KR100654593B1 - Escr-강성 관계와 팽윤비가 개선된 폴리에틸렌 성형배합물, 이의 제조방법 및 이의 용도 - Google Patents
Escr-강성 관계와 팽윤비가 개선된 폴리에틸렌 성형배합물, 이의 제조방법 및 이의 용도 Download PDFInfo
- Publication number
- KR100654593B1 KR100654593B1 KR1020027003779A KR20027003779A KR100654593B1 KR 100654593 B1 KR100654593 B1 KR 100654593B1 KR 1020027003779 A KR1020027003779 A KR 1020027003779A KR 20027003779 A KR20027003779 A KR 20027003779A KR 100654593 B1 KR100654593 B1 KR 100654593B1
- Authority
- KR
- South Korea
- Prior art keywords
- reactor
- weight
- molecular weight
- range
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Polymerisation Methods In General (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19945980A DE19945980A1 (de) | 1999-09-24 | 1999-09-24 | Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper |
| DE19945980.0 | 1999-09-24 | ||
| PCT/EP2000/008817 WO2001023446A1 (de) | 1999-09-24 | 2000-09-09 | Polyethylen formmasse mit verbesserter escr-steifigkeitsrelation und schwellrate, verfahren zu ihrer herstellung und ihre verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20030004297A KR20030004297A (ko) | 2003-01-14 |
| KR100654593B1 true KR100654593B1 (ko) | 2006-12-07 |
Family
ID=7923276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020027003779A Expired - Fee Related KR100654593B1 (ko) | 1999-09-24 | 2000-09-09 | Escr-강성 관계와 팽윤비가 개선된 폴리에틸렌 성형배합물, 이의 제조방법 및 이의 용도 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6713561B1 (enExample) |
| EP (1) | EP1228101B1 (enExample) |
| JP (1) | JP2003510429A (enExample) |
| KR (1) | KR100654593B1 (enExample) |
| CN (1) | CN1162453C (enExample) |
| AT (1) | ATE244264T1 (enExample) |
| AU (1) | AU769434B2 (enExample) |
| BR (1) | BR0014232B1 (enExample) |
| CA (1) | CA2387708C (enExample) |
| DE (2) | DE19945980A1 (enExample) |
| ES (1) | ES2200919T3 (enExample) |
| RU (1) | RU2249018C2 (enExample) |
| WO (1) | WO2001023446A1 (enExample) |
| ZA (1) | ZA200202267B (enExample) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9919718D0 (en) | 1999-08-19 | 1999-10-20 | Borealis As | Process |
| US20030113496A1 (en) | 2001-12-17 | 2003-06-19 | Harris Michael G. | Polyethylene melt blends for high density polyethylene applications |
| US6822051B2 (en) * | 2002-03-29 | 2004-11-23 | Media Plus, Inc. | High density polyethylene melt blends for improved stress crack resistance in pipe |
| EP1357152A1 (en) * | 2002-04-26 | 2003-10-29 | Solvay Polyolefins Europe-Belgium (Société Anonyme) | Polymer for fuel tanks |
| DE10259491A1 (de) * | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Behältern durch Blasformen und damit hergestellte Kleinhohlkörper |
| KR20050088310A (ko) * | 2002-12-19 | 2005-09-05 | 바젤 폴리올레핀 게엠베하 | 소형 콘테이너 생산을 위한 폴리에틸렌 취입 성형 조성물 |
| RU2350633C2 (ru) * | 2002-12-19 | 2009-03-27 | Базелль Полиолефине Гмбх | Полиэтиленовая композиция для формования с раздувом, предназначенная для изготовления небольших контейнеров |
| DE10261064A1 (de) * | 2002-12-24 | 2004-07-08 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Behältern duch Blasformen und damit hergestellte L-Ring-Container |
| DE60306811T2 (de) * | 2002-12-24 | 2007-02-22 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Behältern durch Blasformen und damit hergestellte L-Ring-Conrainer |
| JP2006512474A (ja) * | 2002-12-24 | 2006-04-13 | バーゼル・ポリオレフィン・ゲーエムベーハー | ジェリー缶を製造するためのポリエチレン吹込成形用組成物 |
| DE10261066A1 (de) * | 2002-12-24 | 2004-07-08 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Behältern durch Blasformen und damit hergestellte Kanister |
| KR20050088113A (ko) * | 2002-12-24 | 2005-09-01 | 바젤 폴리올레핀 게엠베하 | 대형 콘테이너를 위한 폴리에틸렌 취입 성형 조성물 |
| US7288596B2 (en) * | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
| US7379696B2 (en) * | 2004-04-30 | 2008-05-27 | Ricoh Company Limited | Toner for developing electrostatic image, fixing method for fixing image formed of the toner, and image forming method and process cartridge using the toner |
| JP2008501850A (ja) * | 2004-06-07 | 2008-01-24 | ティコナ・エルエルシー | ポリエチレン成形粉およびそれより製造される多孔質物品 |
| US7432328B2 (en) * | 2005-06-14 | 2008-10-07 | Univation Technologies, Llc | Enhanced ESCR bimodal HDPE for blow molding applications |
| GB0418581D0 (en) * | 2004-08-20 | 2004-09-22 | Solvay | Polymer composition |
| DE102004055587A1 (de) | 2004-11-18 | 2006-05-24 | Basell Polyolefine Gmbh | Polyethylen Formmasse für die äußere Ummantelung von Elektrokabeln |
| BRPI0518320A2 (pt) * | 2004-11-18 | 2008-11-18 | Basell Polyolefine Gmbh | composiÇço de moldagem de polietileno, processo para a preparaÇço de uma composiÇço de moldagem de polietileno, uso de uma composiÇço de moldagem de polietileno, e, cabo de transmissço elÉtrica ou de informaÇÕes |
| DE102004055588A1 (de) * | 2004-11-18 | 2006-05-24 | Basell Polyolefine Gmbh | Polyethylen Formmasse für die Beschichtung von Stahlrohren |
| DE102005009916A1 (de) | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005009895A1 (de) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005009896A1 (de) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005030941A1 (de) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen |
| DE102005040390A1 (de) * | 2005-08-25 | 2007-03-01 | Basell Polyolefine Gmbh | Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften |
| KR101229632B1 (ko) * | 2005-09-28 | 2013-02-05 | 고에키자이단호진 고쿠사이카가쿠 신고우자이단 | 분위기 제어된 접합 장치, 접합 방법 및 전자 장치 |
| EP1772485A1 (en) | 2005-10-07 | 2007-04-11 | Borealis Technology Oy | Polyethylene composition with improved stress crack resistance/stiffness relation for blow moulding |
| EP1840140A1 (en) * | 2006-03-30 | 2007-10-03 | Total Petrochemicals Research Feluy | Method for making a transition between polymer grades |
| EP2218752B1 (en) * | 2006-04-07 | 2013-06-12 | Dow Global Technologies LLC | Polyolefin compositions and articles made therefrom |
| US7893181B2 (en) * | 2006-07-11 | 2011-02-22 | Fina Technology, Inc. | Bimodal film resin and products made therefrom |
| US7449529B2 (en) * | 2006-07-11 | 2008-11-11 | Fina Technology, Inc. | Bimodal blow molding resin and products made therefrom |
| US20080051538A1 (en) * | 2006-07-11 | 2008-02-28 | Fina Technology, Inc. | Bimodal pipe resin and products made therefrom |
| WO2008049551A1 (en) * | 2006-10-24 | 2008-05-02 | Basell Polyolefine Gmbh | Multimodal polyethylene molding composition for producing pipes having improved mechanical properties |
| KR101099205B1 (ko) | 2006-11-27 | 2011-12-27 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조방법 |
| ATE551392T1 (de) | 2007-01-16 | 2012-04-15 | Prime Polymer Co Ltd | Ethylenharzzusammensetzung für blasgeformten körper und damit erhaltener blasgeformter körper |
| EP1950241A1 (en) | 2007-01-25 | 2008-07-30 | Borealis Technology Oy | Multimodal medium density polyethylene polymer composition |
| DE102007016348A1 (de) * | 2007-04-03 | 2008-10-09 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Hohlkörpern durch Thermoformen und damit hergestellte Kraftstoffbehälter |
| DE102007031450A1 (de) * | 2007-07-05 | 2009-01-08 | Basell Polyolefine Gmbh | PE-Formmasse zum Blasformen von Kleinhohlkörpern mit niedriger Dichte |
| DE102007031449A1 (de) * | 2007-07-05 | 2009-01-08 | Basell Polyolefine Gmbh | PE-Formmasse zum Blasformen von Kleinhohlkörpern mit niedriger Dichte |
| CN101981110B (zh) * | 2007-12-18 | 2013-03-27 | 巴塞尔聚烯烃股份有限公司 | 生产注塑螺帽盖子的pe模塑组合物和用其生产的用于充碳酸气的饮料的高强度螺帽盖子 |
| ES2719527T3 (es) | 2007-12-31 | 2019-07-11 | Dow Global Technologies Llc | Composiciones de polímeros a base de etileno, métodos de preparación de las mismas y artículos preparados a partir de las mismas |
| RU2372360C1 (ru) * | 2008-06-06 | 2009-11-10 | Открытое акционерное общество "НИИ шинной промышленности" | Способ производства термоусадочных пленок |
| WO2010025342A2 (en) * | 2008-08-28 | 2010-03-04 | Dow Global Technologies Inc. | Process and compositions for injections blow molding |
| US9187627B2 (en) * | 2008-10-23 | 2015-11-17 | Equistar Chemicals, Lp | Polyethylene having faster crystallization rate and improved environmental stress cracking resistance |
| WO2010139419A2 (en) * | 2009-06-03 | 2010-12-09 | Basell Polyolefine Gmbh | Polyethylene composition and finished products made thereof |
| ES2421297T3 (es) | 2009-06-30 | 2013-08-30 | Basell Polyolefine Gmbh | Composición para el moldeo de polietileno |
| RU2436815C2 (ru) * | 2009-09-07 | 2011-12-20 | Общество с ограниченной ответственностью "ОСБИО" | Полимерный композиционный материал для изготовления электролизных ванн |
| US9493590B2 (en) | 2009-11-20 | 2016-11-15 | Basell Polyolefine Gmbh | Trimodal polyethylene for use in blow moulding |
| BR122019023821B1 (pt) * | 2010-11-22 | 2021-03-02 | Basell Polyolefine Gmbh | artigo moldado por sopro |
| AU2012210433B2 (en) | 2011-01-28 | 2014-11-06 | Borealis Ag | Polyethylene composition |
| CN103476854B (zh) | 2011-04-19 | 2016-02-10 | 巴塞尔聚烯烃股份有限公司 | 用于吹塑的新的聚合物组合物 |
| GB2498936A (en) * | 2012-01-31 | 2013-08-07 | Norner Innovation As | Polyethylene with multi-modal molecular weight distribution |
| EP2746334B1 (en) | 2012-12-19 | 2015-05-13 | Borealis AG | Polyethylene blend with improved ESCR |
| EP2818508A1 (en) * | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition having high impact and stress cracking resistance |
| GB201313937D0 (en) | 2013-08-05 | 2013-09-18 | Ineos Europe Ag | Polymerisation process |
| EP2860203B1 (en) | 2013-10-10 | 2016-12-14 | Borealis AG | Multistage process for producing polyethylene compositions |
| WO2015195189A1 (en) * | 2014-06-16 | 2015-12-23 | Univation Technologies, Llc | Polyethylene resins |
| WO2016075163A1 (en) * | 2014-11-13 | 2016-05-19 | Total Research & Technology Feluy | Metallocene catalyzed polyethylene resin |
| ES2883800T3 (es) | 2016-09-12 | 2021-12-09 | Thai Polyethylene Co Ltd | Composición de polietileno multimodal |
| ES2746570T3 (es) * | 2016-09-12 | 2020-03-06 | Thai Polyethylene Co Ltd | Tapón de rosca de polietileno multimodal |
| EP3293213B1 (en) * | 2016-09-12 | 2019-08-14 | Thai Polyethylene Co., Ltd. | Multimodal polyethylene container |
| CN109790229B (zh) | 2016-09-12 | 2021-08-06 | 泰国聚乙烯有限公司 | 双峰聚乙烯组合物和包含该组合物的管 |
| EP3293210B1 (en) | 2016-09-12 | 2019-03-06 | Thai Polyethylene Co., Ltd. | Multimodal polyethylene film |
| HUE047268T2 (hu) | 2016-09-12 | 2020-04-28 | Thai Polyethylene Co Ltd | Többmódusú polietilén csõ |
| ES2945358T3 (es) * | 2016-09-12 | 2023-06-30 | Thai Polyethylene Co Ltd | Composición polimérica para cierres de recipiente |
| HUE047431T2 (hu) * | 2016-09-12 | 2020-04-28 | Thai Polyethylene Co Ltd | Multimodális polietilén csõ |
| EP3293209B1 (en) | 2016-09-12 | 2019-08-14 | Thai Polyethylene Co., Ltd. | Multimodal polyethylene thin film |
| PL3293214T3 (pl) * | 2016-09-12 | 2020-07-27 | Thai Polyethylene Co., Ltd. | Wielomodalny polietylen o ultradużej masie cząsteczkowej o wysokich parametrach |
| US9963529B1 (en) | 2017-04-19 | 2018-05-08 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization |
| US10538654B2 (en) | 2017-04-19 | 2020-01-21 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization, polyethylene and polyethylene film |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5910724B2 (ja) | 1979-08-24 | 1984-03-10 | 旭化成株式会社 | エチレンの連続重合法 |
| DE3124223A1 (de) | 1981-06-20 | 1982-12-30 | Hoechst Ag, 6000 Frankfurt | "verfahren zur herstellung eines polyolefins und katalysator hierfuer" |
| JPS59196346A (ja) * | 1983-04-21 | 1984-11-07 | Asahi Chem Ind Co Ltd | ポリエチレン樹脂組成物 |
| JPS6036546A (ja) * | 1983-08-09 | 1985-02-25 | Asahi Chem Ind Co Ltd | ポリエチレン樹脂組成物 |
| CA1218181A (en) * | 1983-04-21 | 1987-02-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyethylene composition |
| JPS59227913A (ja) * | 1983-06-10 | 1984-12-21 | Idemitsu Petrochem Co Ltd | エチレン重合体あるいは共重合体の製造方法 |
| JPH07116251B2 (ja) * | 1985-03-11 | 1995-12-13 | 東ソー株式会社 | 改質されたポリエチレンの製造方法 |
| JP2712307B2 (ja) * | 1987-06-23 | 1998-02-10 | 東ソー株式会社 | ポリエチレンの製造方法 |
| DE3918646A1 (de) | 1989-06-08 | 1990-12-13 | Hoechst Ag | Verfahren zur herstellung eines poly-l-olefins |
| US5648309A (en) | 1990-06-01 | 1997-07-15 | Hoechst Aktiengesellschaft | Process for the preparation of a poly-1-olefin |
| US5338589A (en) | 1991-06-05 | 1994-08-16 | Hoechst Aktiengesellschaft | Polyethylene molding composition |
| JP2716615B2 (ja) * | 1991-10-25 | 1998-02-18 | 丸善ポリマー株式会社 | エチレン系重合体組成物の製造方法 |
| BE1006439A3 (fr) | 1992-12-21 | 1994-08-30 | Solvay Societe Annonyme | Procede de preparation d'une composition de polymeres d'ethylene, composition de polymeres d'ethylene et son utilisation. |
| FI96216C (fi) | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
| EP0905151A1 (en) | 1997-09-27 | 1999-03-31 | Fina Research S.A. | Production of polyethylene having a broad molecular weight distribution |
-
1999
- 1999-09-24 DE DE19945980A patent/DE19945980A1/de not_active Withdrawn
-
2000
- 2000-09-09 AU AU70017/00A patent/AU769434B2/en not_active Ceased
- 2000-09-09 JP JP2001526594A patent/JP2003510429A/ja active Pending
- 2000-09-09 CA CA002387708A patent/CA2387708C/en not_active Expired - Fee Related
- 2000-09-09 CN CNB008132518A patent/CN1162453C/zh not_active Expired - Fee Related
- 2000-09-09 WO PCT/EP2000/008817 patent/WO2001023446A1/de not_active Ceased
- 2000-09-09 ES ES00958529T patent/ES2200919T3/es not_active Expired - Lifetime
- 2000-09-09 DE DE50002772T patent/DE50002772D1/de not_active Expired - Lifetime
- 2000-09-09 RU RU2002110817/04A patent/RU2249018C2/ru not_active IP Right Cessation
- 2000-09-09 EP EP00958529A patent/EP1228101B1/de not_active Revoked
- 2000-09-09 US US10/088,855 patent/US6713561B1/en not_active Expired - Lifetime
- 2000-09-09 AT AT00958529T patent/ATE244264T1/de not_active IP Right Cessation
- 2000-09-09 BR BRPI0014232-8A patent/BR0014232B1/pt active IP Right Grant
- 2000-09-09 KR KR1020027003779A patent/KR100654593B1/ko not_active Expired - Fee Related
-
2002
- 2002-03-20 ZA ZA200202267A patent/ZA200202267B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1162453C (zh) | 2004-08-18 |
| CA2387708A1 (en) | 2001-04-05 |
| JP2003510429A (ja) | 2003-03-18 |
| DE50002772D1 (de) | 2003-08-07 |
| KR20030004297A (ko) | 2003-01-14 |
| EP1228101B1 (de) | 2003-07-02 |
| BR0014232A (pt) | 2002-06-04 |
| RU2249018C2 (ru) | 2005-03-27 |
| ES2200919T3 (es) | 2004-03-16 |
| CN1376170A (zh) | 2002-10-23 |
| EP1228101A1 (de) | 2002-08-07 |
| WO2001023446A1 (de) | 2001-04-05 |
| BR0014232B1 (pt) | 2010-08-24 |
| CA2387708C (en) | 2008-11-18 |
| US6713561B1 (en) | 2004-03-30 |
| AU7001700A (en) | 2001-04-30 |
| ATE244264T1 (de) | 2003-07-15 |
| ZA200202267B (en) | 2003-11-26 |
| AU769434B2 (en) | 2004-01-29 |
| DE19945980A1 (de) | 2001-03-29 |
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