 2009-03-31 2010-10-21 Nippon Shokubai Co Ltd エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
EP2421643A2 (en) * 2009-04-21 2012-02-29 Dow Technology Investments LLC Rhenium-promoted epoxidation catalysts and methods of making and using them
CN102421724A (zh) * 2009-04-29 2012-04-18 陶氏技术投资有限公司 多孔体前体，成形多孔体，用于制造它们的方法及基于其的最终用途产品
JP5717732B2 (ja) * 2009-07-02 2015-05-13 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 酸化的脱水素化またはエポキシ化のための貴金属含有担持触媒
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
CA2791210C (en) * 2010-03-01 2019-10-29 Shell Internationale Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
US8883678B2 (en) 2010-06-04 2014-11-11 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
JP6062417B2 (ja) * 2011-04-14 2017-01-18 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ エチレンをエチレンオキシドに酸化するための触媒の製造方法
US9073035B2 (en) 2011-10-14 2015-07-07 Saint-Gobain Ceramics & Plastics, Inc. Catalyst and catalyst carrier
TWI590867B (zh) * 2011-10-14 2017-07-11 聖高拜陶器塑膠公司 催化劑及催化劑載體
SG11201401948UA (en) 2011-10-31 2014-09-26 Dow Technology Investments Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing these
BR112014012128A8 (pt) * 2011-11-21 2017-06-20 Scient Design Co veículo para catalisadores de óxido de etileno
CN104125858B (zh) 2011-12-19 2017-07-11 陶氏技术投资有限责任公司 根据催化剂参考性质配制环氧烷催化剂的方法
EP2819781A4 (en) * 2012-03-02 2016-01-27 Basf Se Porous inorganic body
CN104707592B (zh) * 2013-12-12 2017-07-28 中国石油化工股份有限公司 一种用于银催化剂的α‑氧化铝载体的制备方法
CN104707664B (zh) * 2013-12-13 2017-11-07 中国石油化工股份有限公司 一种用于银催化剂的α‑氧化铝载体的制备方法
CN105080618B (zh) * 2014-05-09 2017-12-19 中国石油化工股份有限公司 一种用于银催化剂的α‑氧化铝载体的制备方法
CA2987427A1 (en) * 2015-06-02 2016-12-08 Scientific Design Company, Inc. Epoxidation process
CN106955745A (zh) * 2016-01-08 2017-07-18 中国石油化工股份有限公司 一种α-氧化铝载体、由其制备的银催化剂和应用
US10815169B2 (en) 2016-02-04 2020-10-27 Shell Oil Company Conversion of mixed methane/ethane streams
CN107413389B (zh) * 2016-05-23 2020-07-24 中国石油化工股份有限公司 用于银催化剂的α-氧化铝载体及其制备方法与应用
RU2623436C1 (ru) * 2016-06-02 2017-06-26 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Носитель для катализаторов на основе оксида алюминия и способ его приготовления
WO2018029189A1 (en) 2016-08-08 2018-02-15 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide
CA3043504A1 (en) 2016-12-02 2018-06-07 Shell Internationale Research Maatschappij B.V. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
CN108607533B (zh) * 2016-12-09 2020-12-18 中国石油化工股份有限公司 氧化铝载体、催化剂及应用
CN109225180A (zh) * 2017-07-10 2019-01-18 中国石油化工股份有限公司 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法
CN110038543B (zh) * 2018-01-17 2022-07-12 中国石油化工股份有限公司 乙烯环氧化用银催化剂的α-氧化铝载体、银催化剂及乙烯环氧化生产环氧乙烷的方法
CN110354841A (zh) * 2018-03-26 2019-10-22 中国石油化工股份有限公司 银催化剂用α-氧化铝载体及其制备方法和乙烯环氧化用银催化剂及应用
US10676401B2 (en) * 2018-04-23 2020-06-09 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared with oxalic acid
CN111437888A (zh) * 2019-01-16 2020-07-24 中国石油化工股份有限公司 α-氧化铝载体及乙烯环氧化用银催化剂和应用
CN111939884B (zh) * 2019-05-16 2023-05-09 中国石油化工股份有限公司 一种α-氧化铝载体及其制备方法和银催化剂及应用
CN111068654A (zh) * 2019-12-20 2020-04-28 山东爱亿普环保科技股份有限公司 一种中高温scr脱硝催化剂及其制备方法
CN111420659B (zh) * 2020-04-21 2022-08-09 湖北荟煌科技股份有限公司 一种贵金属催化剂
WO2021260140A1 (en) 2020-06-26 2021-12-30 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
WO2021260182A1 (en) 2020-06-26 2021-12-30 Basf Se Process for producing a porous alpha-alumina catalyst support
WO2022147407A1 (en) 2020-12-29 2022-07-07 Saint-Gobain Ceramics & Plastics, Inc. Ceramic article and methods of making the same
CN116723893A (zh) * 2021-01-26 2023-09-08 巴斯夫欧洲公司 环氧化催化剂

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4845296A (en) 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
WO1997040932A1 (en) 1996-04-30 1997-11-06 Norton Chemical Process Products Corporation Catalyst carrier

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3664970A (en) * 1969-04-17 1972-05-23 Halcon International Inc Ethylene oxide catalyst
US4007123A (en) * 1972-02-28 1977-02-08 Mcdonnell Douglas Corporation Fire resistant functional fluid compositions
GB1491447A (en) * 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
JPS5637050A (en) * 1979-09-04 1981-04-10 Ube Ind Ltd Preparation of catalyst for preparing unsaturated acid
US4551443A (en) * 1984-11-27 1985-11-05 Shell Oil Company Catalysts for the selective hydrogenation of acetylenes
US4577047A (en) * 1984-11-27 1986-03-18 Shell Oil Company Catalysts and process for the selective hydrogenation of acetylenes
IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
CA2053411C (en) * 1990-10-12 1997-06-03 Albert Cheng-Yu Liu Alkylene oxide catalysts having enhanced activity and/or stability
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5145824A (en) * 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5384302A (en) * 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
DE69409463T2 (de) * 1993-11-02 1998-07-30 Nippon Catalytic Chem Ind Verfahren zur Herstellung von Alkanolamin, Katalysator für dieses Verfahren und Verfahren zur Herstellung des Katalysators
WO1997046317A1 (en) * 1996-06-05 1997-12-11 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst and process
EP0937498B1 (en) * 1998-02-20 2004-08-18 Nippon Shokubai Co., Ltd. Silver catalyst for production of ethylene Oxide, method for production thereof, and method for production of ethylene oxide
ATE291962T1 (de) * 2000-10-25 2005-04-15 Mitsubishi Chem Corp Verfahren zur oxidation von olefinen unter verwendung eines silber und alkalimetall(e) enthaltenden katalysator

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4845296A (en) 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
WO1997040932A1 (en) 1996-04-30 1997-11-06 Norton Chemical Process Products Corporation Catalyst carrier

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200115635A (ko) * 2018-02-07 2020-10-07 바스프 에스이 에틸렌으로부터 에틸렌 옥사이드로의 산화성 전환에 효과적인 촉매
KR102738540B1 (ko) 2018-02-07 2024-12-05 바스프 에스이 에틸렌으로부터 에틸렌 옥사이드로의 산화성 전환에 효과적인 촉매

Also Published As

Publication number Publication date
CN1642637A (zh) 2005-07-20
CN100408168C (zh) 2008-08-06
CN101085425A (zh) 2007-12-12
MXPA04008167A (es) 2004-11-26
AU2003217756A1 (en) 2003-09-09
CN100553763C (zh) 2009-10-28
US20030162984A1 (en) 2003-08-28
CA2477069C (en) 2012-08-21
IN2004DE02399A (enExample) 2005-04-01
KR20040086431A (ko) 2004-10-08
RU2004128458A (ru) 2005-04-10
EP1511563B1 (en) 2012-11-28
US20070184973A1 (en) 2007-08-09
ZA200406645B (en) 2006-05-31
RU2342190C2 (ru) 2008-12-27
WO2003072246A2 (en) 2003-09-04
CA2477069A1 (en) 2003-09-04
WO2003072246A3 (en) 2004-01-08
JP4335692B2 (ja) 2009-09-30
EP1511563A2 (en) 2005-03-09
JP2005518276A (ja) 2005-06-23
BR0307958A (pt) 2004-12-21
US20090177016A1 (en) 2009-07-09
BR0307958B1 (pt) 2013-07-09
AU2003217756B2 (en) 2008-11-20

Similar Documents

Publication Publication Date Title
KR101001503B1 (ko) 지지된 은 촉매 및 이 촉매를 사용한 에폭시화 방법
JP5547256B2 (ja) 触媒担体およびその触媒担体の調製方法
US8357813B2 (en) Process for the production of an olefin oxide
US8999882B2 (en) Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
JP2013521119A (ja) エポキシ化触媒、前記触媒の調製方法及びオレフィンオキシドの製造方法

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20131119

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20141120

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20151118

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

FPAY Annual fee payment

Payment date: 20161123

Year of fee payment: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

FPAY Annual fee payment

Payment date: 20171117

Year of fee payment: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

FPAY Annual fee payment

Payment date: 20181115

Year of fee payment: 9

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 10

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 11

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 12

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 13

PC1801 Expiration of term

St.27 status event code: N-4-6-H10-H14-oth-PC1801

Not in force date: 20230226

Ip right cessation event data comment text: Termination Category : EXPIRATION_OF_DURATION

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000