KR100707286B1 - 금속 시아나이드 촉매/폴리올 개시제 슬러리의 제조방법 - Google Patents

금속 시아나이드 촉매/폴리올 개시제 슬러리의 제조방법 Download PDF

Info

Publication number
KR100707286B1
KR100707286B1 KR1020027015604A KR20027015604A KR100707286B1 KR 100707286 B1 KR100707286 B1 KR 100707286B1 KR 1020027015604 A KR1020027015604 A KR 1020027015604A KR 20027015604 A KR20027015604 A KR 20027015604A KR 100707286 B1 KR100707286 B1 KR 100707286B1
Authority
KR
South Korea
Prior art keywords
compound
initiator
metal
mixture
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020027015604A
Other languages
English (en)
Korean (ko)
Other versions
KR20030017976A (ko
Inventor
웨메이어리차드엠.
Original Assignee
다우 글로벌 테크놀로지스 인크.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 인크. filed Critical 다우 글로벌 테크놀로지스 인크.
Publication of KR20030017976A publication Critical patent/KR20030017976A/ko
Application granted granted Critical
Publication of KR100707286B1 publication Critical patent/KR100707286B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Treatment Of Sludge (AREA)
KR1020027015604A 2000-05-19 2000-07-07 금속 시아나이드 촉매/폴리올 개시제 슬러리의 제조방법 Expired - Fee Related KR100707286B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/574,847 US6429166B1 (en) 2000-05-19 2000-05-19 Method for preparing metal cyanide catalyst/polyol initiator slurries
US09/574,847 2000-05-19
PCT/US2000/018622 WO2001090216A1 (en) 2000-05-19 2000-07-07 Method for preparing metal cyanide catalyst/polyol initiator slurries

Publications (2)

Publication Number Publication Date
KR20030017976A KR20030017976A (ko) 2003-03-04
KR100707286B1 true KR100707286B1 (ko) 2007-04-16

Family

ID=24297899

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027015604A Expired - Fee Related KR100707286B1 (ko) 2000-05-19 2000-07-07 금속 시아나이드 촉매/폴리올 개시제 슬러리의 제조방법

Country Status (15)

Country Link
US (1) US6429166B1 (enExample)
EP (1) EP1290060B1 (enExample)
JP (1) JP4975935B2 (enExample)
KR (1) KR100707286B1 (enExample)
CN (1) CN1239570C (enExample)
AT (1) ATE400601T1 (enExample)
AU (1) AU2000260775A1 (enExample)
BR (1) BR0015890A (enExample)
CA (1) CA2408147C (enExample)
DE (1) DE60039463D1 (enExample)
ES (1) ES2304968T3 (enExample)
MX (1) MXPA02011432A (enExample)
TW (1) TW555594B (enExample)
WO (1) WO2001090216A1 (enExample)
ZA (1) ZA200209059B (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR0308674A (pt) 2002-03-19 2005-02-01 Dow Global Technologies Inc Métodos para preparar catalisador de cianeto metálico usando sais metálicos insolúveis
MXPA04009144A (es) * 2002-03-21 2004-11-26 Dow Global Technologies Inc Metodo para preparar catalizadores de cianuro de metal usando metales de valencia cero.
DE602004004531T2 (de) * 2003-05-22 2007-06-06 Dow Global Technologies, Inc., Midland Nanoskalige dmc-katalysatorpartikel
KR20050041543A (ko) * 2003-10-31 2005-05-04 엘지전자 주식회사 광기록재생기의 디스플레이 제어방법 및 제어장치
US6869905B1 (en) * 2004-03-02 2005-03-22 Basf Corporation Synthesis of double metal cyanides with non-aqueous solutions
MX221601B (en) * 2004-05-14 2004-07-22 Basf Ag Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity
KR101315527B1 (ko) * 2004-10-26 2013-10-08 다우 글로벌 테크놀로지스 엘엘씨 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및그로부터 제조된 알콕시화 화합물
MX2009008311A (es) * 2007-02-05 2009-08-12 Basf Se Catalizadores de dmc, metodo para la produccion de los mismos y uso de los mismos.
MX2012004169A (es) 2009-10-19 2012-05-08 Basf Se Acondicionado de catalizadores de cianuro de doble metal.
WO2011160296A1 (en) 2010-06-23 2011-12-29 Basf Se Modified double metal cyanide catalyst
CN103764715B (zh) 2011-08-25 2017-02-15 陶氏环球技术有限责任公司 通过碳酸乙二醇酯在双金属氰化物催化剂的存在下的聚合制备具有氧亚乙基单元的聚醚醇的方法
KR102606479B1 (ko) * 2021-01-20 2023-11-24 아주대학교산학협력단 고순도의 하이드로젠 헥사시아노코발테이트 화합물 및 이의 제조 방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5639705A (en) 1996-01-19 1997-06-17 Arco Chemical Technology, L.P. Double metal cyanide catalysts and methods for making them

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3278457A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
AU551979B2 (en) 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
AU552988B2 (en) 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5767323A (en) 1995-12-22 1998-06-16 Arco Chemical Technology, L.P. Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation
US5777177A (en) 1996-02-07 1998-07-07 Arco Chemical Technology, L.P. Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter
US5627120A (en) * 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5689012A (en) 1996-07-18 1997-11-18 Arco Chemical Technology, L.P. Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter
DE19709031A1 (de) * 1997-03-06 1998-09-10 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
DE19730467A1 (de) 1997-07-16 1999-01-21 Bayer Ag Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19809538A1 (de) 1998-03-05 1999-09-09 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
DE19809539A1 (de) * 1998-03-05 1999-09-09 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
US6063897A (en) * 1998-05-05 2000-05-16 Arco Chemical Technology, L.P. Acid-treated double metal cyanide complex catalysts
US6800583B2 (en) * 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
US6613714B2 (en) * 1999-06-02 2003-09-02 Basf Aktiengesellschaft Multimetal cyanide compounds, their preparation and their use
ES2244446T3 (es) * 1999-06-02 2005-12-16 Basf Aktiengesellschaft Procedimiento para la preparacion de polieterpolioles con empleo de catalizadores cristalinos de cianuros polimetalicos.
EP1200506B1 (en) * 1999-07-09 2006-04-12 Dow Global Technologies Inc. Polymerization of ethylene oxide using metal cyanide catalsyts
AU5788500A (en) * 1999-07-09 2001-01-30 Dow Chemical Company, The Polymerization of alkylene oxides using metal cyanide catalysts and unsaturated initiator compounds

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5639705A (en) 1996-01-19 1997-06-17 Arco Chemical Technology, L.P. Double metal cyanide catalysts and methods for making them

Also Published As

Publication number Publication date
JP4975935B2 (ja) 2012-07-11
WO2001090216A1 (en) 2001-11-29
BR0015890A (pt) 2003-06-10
WO2001090216A9 (en) 2004-02-12
ATE400601T1 (de) 2008-07-15
CA2408147A1 (en) 2001-11-29
ES2304968T3 (es) 2008-11-01
TW555594B (en) 2003-10-01
JP2004516337A (ja) 2004-06-03
EP1290060B1 (en) 2008-07-09
CN1452644A (zh) 2003-10-29
DE60039463D1 (de) 2008-08-21
EP1290060A1 (en) 2003-03-12
US6429166B1 (en) 2002-08-06
MXPA02011432A (es) 2003-06-06
AU2000260775A8 (enExample) 2002-02-21
CA2408147C (en) 2009-01-06
CN1239570C (zh) 2006-02-01
AU2000260775A1 (en) 2001-12-03
ZA200209059B (en) 2003-11-27
KR20030017976A (ko) 2003-03-04

Similar Documents

Publication Publication Date Title
JP4043061B2 (ja) 改良されたポリエーテル含有二重金属シアン化物触媒並びにその製法および用途
CN100506382C (zh) 用部分可溶的络合剂制备金属氰化物催化剂络合物的方法
KR20030017976A (ko) 금속 시아나이드 촉매/폴리올 개시제 슬러리의 제조방법
WO2001004180A1 (en) Method for preparing metal cyanide catalysts using polycarboxylic acids
KR20020028211A (ko) 금속 함유 시아나이드 촉매의 초기 습식 제조방법
US7022641B2 (en) Method for preparing metal cyanide catalysts using insoluble metal salts
US6900156B2 (en) Method for preparing metal cyanide catalysts using zero valent metals
JP2003534419A (ja) 錯化剤で変性された三金属シアン化物触媒
US6384183B1 (en) Metal hexacyanocobaltate nitroferricyanide complexes
US6376645B1 (en) Complexing agent-modified hexacyanometallate hexanitrometallate catalysts
US6358877B1 (en) Metal catalysts complexed with sulfone or sulfoxide compounds
WO2001090217A1 (en) Method for preparing metal cyanide catalysts and for using same
EP1194230A1 (en) Metal catalysts complexed with sulfone or sulfoxide compounds

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

FPAY Annual fee payment

Payment date: 20110318

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20120407

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20120407

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000