DE50002160D1 - Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale - Google Patents

Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale

Info

Publication number
DE50002160D1
DE50002160D1 DE50002160T DE50002160T DE50002160D1 DE 50002160 D1 DE50002160 D1 DE 50002160D1 DE 50002160 T DE50002160 T DE 50002160T DE 50002160 T DE50002160 T DE 50002160T DE 50002160 D1 DE50002160 D1 DE 50002160D1
Authority
DE
Germany
Prior art keywords
alcohols
selective oxidation
oxy
easily removable
nitroxyl radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE50002160T
Other languages
German (de)
English (en)
Inventor
Reinhard Sommerlade
Hansjoerg Gruetzmacher
Souad Boulmaaz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Application granted granted Critical
Publication of DE50002160D1 publication Critical patent/DE50002160D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/025—Polyphosphazenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
    • C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
    • C07F9/65815—Cyclic phosphazenes [P=N-]n, n>=3 n = 3
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Polyethers (AREA)
DE50002160T 1999-11-19 2000-11-10 Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale Expired - Lifetime DE50002160D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH211399 1999-11-19

Publications (1)

Publication Number Publication Date
DE50002160D1 true DE50002160D1 (de) 2003-06-18

Family

ID=4226187

Family Applications (1)

Application Number Title Priority Date Filing Date
DE50002160T Expired - Lifetime DE50002160D1 (de) 1999-11-19 2000-11-10 Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale

Country Status (11)

Country Link
US (2) US6441243B1 (https=)
EP (1) EP1103537B1 (https=)
JP (1) JP4727806B2 (https=)
KR (1) KR100707839B1 (https=)
CN (1) CN1173913C (https=)
AT (1) ATE240285T1 (https=)
CA (1) CA2326304A1 (https=)
CZ (1) CZ20004299A3 (https=)
DE (1) DE50002160D1 (https=)
SK (1) SK284566B6 (https=)
TW (1) TWI266763B (https=)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004524296A (ja) * 2001-01-23 2004-08-12 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 酸化触媒としての安定なフリーニトロキシルラジカル及び酸化方法
ATE257136T1 (de) 2001-10-11 2004-01-15 Consortium Elektrochem Ind Verfahren zur oxidation von alkoholen unter katalyse von nitroxylverbindungen
KR101029863B1 (ko) * 2001-12-21 2011-04-18 시바 홀딩 인코포레이티드 신규한 난연제 화합물
JP4369240B2 (ja) * 2002-01-29 2009-11-18 フイルメニツヒ ソシエテ アノニム 不飽和アルコールの酸化法
JPWO2003080575A1 (ja) * 2002-03-26 2005-07-21 広栄化学工業株式会社 複素環式アルデヒドの製造方法
WO2003084911A1 (en) * 2002-04-05 2003-10-16 Ciba Specialty Chemicals Holding Inc. Process for converting alcohols to carbonyl compounds
DE10244633B3 (de) 2002-09-25 2004-02-26 Consortium für elektrochemische Industrie GmbH Verfahren zur Herstellung von Alkincarbonsäuren durch Oxidation von Alkinalkoholen
AU2003276010A1 (en) * 2002-10-07 2004-04-23 Ciba Specialty Chemicals Holding Inc. Oxoammonium salts of 1-oxy-2,2,6,6-tetramethyl-1-piperidine (tempo) and their use as oxidizing agents
WO2005084800A1 (en) * 2004-03-02 2005-09-15 Johnson Matthey Plc Oxidation catalysts
CN1300081C (zh) * 2004-12-30 2007-02-14 中国科学院大连化学物理研究所 一种催化空气氧化醇制备醛和酮的方法
US7658802B2 (en) * 2005-11-22 2010-02-09 Applied Materials, Inc. Apparatus and a method for cleaning a dielectric film
CN101774898B (zh) * 2009-01-14 2012-08-08 中国科学院大连化学物理研究所 一种丙酮醇的制备方法
CN105272954B (zh) * 2014-06-27 2017-10-13 上海弈柯莱生物医药科技有限公司 一种6‑取代甲基‑4‑羟基四氢吡喃‑2‑酮及其衍生物的制备方法
CN111646963B (zh) * 2020-06-29 2022-09-27 张明 一种δ-环戊内酯的制备方法
CN115819388B (zh) * 2021-09-17 2024-06-11 台州学院 一种δ-环戊内酯的制备方法
US20250170565A1 (en) * 2022-03-02 2025-05-29 Asymchem Life Science (Tianjin) Co. Ltd. Catalyst Loaded with TEMPO Compound, and Preparation Method and Use thereof
WO2024107929A1 (en) * 2022-11-16 2024-05-23 Wisconsin Alumni Research Foundation Catalytic synthesis of delta-valerolactone (dvl) from furfural-derived 2-hydroxytetrahydropyran (hthp)
CN116751173A (zh) * 2023-05-05 2023-09-15 易简和成(江苏)医药科技有限公司 一种药物中间体的绿色合成方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01132635A (ja) * 1987-11-19 1989-05-25 Nippon Soda Co Ltd オルガノホスファゼンポリマーの製造法
JPH0832647B2 (ja) * 1989-01-27 1996-03-29 大阪有機化学工業株式会社 １級アルコールからアルデヒドの製造法
JP3039025B2 (ja) * 1991-07-19 2000-05-08 吉富製薬株式会社 置換アセトアルデヒドの製造方法
US5155278A (en) * 1991-09-30 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
US5155280A (en) * 1991-09-30 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
US5155279A (en) * 1991-10-18 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
JPH05310632A (ja) * 1992-04-28 1993-11-22 Sumitomo Chem Co Ltd ｍ−フェノキシベンズアルデヒドの製造方法
DK0734392T3 (da) * 1993-12-17 1999-08-23 Upjohn Co Omdannelse af bisnoralkohol til bisnoraldehyd
US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
JP3775919B2 (ja) * 1998-03-13 2006-05-17 大塚化学ホールディングス株式会社 難燃性樹脂、その組成物及びその製造法
JP2000290214A (ja) * 1999-04-02 2000-10-17 Kuraray Co Ltd ベンジルオキシアセトアルデヒドの製造方法
JP2001011007A (ja) * 1999-07-01 2001-01-16 Sumika Fine Chemicals Co Ltd ベンジルオキシアセトアルデヒド化合物の製造法

Also Published As

Publication number Publication date
ATE240285T1 (de) 2003-05-15
JP2001199923A (ja) 2001-07-24
TWI266763B (en) 2006-11-21
SK284566B6 (sk) 2005-06-02
US6660860B2 (en) 2003-12-09
EP1103537B1 (de) 2003-05-14
CZ20004299A3 (cs) 2002-05-15
KR100707839B1 (ko) 2007-04-17
KR20010051782A (ko) 2001-06-25
US20020161265A1 (en) 2002-10-31
CN1304921A (zh) 2001-07-25
CN1173913C (zh) 2004-11-03
US6441243B1 (en) 2002-08-27
CA2326304A1 (en) 2001-05-19
SK17582000A3 (sk) 2001-06-11
EP1103537A1 (de) 2001-05-30
JP4727806B2 (ja) 2011-07-20

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Legal Events

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Owner name: CIBA HOLDING INC., BASEL, CH