JP4975935B2 - 金属シアン化物触媒／ポリオール開始剤スラリーの製造方法 - Google Patents
金属シアン化物触媒／ポリオール開始剤スラリーの製造方法 Download PDFInfo
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- JP4975935B2 JP4975935B2 JP2001587024A JP2001587024A JP4975935B2 JP 4975935 B2 JP4975935 B2 JP 4975935B2 JP 2001587024 A JP2001587024 A JP 2001587024A JP 2001587024 A JP2001587024 A JP 2001587024A JP 4975935 B2 JP4975935 B2 JP 4975935B2
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- 239000003054 catalyst Substances 0.000 title claims abstract description 133
- 239000003999 initiator Substances 0.000 title claims abstract description 115
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 102
- 239000002184 metal Substances 0.000 title claims abstract description 102
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 32
- 229920005862 polyol Polymers 0.000 title claims description 16
- 150000003077 polyols Chemical class 0.000 title claims description 16
- 239000002002 slurry Substances 0.000 title abstract description 59
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 59
- 150000001875 compounds Chemical class 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 41
- 239000006185 dispersion Substances 0.000 claims abstract description 34
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims abstract description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 178
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 56
- 150000003839 salts Chemical class 0.000 claims description 43
- -1 cyanide compound Chemical class 0.000 claims description 42
- 239000002244 precipitate Substances 0.000 claims description 33
- 229920000570 polyether Polymers 0.000 claims description 20
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 8
- 229910001428 transition metal ion Inorganic materials 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
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- 150000003573 thiols Chemical class 0.000 claims description 2
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- 239000000243 solution Substances 0.000 description 80
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- 235000011187 glycerol Nutrition 0.000 description 16
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- 238000003756 stirring Methods 0.000 description 14
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- 238000004458 analytical method Methods 0.000 description 9
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
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- 239000002253 acid Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
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- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 3
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- 239000002994 raw material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 description 2
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 description 2
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
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- KTUQUZJOVNIKNZ-UHFFFAOYSA-N butan-1-ol;hydrate Chemical compound O.CCCCO KTUQUZJOVNIKNZ-UHFFFAOYSA-N 0.000 description 2
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- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
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- 239000000463 material Substances 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
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- RKBAPHPQTADBIK-UHFFFAOYSA-N cobalt;hexacyanide Chemical compound [Co].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] RKBAPHPQTADBIK-UHFFFAOYSA-N 0.000 description 1
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- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- YOIAWAIKYVEKMF-UHFFFAOYSA-N trifluoromethanesulfonic acid Chemical compound OS(=O)(=O)C(F)(F)F.OS(=O)(=O)C(F)(F)F YOIAWAIKYVEKMF-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Treatment Of Sludge (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/574,847 US6429166B1 (en) | 2000-05-19 | 2000-05-19 | Method for preparing metal cyanide catalyst/polyol initiator slurries |
| US09/574,847 | 2000-05-19 | ||
| PCT/US2000/018622 WO2001090216A1 (en) | 2000-05-19 | 2000-07-07 | Method for preparing metal cyanide catalyst/polyol initiator slurries |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004516337A JP2004516337A (ja) | 2004-06-03 |
| JP2004516337A5 JP2004516337A5 (enExample) | 2007-08-23 |
| JP4975935B2 true JP4975935B2 (ja) | 2012-07-11 |
Family
ID=24297899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001587024A Expired - Fee Related JP4975935B2 (ja) | 2000-05-19 | 2000-07-07 | 金属シアン化物触媒／ポリオール開始剤スラリーの製造方法 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6429166B1 (enExample) |
| EP (1) | EP1290060B1 (enExample) |
| JP (1) | JP4975935B2 (enExample) |
| KR (1) | KR100707286B1 (enExample) |
| CN (1) | CN1239570C (enExample) |
| AT (1) | ATE400601T1 (enExample) |
| AU (1) | AU2000260775A1 (enExample) |
| BR (1) | BR0015890A (enExample) |
| CA (1) | CA2408147C (enExample) |
| DE (1) | DE60039463D1 (enExample) |
| ES (1) | ES2304968T3 (enExample) |
| MX (1) | MXPA02011432A (enExample) |
| TW (1) | TW555594B (enExample) |
| WO (1) | WO2001090216A1 (enExample) |
| ZA (1) | ZA200209059B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0308674A (pt) | 2002-03-19 | 2005-02-01 | Dow Global Technologies Inc | Métodos para preparar catalisador de cianeto metálico usando sais metálicos insolúveis |
| MXPA04009144A (es) * | 2002-03-21 | 2004-11-26 | Dow Global Technologies Inc | Metodo para preparar catalizadores de cianuro de metal usando metales de valencia cero. |
| DE602004004531T2 (de) * | 2003-05-22 | 2007-06-06 | Dow Global Technologies, Inc., Midland | Nanoskalige dmc-katalysatorpartikel |
| KR20050041543A (ko) * | 2003-10-31 | 2005-05-04 | 엘지전자 주식회사 | 광기록재생기의 디스플레이 제어방법 및 제어장치 |
| US6869905B1 (en) * | 2004-03-02 | 2005-03-22 | Basf Corporation | Synthesis of double metal cyanides with non-aqueous solutions |
| MX221601B (en) * | 2004-05-14 | 2004-07-22 | Basf Ag | Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity |
| KR101315527B1 (ko) * | 2004-10-26 | 2013-10-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및그로부터 제조된 알콕시화 화합물 |
| MX2009008311A (es) * | 2007-02-05 | 2009-08-12 | Basf Se | Catalizadores de dmc, metodo para la produccion de los mismos y uso de los mismos. |
| MX2012004169A (es) | 2009-10-19 | 2012-05-08 | Basf Se | Acondicionado de catalizadores de cianuro de doble metal. |
| WO2011160296A1 (en) | 2010-06-23 | 2011-12-29 | Basf Se | Modified double metal cyanide catalyst |
| CN103764715B (zh) | 2011-08-25 | 2017-02-15 | 陶氏环球技术有限责任公司 | 通过碳酸乙二醇酯在双金属氰化物催化剂的存在下的聚合制备具有氧亚乙基单元的聚醚醇的方法 |
| KR102606479B1 (ko) * | 2021-01-20 | 2023-11-24 | 아주대학교산학협력단 | 고순도의 하이드로젠 헥사시아노코발테이트 화합물 및 이의 제조 방법 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3278457A (en) | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| AU551979B2 (en) | 1982-03-31 | 1986-05-15 | Shell Internationale Research Maatschappij B.V. | Epoxy polymerisation catalysts |
| AU552988B2 (en) | 1982-03-31 | 1986-06-26 | Shell Internationale Research Maatschappij B.V. | Polymerizing epoxides and catalyst suspensions for this |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5767323A (en) | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| US5639705A (en) | 1996-01-19 | 1997-06-17 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts and methods for making them |
| US5777177A (en) | 1996-02-07 | 1998-07-07 | Arco Chemical Technology, L.P. | Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter |
| US5627120A (en) * | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5689012A (en) | 1996-07-18 | 1997-11-18 | Arco Chemical Technology, L.P. | Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter |
| DE19709031A1 (de) * | 1997-03-06 | 1998-09-10 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| DE19730467A1 (de) | 1997-07-16 | 1999-01-21 | Bayer Ag | Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19809538A1 (de) | 1998-03-05 | 1999-09-09 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| DE19809539A1 (de) * | 1998-03-05 | 1999-09-09 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| US6063897A (en) * | 1998-05-05 | 2000-05-16 | Arco Chemical Technology, L.P. | Acid-treated double metal cyanide complex catalysts |
| US6800583B2 (en) * | 1999-06-02 | 2004-10-05 | Basf Aktiengesellschaft | Suspension of multimetal cyanide compounds, their preparation and their use |
| US6613714B2 (en) * | 1999-06-02 | 2003-09-02 | Basf Aktiengesellschaft | Multimetal cyanide compounds, their preparation and their use |
| ES2244446T3 (es) * | 1999-06-02 | 2005-12-16 | Basf Aktiengesellschaft | Procedimiento para la preparacion de polieterpolioles con empleo de catalizadores cristalinos de cianuros polimetalicos. |
| EP1200506B1 (en) * | 1999-07-09 | 2006-04-12 | Dow Global Technologies Inc. | Polymerization of ethylene oxide using metal cyanide catalsyts |
| AU5788500A (en) * | 1999-07-09 | 2001-01-30 | Dow Chemical Company, The | Polymerization of alkylene oxides using metal cyanide catalysts and unsaturated initiator compounds |
-
2000
- 2000-05-19 US US09/574,847 patent/US6429166B1/en not_active Expired - Fee Related
- 2000-07-07 WO PCT/US2000/018622 patent/WO2001090216A1/en not_active Ceased
- 2000-07-07 AT AT00947112T patent/ATE400601T1/de not_active IP Right Cessation
- 2000-07-07 MX MXPA02011432A patent/MXPA02011432A/es active IP Right Grant
- 2000-07-07 CA CA002408147A patent/CA2408147C/en not_active Expired - Fee Related
- 2000-07-07 BR BR0015890-9A patent/BR0015890A/pt not_active Application Discontinuation
- 2000-07-07 KR KR1020027015604A patent/KR100707286B1/ko not_active Expired - Fee Related
- 2000-07-07 AU AU2000260775A patent/AU2000260775A1/en not_active Abandoned
- 2000-07-07 ES ES00947112T patent/ES2304968T3/es not_active Expired - Lifetime
- 2000-07-07 CN CNB008195560A patent/CN1239570C/zh not_active Expired - Fee Related
- 2000-07-07 EP EP00947112A patent/EP1290060B1/en not_active Expired - Lifetime
- 2000-07-07 JP JP2001587024A patent/JP4975935B2/ja not_active Expired - Fee Related
- 2000-07-07 DE DE60039463T patent/DE60039463D1/de not_active Expired - Lifetime
- 2000-10-06 TW TW089113582A patent/TW555594B/zh not_active IP Right Cessation
-
2002
- 2002-11-07 ZA ZA200209059A patent/ZA200209059B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001090216A1 (en) | 2001-11-29 |
| BR0015890A (pt) | 2003-06-10 |
| WO2001090216A9 (en) | 2004-02-12 |
| ATE400601T1 (de) | 2008-07-15 |
| CA2408147A1 (en) | 2001-11-29 |
| ES2304968T3 (es) | 2008-11-01 |
| TW555594B (en) | 2003-10-01 |
| JP2004516337A (ja) | 2004-06-03 |
| EP1290060B1 (en) | 2008-07-09 |
| CN1452644A (zh) | 2003-10-29 |
| DE60039463D1 (de) | 2008-08-21 |
| EP1290060A1 (en) | 2003-03-12 |
| US6429166B1 (en) | 2002-08-06 |
| MXPA02011432A (es) | 2003-06-06 |
| AU2000260775A8 (enExample) | 2002-02-21 |
| KR100707286B1 (ko) | 2007-04-16 |
| CA2408147C (en) | 2009-01-06 |
| CN1239570C (zh) | 2006-02-01 |
| AU2000260775A1 (en) | 2001-12-03 |
| ZA200209059B (en) | 2003-11-27 |
| KR20030017976A (ko) | 2003-03-04 |
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