KR100707839B1 - 제거하기가 용이한 니트록실 라디칼을 사용한 알콜의선택적 산화 방법 - Google Patents
제거하기가 용이한 니트록실 라디칼을 사용한 알콜의선택적 산화 방법 Download PDFInfo
- Publication number
- KR100707839B1 KR100707839B1 KR1020000068475A KR20000068475A KR100707839B1 KR 100707839 B1 KR100707839 B1 KR 100707839B1 KR 1020000068475 A KR1020000068475 A KR 1020000068475A KR 20000068475 A KR20000068475 A KR 20000068475A KR 100707839 B1 KR100707839 B1 KR 100707839B1
- Authority
- KR
- South Korea
- Prior art keywords
- oxy
- formula
- compound
- alcohols
- abandoned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 CC(C)(CC(CC1(C)C)O*2np(OC(CC3(C)C)CC(C)(C)N3O)(OC(CC3(C)C)CC(C)(C)N3O)np(OC(CC3(C)C)CC(C)(C)N3O)(OC(CC3(C)C)CC(C)(C)N3O)n2)N1O Chemical compound CC(C)(CC(CC1(C)C)O*2np(OC(CC3(C)C)CC(C)(C)N3O)(OC(CC3(C)C)CC(C)(C)N3O)np(OC(CC3(C)C)CC(C)(C)N3O)(OC(CC3(C)C)CC(C)(C)N3O)n2)N1O 0.000 description 2
- CSGAUKGQUCHWDP-UHFFFAOYSA-N CC(C)(CC(CC1(C)C)O)N1O Chemical compound CC(C)(CC(CC1(C)C)O)N1O CSGAUKGQUCHWDP-UHFFFAOYSA-N 0.000 description 1
- KRNWYBIEWUXCOB-UHFFFAOYSA-N CC(C)(CC(CC1(C)C)OC)N1O Chemical compound CC(C)(CC(CC1(C)C)OC)N1O KRNWYBIEWUXCOB-UHFFFAOYSA-N 0.000 description 1
- CUCRBSAJOAUBKI-UHFFFAOYSA-N CC(C)(CC(CC1(C)C)Oc2nc(OC(CC3(C)C)CC(C)(C)N3O)nc(OC(CC3(C)C)CC(C)(C)N3O)n2)N1O Chemical compound CC(C)(CC(CC1(C)C)Oc2nc(OC(CC3(C)C)CC(C)(C)N3O)nc(OC(CC3(C)C)CC(C)(C)N3O)n2)N1O CUCRBSAJOAUBKI-UHFFFAOYSA-N 0.000 description 1
- XQPRKWAZQZIMNF-UHFFFAOYSA-N CCCp1(C)np(Cl)(Cl)np(Cl)(Cl)n1 Chemical compound CCCp1(C)np(Cl)(Cl)np(Cl)(Cl)n1 XQPRKWAZQZIMNF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/025—Polyphosphazenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
- C07F9/65815—Cyclic phosphazenes [P=N-]n, n>=3 n = 3
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Pyrane Compounds (AREA)
- Catalysts (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH211399 | 1999-11-19 | ||
| CH2113/99 | 1999-11-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010051782A KR20010051782A (ko) | 2001-06-25 |
| KR100707839B1 true KR100707839B1 (ko) | 2007-04-17 |
Family
ID=4226187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020000068475A Expired - Fee Related KR100707839B1 (ko) | 1999-11-19 | 2000-11-17 | 제거하기가 용이한 니트록실 라디칼을 사용한 알콜의선택적 산화 방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6441243B1 (https=) |
| EP (1) | EP1103537B1 (https=) |
| JP (1) | JP4727806B2 (https=) |
| KR (1) | KR100707839B1 (https=) |
| CN (1) | CN1173913C (https=) |
| AT (1) | ATE240285T1 (https=) |
| CA (1) | CA2326304A1 (https=) |
| CZ (1) | CZ20004299A3 (https=) |
| DE (1) | DE50002160D1 (https=) |
| SK (1) | SK284566B6 (https=) |
| TW (1) | TWI266763B (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004524296A (ja) * | 2001-01-23 | 2004-08-12 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 酸化触媒としての安定なフリーニトロキシルラジカル及び酸化方法 |
| ATE257136T1 (de) | 2001-10-11 | 2004-01-15 | Consortium Elektrochem Ind | Verfahren zur oxidation von alkoholen unter katalyse von nitroxylverbindungen |
| KR101029863B1 (ko) * | 2001-12-21 | 2011-04-18 | 시바 홀딩 인코포레이티드 | 신규한 난연제 화합물 |
| JP4369240B2 (ja) * | 2002-01-29 | 2009-11-18 | フイルメニツヒ ソシエテ アノニム | 不飽和アルコールの酸化法 |
| JPWO2003080575A1 (ja) * | 2002-03-26 | 2005-07-21 | 広栄化学工業株式会社 | 複素環式アルデヒドの製造方法 |
| WO2003084911A1 (en) * | 2002-04-05 | 2003-10-16 | Ciba Specialty Chemicals Holding Inc. | Process for converting alcohols to carbonyl compounds |
| DE10244633B3 (de) | 2002-09-25 | 2004-02-26 | Consortium für elektrochemische Industrie GmbH | Verfahren zur Herstellung von Alkincarbonsäuren durch Oxidation von Alkinalkoholen |
| AU2003276010A1 (en) * | 2002-10-07 | 2004-04-23 | Ciba Specialty Chemicals Holding Inc. | Oxoammonium salts of 1-oxy-2,2,6,6-tetramethyl-1-piperidine (tempo) and their use as oxidizing agents |
| WO2005084800A1 (en) * | 2004-03-02 | 2005-09-15 | Johnson Matthey Plc | Oxidation catalysts |
| CN1300081C (zh) * | 2004-12-30 | 2007-02-14 | 中国科学院大连化学物理研究所 | 一种催化空气氧化醇制备醛和酮的方法 |
| US7658802B2 (en) * | 2005-11-22 | 2010-02-09 | Applied Materials, Inc. | Apparatus and a method for cleaning a dielectric film |
| CN101774898B (zh) * | 2009-01-14 | 2012-08-08 | 中国科学院大连化学物理研究所 | 一种丙酮醇的制备方法 |
| CN105272954B (zh) * | 2014-06-27 | 2017-10-13 | 上海弈柯莱生物医药科技有限公司 | 一种6‑取代甲基‑4‑羟基四氢吡喃‑2‑酮及其衍生物的制备方法 |
| CN111646963B (zh) * | 2020-06-29 | 2022-09-27 | 张明 | 一种δ-环戊内酯的制备方法 |
| CN115819388B (zh) * | 2021-09-17 | 2024-06-11 | 台州学院 | 一种δ-环戊内酯的制备方法 |
| US20250170565A1 (en) * | 2022-03-02 | 2025-05-29 | Asymchem Life Science (Tianjin) Co. Ltd. | Catalyst Loaded with TEMPO Compound, and Preparation Method and Use thereof |
| WO2024107929A1 (en) * | 2022-11-16 | 2024-05-23 | Wisconsin Alumni Research Foundation | Catalytic synthesis of delta-valerolactone (dvl) from furfural-derived 2-hydroxytetrahydropyran (hthp) |
| CN116751173A (zh) * | 2023-05-05 | 2023-09-15 | 易简和成(江苏)医药科技有限公司 | 一种药物中间体的绿色合成方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05310632A (ja) * | 1992-04-28 | 1993-11-22 | Sumitomo Chem Co Ltd | m−フェノキシベンズアルデヒドの製造方法 |
| WO1999029646A1 (en) * | 1997-08-06 | 1999-06-17 | The Nutrasweet Company | Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3,3-dimethylbutanol |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01132635A (ja) * | 1987-11-19 | 1989-05-25 | Nippon Soda Co Ltd | オルガノホスファゼンポリマーの製造法 |
| JPH0832647B2 (ja) * | 1989-01-27 | 1996-03-29 | 大阪有機化学工業株式会社 | 1級アルコールからアルデヒドの製造法 |
| JP3039025B2 (ja) * | 1991-07-19 | 2000-05-08 | 吉富製薬株式会社 | 置換アセトアルデヒドの製造方法 |
| US5155278A (en) * | 1991-09-30 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5155280A (en) * | 1991-09-30 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5155279A (en) * | 1991-10-18 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| DK0734392T3 (da) * | 1993-12-17 | 1999-08-23 | Upjohn Co | Omdannelse af bisnoralkohol til bisnoraldehyd |
| JP3775919B2 (ja) * | 1998-03-13 | 2006-05-17 | 大塚化学ホールディングス株式会社 | 難燃性樹脂、その組成物及びその製造法 |
| JP2000290214A (ja) * | 1999-04-02 | 2000-10-17 | Kuraray Co Ltd | ベンジルオキシアセトアルデヒドの製造方法 |
| JP2001011007A (ja) * | 1999-07-01 | 2001-01-16 | Sumika Fine Chemicals Co Ltd | ベンジルオキシアセトアルデヒド化合物の製造法 |
-
2000
- 2000-11-10 AT AT00811058T patent/ATE240285T1/de not_active IP Right Cessation
- 2000-11-10 EP EP00811058A patent/EP1103537B1/de not_active Expired - Lifetime
- 2000-11-10 DE DE50002160T patent/DE50002160D1/de not_active Expired - Lifetime
- 2000-11-14 JP JP2000346074A patent/JP4727806B2/ja not_active Expired - Fee Related
- 2000-11-15 US US09/713,277 patent/US6441243B1/en not_active Expired - Fee Related
- 2000-11-16 CZ CZ20004299A patent/CZ20004299A3/cs unknown
- 2000-11-17 TW TW089124350A patent/TWI266763B/zh not_active IP Right Cessation
- 2000-11-17 CA CA002326304A patent/CA2326304A1/en not_active Abandoned
- 2000-11-17 KR KR1020000068475A patent/KR100707839B1/ko not_active Expired - Fee Related
- 2000-11-17 SK SK1758-2000A patent/SK284566B6/sk unknown
- 2000-11-20 CN CNB001329987A patent/CN1173913C/zh not_active Expired - Fee Related
-
2002
- 2002-06-07 US US10/164,768 patent/US6660860B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05310632A (ja) * | 1992-04-28 | 1993-11-22 | Sumitomo Chem Co Ltd | m−フェノキシベンズアルデヒドの製造方法 |
| WO1999029646A1 (en) * | 1997-08-06 | 1999-06-17 | The Nutrasweet Company | Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3,3-dimethylbutanol |
Non-Patent Citations (5)
| Title |
|---|
| J. Org. Chem., 1999, 64(1), 310-312. * |
| Makromol. Chem., Macromol. Chem. Phys., 1988, 2611 |
| Makromol. Chem., Macromol. Chem. Phys., 1988, 2611-2615. * |
| Synthesis, 1996, 1153-1174. * |
| Synthesis, 1998, 977-979. * |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE240285T1 (de) | 2003-05-15 |
| JP2001199923A (ja) | 2001-07-24 |
| TWI266763B (en) | 2006-11-21 |
| SK284566B6 (sk) | 2005-06-02 |
| US6660860B2 (en) | 2003-12-09 |
| EP1103537B1 (de) | 2003-05-14 |
| CZ20004299A3 (cs) | 2002-05-15 |
| KR20010051782A (ko) | 2001-06-25 |
| US20020161265A1 (en) | 2002-10-31 |
| CN1304921A (zh) | 2001-07-25 |
| CN1173913C (zh) | 2004-11-03 |
| US6441243B1 (en) | 2002-08-27 |
| CA2326304A1 (en) | 2001-05-19 |
| DE50002160D1 (de) | 2003-06-18 |
| SK17582000A3 (sk) | 2001-06-11 |
| EP1103537A1 (de) | 2001-05-30 |
| JP4727806B2 (ja) | 2011-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100707839B1 (ko) | 제거하기가 용이한 니트록실 라디칼을 사용한 알콜의선택적 산화 방법 | |
| Polin et al. | Functionalization of 2, 2′-bipyridines in their 4 and 5 positions. Synthesis of 5-ethynyl-2, 2′-bipyridine | |
| US6750371B2 (en) | Process for the oxidation of alcohols to aldehydes and ketones in the presence of nitroxyl compounds as catalysts | |
| Oba et al. | Photosensitized oxygenation of diaryl tellurides to telluroxides and their oxidizing properties | |
| JP4971538B2 (ja) | 酸化触媒ポリマー及びそれを用いたアルコールより高次な酸化物の製造方法 | |
| EP1353750B1 (en) | Stable free nitroxyl radicals as oxidation catalysts and process for oxidation | |
| KR100596076B1 (ko) | 4-치환된 n-[(알크-2-엔-1-일)옥시]- 및n-아르알킬옥시-2,2,6,6-테트라알킬피페리딘의 합성방법 | |
| JPH07145157A (ja) | 光学活性エポキシドの製造法 | |
| MXPA00011305A (en) | Process for the selective oxidation of alcohols using easily separable nitroxyl radicals | |
| JP2775319B2 (ja) | ジアリールエチレングリコールの製造方法 | |
| JP2002201156A (ja) | β−ヒドロキシヒドロペルオキシド類およびカルボン酸類の製造法とその触媒 | |
| CN101146755A (zh) | 通过对-二甲苯在水中的液相氧化来制备对-甲苯甲酸的方法 | |
| JP4369240B2 (ja) | 不飽和アルコールの酸化法 | |
| CA1143741A (en) | Process for oxidation of ketones by hydrogen peroxide | |
| JPH041189A (ja) | 大環状ラクトンの製造方法 | |
| Zolfigol et al. | Silica sulfuric acid/wet SiO2 as a novel heterogeneous system for cleavage of carbon nitrogen double bonds under mild conditions | |
| JP3068899B2 (ja) | エポキシ基含有化合物の製造方法 | |
| JPH04266878A (ja) | エポキシ基含有化合物の製造方法 | |
| JPH08119904A (ja) | 乳酸エステルの製造方法 | |
| JP2845607B2 (ja) | カルボニル基含有化合物の製造方法 | |
| CN101024602A (zh) | 使用稳定的硝酰游离基在温和的条件下使醇发生无过渡金属催化的需氧氧化反应的方法 | |
| JPH11228544A (ja) | ホルミルイミダゾール類の製造方法 | |
| JP4352130B2 (ja) | ポリマー固定化チタン化合物、その製造方法及びそれからなるポリマー固定化ルイス酸触媒 | |
| JP2003081977A (ja) | 1,4−エンドぺルオキシド誘導体及びこれを用いた一重項酸素発生試薬 | |
| JPH04221391A (ja) | エポキシ基含有化合物の製造方法および新規な鉄化合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
St.27 status event code: A-0-1-A10-A12-nap-PA0109 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| A201 | Request for examination | ||
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
| PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U11-oth-PR1002 Fee payment year number: 1 |
|
| PG1601 | Publication of registration |
St.27 status event code: A-4-4-Q10-Q13-nap-PG1601 |
|
| R18-X000 | Changes to party contact information recorded |
St.27 status event code: A-5-5-R10-R18-oth-X000 |
|
| LAPS | Lapse due to unpaid annual fee | ||
| PC1903 | Unpaid annual fee |
St.27 status event code: A-4-4-U10-U13-oth-PC1903 Not in force date: 20100410 Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE |
|
| PC1903 | Unpaid annual fee |
St.27 status event code: N-4-6-H10-H13-oth-PC1903 Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE Not in force date: 20100410 |