KR100690496B1 - 폴리에스테르 및 폴리아미드용 양이온성 염색성 개질제 - Google Patents
폴리에스테르 및 폴리아미드용 양이온성 염색성 개질제 Download PDFInfo
- Publication number
- KR100690496B1 KR100690496B1 KR1020027010385A KR20027010385A KR100690496B1 KR 100690496 B1 KR100690496 B1 KR 100690496B1 KR 1020027010385 A KR1020027010385 A KR 1020027010385A KR 20027010385 A KR20027010385 A KR 20027010385A KR 100690496 B1 KR100690496 B1 KR 100690496B1
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- KR
- South Korea
- Prior art keywords
- copolymer
- integer
- group
- sodium
- dyed
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyamides (AREA)
- Coloring (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
(여기서, 기 Y는 -SO3M이거나 또는 인을 함유함)인 단위를 포함하는 폴리에스테르에 관한 것이다. 미국 특허 제3,018,272호는 금속염 형태의 설포네이트기를 함유한 필름 및(또는) 섬유 형성 폴리에스테르에 관한 것이다. 설포네이트기는 화학식이
(여기서 -Z(SO3M)는 R이 탄소 원자 3개 이상에 의해 -SO3M 라디칼로부터 분리되도록 하는 2가 아릴렌 라디칼의 금속염 및 2가 알킬렌 라디칼의 금속염으로 이루어진 군의 구성원이고, R은 -O-(CO)-저급 알킬, -(CO)-OH, -(CO)-O-저급 알킬, -(CH2)nOH, -O(CH2)nOH, -O-(CH2)n-[O(CH2)n]m-OH 및 -(CO)-[O(CH2)n]m-OH로 이루어진 군의 구성원이고, R'은 수소 및 R로 이루어진 군의 구성원임)인, 상기 문헌 칼럼 7에 기술된 단량체기의 일부이다.
시료 | 중합체 | 세브론 염료 염착, % | ||
블루(655 nm) | 레드(Red)(510 mm) | 옐로우(Yellow)(440 nm) | ||
(캐리어 없음, 대기압, 100 ℃) | ||||
1 | A | 55.8 | 2.3 | 23.7 |
2 | B | 38.0 | 21.0 | 26.1 |
3 | C | 0 | 0 | 0 |
(캐리어 있음*, 대기압, 100 ℃) | ||||
4 | A | 85.1 | 63.9 | 74.8 |
5 | B | 100.0 | 96.1 | 97.2 |
(캐리어 없음, 압력 25.3 psi(1.746×105 N/m2), 116 ℃) | ||||
6 | A | 75.3 | 60.9 | 65.1 |
7 | B | 98.6 | 97.4 | 96.7 |
* 캐리어는 타날론 HIW(상표명)(사이브론 케미칼즈, 인크.), 물에 유화된 비이온성 부틸 벤조에이트 캐리어. |
중합체 | 세브론 염료 염착 % | ||
블루(655 nm) | 레드(510 nm) | 옐로우(440 nm) | |
나일론 6,6 단일중합체 | 10.7 | 10.8 | 8.8 |
코폴리아미드 | 94.5 | 63.5 | 94.5 |
Claims (16)
- 화학식이R1OOC-(CH2)n-CH(CH2CH2SO3X)-(CH2 )m-COOR2(여기서, n은 1 내지 10의 정수이고, m은 1 내지 10의 정수이고, X는 리튬, 나트륨 및 칼륨으로 이루어진 군으로부터 선택된 알칼리 금속이고, R1 및 R2는 독립적으로 수소 또는 탄소 원자수가 1 내지 4인 알킬기임)인 화합물.
- 화학식이R1OOC-(CH2)n-CH(CH2CH2SO3X)-(CH2)m-COOR2(여기서, n은 1 내지 10의 정수이고, m은 1 내지 10의 정수이고, X는 리튬, 나트륨 및 칼륨으로 이루어진 군으로부터 선택된 알칼리 금속이고, R1 및 R2는 독립적으로 수소 또는 탄소 원자수가 1 내지 4인 알킬기임)인 화합물로부터 제조되고 염기성 염료에 대한 공중합체의 친화성을 개선하기 위하여 공중합체의 중합체 사슬에 혼입된 공단량체를 포함함을 특징으로 하는, 폴리(트리메틸렌 테레프탈레이트)로부터 유도된 코폴리에스테르인 공중합체.
- 제2항의 공중합체를 포함함을 특징으로 하는 성형 물품.
- 제3항에 있어서, 섬유인 성형 물품.
- 염색된 제2항의 공중합체를 포함함을 특징으로 하는 염색된 조성물.
- 염색된 제2항의 공중합체를 포함함을 특징으로 하는 염색된 성형 물품.
- 제2항의 공중합체를 포함함을 특징으로 하는 염색된 섬유.
- 제2항의 공중합체를 제공하고 이 공중합체를 염색하는 것을 포함함을 특징으로 하는 염색 방법.
- (a) 폴리(알킬렌 테레프탈레이트) 형성 단량체 및 폴리옥시알킬렌 글리콜 올리고머로 이루어진 군으로부터 선택된 1종 이상의 물질을 화학식R1OOC-(CH2)n-CH(CH2CH2SO3X)-(CH2)m-COOR2(여기서, n은 1 내지 10의 정수이고, m은 1 내지 10의 정수이고, X는 리튬, 나트륨 및 칼륨으로 이루어진 군으로부터 선택된 알칼리 금속이고, R1 및 R2는 독립적으로 수소 또는 탄소 원자수가 1 내지 4인 알킬기임)의 공단량체와 배합하는 단계, 및(b) 염기성 염료에 대한 코폴리에스테르의 친화성을 개선하는 공단량체를 함유한 코폴리에스테르를 형성하는 공중합을 유발하기 위하여 상기 물질 및 상기 공단량체를 혼합하고 가열하는 단계를 포함함을 특징으로 하는 코폴리에스테르의 제조 방법.
- 삭제
- 제1항에 있어서, 화합물이 3-(2-설포에틸) 헥산디산의 알칼리 금속염 및 디메틸-3-(2-설포에틸) 아디페이트의 알칼리 금속염으로 이루어진 군으로부터 선택된 것인 화합물.
- 제11항에 있어서, 화합물이 3-(2-설포에틸) 헥산디산의 나트륨염 및 디메틸-3-(2-설포에틸) 아디페이트의 나트륨염으로 이루어진 군으로부터 선택된 것인 화합물.
- 제2항에 있어서, 공단량체를 0.5 내지 4 몰% 포함하는 공중합체.
- 삭제
- 삭제
- 삭제
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/502,322 | 2000-02-11 | ||
US09/502,322 US6312805B1 (en) | 2000-02-11 | 2000-02-11 | Cationic dyeability modifier for use with polyester and polyamide |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020092953A KR20020092953A (ko) | 2002-12-12 |
KR100690496B1 true KR100690496B1 (ko) | 2007-03-09 |
Family
ID=23997291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020027010385A KR100690496B1 (ko) | 2000-02-11 | 2001-01-29 | 폴리에스테르 및 폴리아미드용 양이온성 염색성 개질제 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6312805B1 (ko) |
EP (1) | EP1254109B1 (ko) |
JP (1) | JP2003522755A (ko) |
KR (1) | KR100690496B1 (ko) |
CN (1) | CN1398253A (ko) |
AT (1) | ATE308516T1 (ko) |
DE (1) | DE60114566T2 (ko) |
TW (1) | TW588063B (ko) |
WO (1) | WO2001058863A1 (ko) |
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US20030146536A1 (en) * | 2001-12-07 | 2003-08-07 | General Electric Company | Color enhancement for resin blends |
EP1318176B1 (en) | 2001-12-07 | 2011-01-26 | SABIC Innovative Plastics IP B.V. | Color enhancement for resin blends |
US6923925B2 (en) | 2002-06-27 | 2005-08-02 | E. I. Du Pont De Nemours And Company | Process of making poly (trimethylene dicarboxylate) fibers |
US6921803B2 (en) * | 2002-07-11 | 2005-07-26 | E.I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate) fibers, their manufacture and use |
US6641916B1 (en) | 2002-11-05 | 2003-11-04 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate) bicomponent fibers |
JP2006511726A (ja) * | 2002-12-23 | 2006-04-06 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリ(トリメチレンテレフタレート)複合繊維方法 |
US7578957B2 (en) * | 2002-12-30 | 2009-08-25 | E. I. Du Pont De Nemours And Company | Process of making staple fibers |
US7005093B2 (en) | 2003-02-05 | 2006-02-28 | E. I. Du Pont De Nemours And Company | Spin annealed poly(trimethylene terephthalate) yarn |
US20040192976A1 (en) * | 2003-03-24 | 2004-09-30 | Shaorong Chen | Process for hydrolyzing water-insoluble epoxides |
US6906220B2 (en) * | 2003-03-24 | 2005-06-14 | Invista North America S.àr.l. | Process to produce 4-(2-sulfoethyl) cyclohexane, 1,2-diol sodium salt from 4-vinylcyclohexane-1,2-diol |
US20070035057A1 (en) * | 2003-06-26 | 2007-02-15 | Chang Jing C | Poly(trimethylene terephthalate) bicomponent fiber process |
US7785507B2 (en) * | 2004-04-30 | 2010-08-31 | E. I. Du Pont De Nemours And Company | Spinning poly(trimethylene terephthalate) yarns |
AR049538A1 (es) * | 2004-06-29 | 2006-08-09 | Procter & Gamble | Composiciones de detergentes para lavanderia con colorante entonador eficiente |
US20060041039A1 (en) * | 2004-08-20 | 2006-02-23 | Gyorgyi Fenyvesi | Fluorescent poly(alkylene terephthalate) compositions |
US7357985B2 (en) * | 2005-09-19 | 2008-04-15 | E.I. Du Pont De Nemours And Company | High crimp bicomponent fibers |
US20070129503A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles |
US7666501B2 (en) * | 2005-12-07 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments |
US20070128459A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films |
US20080135662A1 (en) * | 2006-12-06 | 2008-06-12 | Chang Jing C | Melt-spun elastoester multifilament yarns |
US9434648B2 (en) | 2011-04-21 | 2016-09-06 | Construction Research & Technology Gmbh | Accelerator composition |
CN118164849A (zh) * | 2024-05-09 | 2024-06-11 | 广州华新科智造技术有限公司 | 一种透明尼龙复合树脂及其制备方法与应用 |
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-
2000
- 2000-02-11 US US09/502,322 patent/US6312805B1/en not_active Expired - Lifetime
-
2001
- 2001-01-29 JP JP2001558415A patent/JP2003522755A/ja active Pending
- 2001-01-29 WO PCT/US2001/002655 patent/WO2001058863A1/en active IP Right Grant
- 2001-01-29 CN CN01804629A patent/CN1398253A/zh active Pending
- 2001-01-29 EP EP01905112A patent/EP1254109B1/en not_active Expired - Lifetime
- 2001-01-29 DE DE60114566T patent/DE60114566T2/de not_active Expired - Lifetime
- 2001-01-29 AT AT01905112T patent/ATE308516T1/de not_active IP Right Cessation
- 2001-01-29 KR KR1020027010385A patent/KR100690496B1/ko active IP Right Grant
- 2001-02-09 TW TW090102911A patent/TW588063B/zh not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US3018272A (en) * | 1955-06-30 | 1962-01-23 | Du Pont | Sulfonate containing polyesters dyeable with basic dyes |
US3389549A (en) | 1966-01-17 | 1968-06-25 | Du Pont | Aromatic dicarbonyl sulfonate modified polycarbonamides |
US3823120A (en) * | 1972-09-06 | 1974-07-09 | Allied Chem | Preparation and uses of n-(omega-aminoalkyl)-2-aminoethane sulfonic acids as cationic dyeable additives to polyamides |
JPH0753699A (ja) * | 1993-07-06 | 1995-02-28 | Teijin Ltd | 改質ポリエステルの製造方法 |
Also Published As
Publication number | Publication date |
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DE60114566T2 (de) | 2006-08-10 |
KR20020092953A (ko) | 2002-12-12 |
US6312805B1 (en) | 2001-11-06 |
EP1254109A1 (en) | 2002-11-06 |
WO2001058863A1 (en) | 2001-08-16 |
CN1398253A (zh) | 2003-02-19 |
TW588063B (en) | 2004-05-21 |
ATE308516T1 (de) | 2005-11-15 |
JP2003522755A (ja) | 2003-07-29 |
DE60114566D1 (de) | 2005-12-08 |
EP1254109B1 (en) | 2005-11-02 |
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